{2-[(4-Bromophenyl)dimethylsilyl]phenyl}methanol synthesis
- Product Name:{2-[(4-Bromophenyl)dimethylsilyl]phenyl}methanol
- CAS Number:947515-73-3
- Molecular formula:C15H17BrOSi
- Molecular Weight:321.28
106-37-6
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$9.00/5g
![1,1-DiMethyl-1,3-dihydrobenzo[c][1,2]oxasilole](/CAS/GIF/321903-29-1.gif)
321903-29-1
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$47.00/100mg
947515-73-3
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$75.00/100mg
Yield:947515-73-3 91%
Reaction Conditions:
Stage #1: 1.4-dibromobenzenewith n-butyllithium in hexane at -78; for 2 h;
Stage #2: 1,1-dimethyl-1,3-dihydrobenzo[c][1,2]oxasilole in tetrahydrofuran;hexane at -78 - 20;Further stages.;
References:
Nakao, Yoshiaki;Chen, Jinshui;Imanaka, Hidekazu;Hiyama, Tamejiro;Ichikawa, Yoshitaka;Duan, Wei-Liang;Shintani, Ryo;Hayashi, Tamio [Journal of the American Chemical Society,2007,vol. 129,# 29,p. 9137 - 9143]