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ChemicalBook CAS DataBase List (Z)-1-(2,6,6-trimethyl-2-cyclohexen-1-yl)-2-buten-1-one

(Z)-1-(2,6,6-trimethyl-2-cyclohexen-1-yl)-2-buten-1-one synthesis

4synthesis methods
Oxirane, 2-(1-bromoethyl)-3-(2,6,6-trimethyl-2-cyclohexen-1-yl)-

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(Z)-1-(2,6,6-trimethyl-2-cyclohexen-1-yl)-2-buten-1-one

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-

Yield:-

Steps:

Multi-step reaction with 2 steps
1: 91 percent / Zn, CuI / aq. ethanol / 1.5 h / sonication
2: 1.) MnO2; 2.) p-TsOH / 1.) CH2Cl2, 17 h; 2.) THF, reflux, 4 h

References:

Sarandeses, Luis A.;Luche, Jean-Louis [Journal of Organic Chemistry,1992,vol. 57,# 9,p. 2757 - 2760]