1,10-Phenanthroline-2,9-diamine synthesis
- Product Name:1,10-Phenanthroline-2,9-diamine
- CAS Number:38182-65-9
- Molecular formula:C12H10N4
- Molecular Weight:210.23
29176-55-4
158 suppliers
$10.00/100mg
38182-65-9
10 suppliers
inquiry
Yield:38182-65-9 48.6%
Reaction Conditions:
with acetamide;potassium carbonate at 200; for 1 h;
Steps:
2.4 Step 4: 2,9-diamino-1,10-phenanthroline
2,9-dichloro-1,10-phenanthroline (747 mg, 3 mmol), acetamide (4.73 g, 80 mmol), potassium carbonate (3.87 g, 28 mmol), and heated to 200 ° C, stirred for 1 hour, dropped to room temperature, add water (30 mL) to the reaction and extract with dichloromethane. The organic phase was collected, dried over anhydrous sodium sulfate and filtered. The organic phase was removed by concentration under reduced pressure. The residue was subjected to silica gel column chromatography to give 2,9-diamino-1,10-phenanthroline 306 mg (1.46 mmol, 48.6%).
References:
CN109776532,2019,A Location in patent:Paragraph 0026; 0031; 0032
66-71-7
400 suppliers
$6.00/5g
38182-65-9
10 suppliers
inquiry
7089-68-1
155 suppliers
$50.00/25mg
38182-65-9
10 suppliers
inquiry
1891-19-6
12 suppliers
inquiry
38182-65-9
10 suppliers
inquiry
1272970-40-7
0 suppliers
inquiry
38182-65-9
10 suppliers
inquiry