1-(Furan-2-yl)-2,2-diMethylpropane-1,3-diol synthesis
- Product Name:1-(Furan-2-yl)-2,2-diMethylpropane-1,3-diol
- CAS Number:4946-64-9
- Molecular formula:C9H14O3
- Molecular Weight:170.21
98-01-1
500 suppliers
$22.00/25g
6651-34-9
59 suppliers
$168.00/10g
4946-64-9
18 suppliers
$483.00/1g
Yield:4946-64-9 73 % Spectr.
Reaction Conditions:
Stage #1: furfural;2-methyl-1-(trimethylsilyloxy)-1-propenewith lithium acetate in N,N-dimethyl-formamide at 20; for 16 h;
Stage #2: with hydrogenchloride in N,N-dimethyl-formamide at -45;
Stage #3: with sodium tetrahydroborate;sodium hydrogencarbonate in methanol;N,N-dimethyl-formamide at -45 - 20;
References:
Kawano, Yoshikazu;Fujisawa, Hidehiko;Mukaiyama, Teruaki [Chemistry Letters,2005,vol. 34,# 4,p. 614 - 615]
98-01-1
500 suppliers
$22.00/25g
78-84-2
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$10.00/25mL
4946-64-9
18 suppliers
$483.00/1g