Stannane, tributyl[1-[[(1,1-dimethylethyl)dimethylsilyl]oxy]ethenyl]- synthesis
1synthesis methods
- Product Name:Stannane, tributyl[1-[[(1,1-dimethylethyl)dimethylsilyl]oxy]ethenyl]-
- CAS Number:136201-90-6
- Molecular formula:C20H44OSiSn
- Molecular Weight:447.36
Yield: 63%
Reaction Conditions:
with N,N,N,N,N,N-hexamethylphosphoric triamide;lithium diisopropyl amide in tetrahydrofuranSn-compound added to LDA in THF (stirring, -78°C, under N2); temp. allowed to reach 0°C for 15 min; soln. cooled to -78°C; addn. of chlorotrimethylsilane; mixt. allowed to reach room temp.; HMPA added, quenching with water, extn. (pentane);
References:
Verlhac, Jean-Baptiste;Pereyre, Michel;Shin, HeeAn [Organometallics,1991,vol. 10,# 9,p. 3007 - 3009]