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HYDROGEN SULFIDE

HYDROGEN SULFIDE
HYDROGEN SULFIDE
CAS No.
7783-06-4
Chemical Name:
HYDROGEN SULFIDE
Synonyms
H2S;sourgas;sewergas;Sour gas;Sewer gas;stinkdamp;Stink damp;Hepatic gas;Siarkowodor;Hepatic acid
CBNumber:
CB0122872
Molecular Formula:
H2S
Formula Weight:
34.08
MOL File:
7783-06-4.mol

HYDROGEN SULFIDE Properties

Melting point:
−85 °C(lit.)
Boiling point:
−60 °C(lit.)
Density 
dgas 1.19 (air = 1.00)
vapor density 
1.19 (15 °C, vs air)
vapor pressure 
252 psi ( 21 °C)
FEMA 
3779 | HYDROGEN SULFIDE
Flash point:
-17℃
storage temp. 
2-8°C
pka
7(at 25℃)
form 
colorless gas
Odor
Strong rotten egg odor detectable at 0.001 to 0.1 ppm (mean = 0.0094 ppm); olfactory fatigue occurs quickly at high concentrations
explosive limit
6%
Water Solubility 
1g dissolves in H2O: 187mL (10°C), 242mL (20°C), 314 (30°C) [MER06]
Merck 
13,4823
BRN 
3535004
Stability:
Stable. Highly flammable. May form explosive mixture with air. Note wide explosive limits. Incompatible with strong oxidizing agents, many metals. May react violently with metal oxides, copper, fluorine, sodium, ethanal.
CAS DataBase Reference
7783-06-4(CAS DataBase Reference)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  F+,T+,N,F
Risk Statements  12-26-50-40-36/37-19-11
Safety Statements  9-16-36-38-45-61-28-26
RIDADR  UN 1053 2.3
WGK Germany  2
RTECS  MX1225000
Autoignition Temperature 260 °C
HazardClass  2.3
Toxicity LC50 in mice, rats (ppm): 634, 712 (1 hr inhalation) (Vernot); LC50 in rats (ppm): 444 (4 hr inhalation) (Tansy)
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H220 Extremely flammable gas Flammable gases Category 1 Danger P210, P377, P381, P403
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H280 Contains gas under pressure; may explode if heated Gases under pressure Compressed gas
Liquefied gas
Dissolved gas
Warning P410+P403
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning P264, P270, P301+P312, P330, P501
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning P264, P280, P305+P351+P338,P337+P313P
H330 Fatal if inhaled Acute toxicity,inhalation Category 1, 2 Danger P260, P271, P284, P304+P340, P310,P320, P403+P233, P405, P501
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning
H351 Suspected of causing cancer Carcinogenicity Category 2 Warning P201, P202, P281, P308+P313, P405,P501
H400 Very toxic to aquatic life Hazardous to the aquatic environment, acute hazard Category 1 Warning P273, P391, P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P284 Wear respiratory protection.
P310 Immediately call a POISON CENTER or doctor/physician.
P370+P378 In case of fire: Use … for extinction.
P403+P235 Store in a well-ventilated place. Keep cool.
P410+P403 Protect from sunlight. Store in a well-ventilated place.

HYDROGEN SULFIDE price More Price(3)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 742546 Hydrogen sulfide solution 0.8 M in THF 7783-06-4 25ml $118 2018-11-20 Buy
Sigma-Aldrich 295442 Hydrogen sulfide ≥99.5% 7783-06-4 227g $450 2018-11-20 Buy
Sigma-Aldrich 742546 Hydrogen sulfide solution 0.8 M in THF 7783-06-4 100ml $277 2018-11-20 Buy

HYDROGEN SULFIDE Chemical Properties,Uses,Production

Chemical Properties

colourless gas with strong odour of rotten eggs (odour threshold ca 0.2 ppt)

Definition

ChEBI: A sulfur hydride consisting of s single sulfur atom bonded to two hydrogen atoms. A highly poisonous, flammable gas with a characteristic odour of rotten eggs, it is often produced by bacterial decomposition of organic matter in the absence of oxygen.

Uses

To produce elemental sulfur and sulfuric acid; in manufacture of heavy water and other chemicals; in metallurgy; as analytical reagent.

Air & Water Reactions

Highly flammable; a flame can very easily flash back to the source of leak. Soluble in water to a maximum of 0.4% by mass at room temperature .

Reactivity Profile

HYDROGEN SULFIDE reacts as an acid and as a reducing agent. Explodes on contact with oxygen difluoride, bromine pentafluoride, chlorine trifluoride, dichlorine oxide, silver fulminate. May ignite and explode when exposed to powdered copper in oxygen [Mertz, V. et al., Ber., 1880, 13, p. 722]. May react similarly with other powdered metals. Ignites on contact with metal oxides and peroxides (barium peroxide, chromium trioxide, copper oxide, lead dioxide, manganese dioxide, nickel oxide, silver oxide, silver dioxide, thallium trioxide, sodium peroxide, mercury oxide, calcium oxide) [Mellor, 1947, vol. 10, p. 129, 141]. Ignites with silver bromate, lead(II) hypochlorite, copper chromate, nitric acid, lead(IV) oxide and rust. May ignite if passed through rusty iron pipes [Mee, A. J., School Sci. Rev., 1940, 22(85), p. 95]. Reacts exothermically with bases. The heat of the reaction with soda lime, sodium hydroxide, potassium hydroxide, barium hydroxide may lead to ignition or explosion of the unreacted portion in the presence of air / oxygen [Mellor, 1947, vol. 10, p. 140].

Hazard

Highly flammable, dangerous fire risk, explosive limits in air 4.3–46%. Toxic by inhalation, strong irritant to eyes and mucous membranes.

Health Hazard

Exposure to very high concentrations causes immediate death. Also death or permanent injury may occur after very short exposure to small quantities. It acts directly upon the nervous system resulting in paralysis of respiratory centers.

Health Hazard

The acute toxicity of hydrogen sulfide by inhalation is moderate. A 5-min exposure to 800 ppm has resulted in death. Inhalation of 1000 to 2000 ppm may cause coma after a single breath. Exposure to lower concentrations may cause headache, dizziness, and upset stomach. Low concentrations of H2S (20 to 150 ppm) can cause eye irritation, which may be delayed in onset. Although the odor of hydrogen sulfide is detectable at very low concentrations, it rapidly causes olfactory fatigue at higher levels, and therefore is not considered to have adequate warning properties. Hydrogen sulfide has not been shown to be carcinogenic or to have reproductive or developmental effects in humans

Fire Hazard

Compound is heavier than air and may travel a considerable distance to source of ignition and flash back. HYDROGEN SULFIDE forms explosive mixtures with air over a wide range. Also reacts explosively with bromine pentafluoride, chlorine trifluoride, nitrogen triiodide, nitrogen trichloride, oxygen difluoride, and phenyl diazonium chloride. When heated to decomposition, HYDROGEN SULFIDE emits highly toxic fumes of oxides of sulfur. Incompatible with many materials including strong oxidizers, metals, strong nitric acid, bromine pentafluoride, chlorine trifluoride, nitrogen triiodide, nitrogen trichloride, oxygen difluoride and phenyl diazonium chloride. Avoid physical damage to containers; sources of ignition; storage near nitric acid, strong oxidizing materials, and corrosive liquids or gases.

Fire Hazard

Hydrogen sulfide is flammable in air in the range of 4.3 to 45.5% (NFPA rating = 4). Combustion products (sulfur oxides) are also toxic by inhalation. In the event of a hydrogen sulfide fire, stop the flow of gas if possible without risk of harmful exposure and let the fire burn itself out.

Agricultural Uses

Hydrogen sulphide (H2S) is a colorless, poisonous, flammable gas with an odor of rotting eggs. It is found in cesspools and mines and is a by-product of decomposed substances containing sulphur. It is one of the gaseous end-products of the reduction of sulphate in highly degraded paddy fields. Hydrogen sulphide is also produced in the laboratory for use as an analytical reagent.

storage

cylinders of hydrogen sulfide should be stored and used in a continuously ventilated gas cabinet or fume hood. Local fire codes should be reviewed for limitations on quantity and storage requirements.

Purification Methods

Wash it, then pass the gas through a train of tubes containing saturated Ba(OH)2 (2x), water (2x), and dilute HCl [Goates et al. J Am Chem Soc 73 707 1951]. It is available in gas cylinders. HIGHLY POISONOUS.

Incompatibilities

Hydrogen sulfide is incompatible with strong oxidizers. It will attack many metals, forming sulfides. Liquid hydrogen sulfide will attack some forms of plastics, rubber, and coatings. H2S reacts violently with a variety of metal oxides, including the oxides of chromium, mercury, silver, lead, nickel, and iron.

Flammability and Explosibility

Hydrogen sulfide is flammable in air in the range of 4.3 to 45.5% (NFPA rating = 4). Combustion products (sulfur oxides) are also toxic by inhalation. In the event of a hydrogen sulfide fire, stop the flow of gas if possible without risk of harmful exposure and let the fire burn itself out.

Waste Disposal

To respond to a release, use appropriate protective equipment and clothing. Positive pressure air-supplied respiratory protection is required. Close cylinder valve and ventilate area. Remove cylinder to a fume hood or remote area if it cannot be shut off. Disposal Excess hydrogen sulfide should be returned to the manufacturer, according to your institution's waste disposal guidelines. For more information on disposal procedures, see Chapter 7 of this volume.

HYDROGEN SULFIDE Preparation Products And Raw materials

Raw materials

Preparation Products


HYDROGEN SULFIDE Suppliers

Global( 41)Suppliers
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HYDROGEN SULFIDE Spectrum


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