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ChemicalBook CAS DataBase List 2,1,3-Benzothiadiazole, 4-broMo-7-(2-thienyl)-
501434-74-8

2,1,3-Benzothiadiazole, 4-broMo-7-(2-thienyl)- synthesis

3synthesis methods
54663-78-4 Synthesis
2-(TRIBUTYLSTANNYL)THIOPHENE

54663-78-4
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$25.00/5g

2,1,3-Benzothiadiazole, 4-broMo-7-(2-thienyl)-

501434-74-8
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Yield:501434-74-8 66%

Reaction Conditions:

Stage #1: 4,7-dibromobenzo[c][1,2,5]thiadiazole;2-tri(n-butyl)stannylthiophenewith [1,1'-bis(diphenylphosphino)ferrocene]dichloropalladium(II) in toluene at 20; for 0.333333 h;Inert atmosphere;
Stage #2: in toluene; for 24 h;Reflux;Inert atmosphere;

References:

Shaker, Mohamed;Lee, Jong-Hoon;Trinh, Cuc Kim;Kim, Wonbin;Lee, Kwanghee;Lee, Jae-Suk [RSC Advances,2015,vol. 5,# 81,p. 66005 - 66012]