1-Chloro-3-(1-chloro-ethyl)-benzene synthesis
- Product Name:1-Chloro-3-(1-chloro-ethyl)-benzene
- CAS Number:34887-78-0
- Molecular formula:C8H8Cl2
- Molecular Weight:175.06
620-16-6
76 suppliers
$60.00/500mg
5182-43-4
11 suppliers
inquiry
34887-78-0
9 suppliers
$45.00/10mg
Yield:34887-78-0 71% ，5182-43-4 23 %Spectr.
Reaction Conditions:
with N-chloro-succinimide;benzophenone in acetonitrile at 27; for 9 h;Irradiation;regioselective reaction;
Steps:
4 General procedure for triplet ketone-catalyzed C(sp3)-H-chlorination
General procedure: To a 4 mL clear vial charged with the reaction substrate, N-chlorosuccinimide, ketone catalyst in anhydrous acetonitrile (0.2 M) was degassed and irradiated with a 19 W compact fluorescent lamp at room temperature for 24 h. The solvent was then removed and the residue was dissolved in diethyl ether, filtrated, concentrated and purified by preparative thin-layer chromatography.
References:
Han, Lei;Xia, Ji-Bao;You, Lin;Chen, Chuo [Tetrahedron,2017,vol. 73,# 26,p. 3696 - 3701]
2039-85-2
170 suppliers
$11.00/1g
34887-78-0
9 suppliers
$45.00/10mg
620-16-6
76 suppliers
$60.00/500mg
34887-78-0
9 suppliers
$45.00/10mg
108-90-7
671 suppliers
$10.00/25G
34887-78-0
9 suppliers
$45.00/10mg
108-37-2
364 suppliers
$6.00/10g
34887-78-0
9 suppliers
$45.00/10mg