ChemicalBook CAS DataBase List 2-Propanethiol

2-Propanethiol synthesis

14synthesis methods

Product Name:2-Propanethiol
CAS Number:75-33-2
Molecular formula:C3H8S
Molecular Weight:76.16

2-Propanethiol is synthesised by the reaction of sodium hydrosulfide and brominated isopropane.

187737-37-7 Synthesis

187737-37-7
1 suppliers
inquiry

107-03-9
220 suppliers
$14.00/25mL

111-47-7
163 suppliers
$14.00/5g

625-80-9
95 suppliers
$12.00/1g

75-33-2
215 suppliers
$10.00/1g

Yield:-

Reaction Conditions:

with hydrogen sulfide at 160; under 1500.15 Torr;

Steps:

1
Hydrogen sulfide and propylene were mixed at a molar ratio of 1: 1, and pressurized at 0.2 MPa by the compressor, heated to 160 ° C by means of a heating furnace. The volume space velocity of propylene was 400 h-1, and solid acid catalyst was added into a thermally insulated fixed bed reactor. The catalyst used was composed of molybdenum oxide 1% by mass, cobalt oxide 1%, ZSM-5 molecular sieve 5%. The rest was alumina carrier. ZSM-5 molecular sieve has silica-alumina molar ratio of 10, grain size of 5μm. The catalyst pore volume was 0.4 ml / g. The specific surface area is 137 m2 / g.The reaction effluent was cooled to 25 ° C by heat transfer, hydrogen sulfide was fed into gas phase return, the liquid phase was fractionated to give isopropyl mercaptan, n-propanethiol, isopropyl sulfide and n-propyl sulfide four products, and has propylene conversion rate of 80.2%. The selectivity of isopropyl mercaptan was 89.4%, the total yield of isopropyl mercaptan was 87.6%.

References:

CHAMBROAD CHEMICAL INDUSTRY RESEARCH INSTITUTE CO.,LTD;GUO, ZHENLIAN;JIANG, XUELI;LI, SHOULI;MA, HUAN;LUAN, LIXIA;MOU, QINGPING;ZHANG, JIANLIN CN104496869, 2016, B Location in patent:Paragraph 0052; 0053

FullText

187737-37-7 Synthesis

187737-37-7
1 suppliers
inquiry

75-33-2
215 suppliers
$10.00/1g

References