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methyl 4-methyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzoate
methyl 4-methyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzoate synthesis
1synthesis methods
- Product Name:methyl 4-methyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzoate
- CAS Number:1147351-76-5
- Molecular formula:C15H21BO4
- Molecular Weight:276.14
Yield:1147351-76-5 99%
Reaction Conditions:
with [Ir(OMe)(COD)]2/tris[3,5-bis(CF3)phenyl]phosphine in octane;80°C, 16 h, benzoate ester (5.0 mmol), bis(pinacolato)diboron (1.0 mmol), (Ir(OMe)(COD))2 (0.015 mmol), tris(3,5-bis(trifluoromethyl)phenyl)phosphine (0.06 mmol);
References:
Ishiyama, Tatsuo;Isou, Hironori;Kikuchi, Takao;Miyaura, Norio [Chemical Communications,2010,vol. 46,# 1,p. 159 - 161]