ChemicalBook CAS DataBase List 2-METHYL-1-PHENYLPROPENE

2-METHYL-1-PHENYLPROPENE synthesis

11synthesis methods

Product Name:2-METHYL-1-PHENYLPROPENE
CAS Number:768-49-0
Molecular formula:C10H12
Molecular Weight:132.2

100-86-7
298 suppliers
$8.00/25g

768-49-0
109 suppliers
$18.00/100mg

Yield:768-49-0 80%

Reaction Conditions:

with aluminum (III) chloride;triphenylphosphine in nitromethane at 80; for 2 h;

Steps:

2.2. A typical alcohol dehydration procedure
General procedure: In a typical reaction, alcohol (0.4 mmol) was mixed with AlCl3 (0.02 mmol, 5 mol%) and triphenylphosphine (PPh3, 0.02 mmol, 5 mol%) in nitromethane (1.0 mL). Thereafter the mixture was stirred at 80 °C for 2 h. After the reaction, the mixture was cooled to room temperature, and the product was isolated using preparative thin layer chromatography (TLC, eluting solution: petroleum ether/ethyl acetate, 5/1 (v/v)). Tests for substrate scope were all performed with an analogous procedure.

References:

Liu, Changhui;Pan, Bin;Gu, Yanlong [Cuihua Xuebao/Chinese Journal of Catalysis,2016,vol. 37,# 6,p. 979 - 986]

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611-69-8 Synthesis