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ChemicalBook CAS DataBase List 2-(ChloroMethyl)-5-Methylpyridine hydrochloride
71670-70-7

2-(ChloroMethyl)-5-Methylpyridine hydrochloride synthesis

7synthesis methods
(5-methylpyridin-2-yl)methanol

22940-71-2

2-(ChloroMethyl)-5-Methylpyridine hydrochloride

71670-70-7

General procedure for the synthesis of 2-(chloromethyl)-5-methylpyridine hydrochloride from 2-(hydroxymethyl)-5-methylpyridine: (5-methylpyridin-2-yl)methanol (2-(hydroxymethyl)-5-methylpyridine) was dissolved in SOCl2 (10 mL) and the reaction was carried out at reflux for 30 min. After completion of the reaction, the mixture was concentrated and dried under vacuum to give 2-(chloromethyl)-5-methylpyridine hydrochloride (2.1 g, 91.3% yield) as a white solid.LCMS showed MH+ of 142.

22940-71-2 Synthesis
(5-methylpyridin-2-yl)methanol

22940-71-2
77 suppliers
$45.00/50mg

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Yield: 91.3%

Reaction Conditions:

with thionyl chloride for 0.5 h;Reflux;

Steps:

50.3 2-(chloromethyl)- -methylpyridine hydrochloride
2-(chloromethyl)- -methylpyridine hydrochloride A solution of (5-methylpyridin-2-yl)methanol in SOCl2 (10 mL) was refluxed 30 min. The mixture was concentrated and dried in vacuo to give 2-(chloromethyl)-5-methylpyridine hydrochloride (2. lg, 91.3% yield) as white solid. LCMS MH+ 142.

References:

HYDRA BIOSCIENCES, INC.;CHENARD, Bertrand;GALLASCHUN, Randall WO2014/143799, 2014, A2 Location in patent:Page/Page column 408; 409