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18162-48-6872-50-4Methylene ChloridenaphthaleneTHFTitanium Dioxide
ChemicalBook CAS DataBase List 2-(Trimethylsilyl)ethanol
2916-68-9

2-(Trimethylsilyl)ethanol synthesis

11synthesis methods
Three methods of preparation have been reported: (a) from the treatment of ethyl bromoacetate with zinc followed by the reaction with chlorotrimethylsilane1 and subsequent reduction of the resultant ethyl trimethylsilylacetate with lithium aluminum hydride2,3 or borane–tetrahydrofuran(eq 1); (b) from the hydroboration/oxidation or oxymercuration/demercuration of vinyltrimethylsilane (eq 2); and (c)most conveniently, by the reaction of the Grignard reagent formed from (chloromethyl)trimethylsilane with paraformaldehyde (eq 3).

Ethyl (trimethylsilyl)acetate

4071-88-9
152 suppliers
$21.00/1g

2-(Trimethylsilyl)ethanol

2916-68-9
335 suppliers
$13.00/5g

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Yield:2916-68-9 78.1%

Reaction Conditions:

with borane-THF in tetrahydrofuran for 48 h;Ambient temperature;

References:

Rosowsky, Andre;Wright, Joel E. [Journal of Organic Chemistry,1983,vol. 48,# 9,p. 1539 - 1541]

FullText

9-Borabicyclo[3.3.1]nonane, 9-[2-(trimethylsilyl)ethyl]-

72610-05-0
0 suppliers
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2-(Trimethylsilyl)ethanol

2916-68-9
335 suppliers
$13.00/5g

CIS-1,5-CYCLOOCTANEDIOL

23418-82-8
20 suppliers
$205.00/10g

References
Ethyl trimethylacetate

3938-95-2
165 suppliers
$12.00/25g

2-(Trimethylsilyl)ethanol

2916-68-9
335 suppliers
$13.00/5g

References
Vinyltrimethylsilane

754-05-2
248 suppliers
$11.00/1g

1-(TRIMETHYLSILYL)ETHANOL, 98

13246-39-4
5 suppliers
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2-(Trimethylsilyl)ethanol

2916-68-9
335 suppliers
$13.00/5g

References
METHYL (TRIMETHYLSILYL)ACETATE

2916-76-9
74 suppliers
$45.00/1g

2-(Trimethylsilyl)ethanol

2916-68-9
335 suppliers
$13.00/5g

References

2-(Trimethylsilyl)ethanol Related Search:

Ethyl acetate Vinyltrimethoxysilane Ethanol Benzyltrimethylammonium chloride allyltrimethylammonium chloride TRIMETHYLSULFOXONIUM CHLORIDE 2-(METHYLDIPHENYLSILYL)ETHANOL 2-(Trimethylsilyl)ethoxymethyl chloride 3-(TRIMETHYLSILYL)-1,2-PROPANEDIOL 2-(TRIMETHYLSILYL)ETHOXYMETHYLTRIPHENYLPHOSPHONIUM CHLORIDE