2-(4-METHYLPHENYL)-1-(3-PYRIDINYL)-1-ETHANONE synthesis
- Product Name:2-(4-METHYLPHENYL)-1-(3-PYRIDINYL)-1-ETHANONE
- CAS Number:40061-21-0
- Molecular formula:C14H13NO
- Molecular Weight:211.26
350-03-8
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$10.00/5g
108-88-3
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$16.10/100ml
40061-21-0
23 suppliers
$187.00/100mg
Yield:40061-21-0 85%
Reaction Conditions:
Stage #1: toluenewith thianthrene-5-oxide;trifluoromethylsulfonic anhydride in acetonitrile at -20 - 20; for 0.666667 h;Inert atmosphere;Schlenk technique;
Stage #2: methyl-3-pyridylketonewith palladium diacetate;cesium fluoride;XPhos in N,N-dimethyl-formamide;acetonitrile at 80; for 11 h;Inert atmosphere;Schlenk technique;
References:
Huang, Yu-Hao;Nie, Xiao-Xue;Wang, Peng [Organic Letters,2020,vol. 22,# 19,p. 7716 - 7720] Location in patent:supporting information
93-60-7
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$8.00/25g
622-47-9
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$17.00/25g
40061-21-0
23 suppliers
$187.00/100mg