
(6S)-6-[[tert-ButyldiMethylsilyloxy]-1,3,4,5,6,7-hexahydro-1-[(E)-[(1R,3aS,7aR)-octahydro-1-[(1S)-2-iodo-1-Methylethyl]-7a-Methyl-4H-inden-4-ylidene]Methyl]benzo[c]thiophene 2,2-Dioxide synthesis
- Product Name:(6S)-6-[[tert-ButyldiMethylsilyloxy]-1,3,4,5,6,7-hexahydro-1-[(E)-[(1R,3aS,7aR)-octahydro-1-[(1S)-2-iodo-1-Methylethyl]-7a-Methyl-4H-inden-4-ylidene]Methyl]benzo[c]thiophene 2,2-Dioxide
- CAS Number:344798-32-9
- Molecular formula:C28H47IO3SSi
- Molecular Weight:618.73
![2-{4-[6-(tert-Butyl-dimethyl-silanyloxy)-2,2-dioxo-2,3,4,5,6,7-hexahydro-1H-2l6-benzo[c]thiophen-1-ylmethylene]-7a-methyl-octahydro-inden-1-yl}-propan-1-ol](/CAS/GIF/344798-31-8.gif)
344798-31-8
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![(6S)-6-[[tert-ButyldiMethylsilyloxy]-1,3,4,5,6,7-hexahydro-1-[(E)-[(1R,3aS,7aR)-octahydro-1-[(1S)-2-iodo-1-Methylethyl]-7a-Methyl-4H-inden-4-ylidene]Methyl]benzo[c]thiophene 2,2-Dioxide](/CAS/20200515/GIF/344798-32-9.gif)
344798-32-9
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Yield:344798-32-9 71%
Reaction Conditions:
with 1H-imidazole;iodine;triphenylphosphine in dichloromethane;1.) 5 deg C, 0.5 h, 2.) room temperature, 2.0 h;
References:
Manchand, Percy S.;Yinnikouros, George P.;Belica, Peter S.;Madan, Pradeep [Journal of Organic Chemistry,1995,vol. 60,# 20,p. 6574 - 6581]
![tert-Butyl-dimethyl-{3-[7a-methyl-1-(1,4,5-trimethyl-hex-2-enyl)-octahydro-inden-4-ylidenemethyl]-2,2-dioxo-2,3,4,5,6,7-hexahydro-1H-2l6-benzo[c]thiophen-5-yloxy}-silane](/CAS/GIF/170081-43-3.gif)
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![(6S)-6-[[tert-ButyldiMethylsilyloxy]-1,3,4,5,6,7-hexahydro-1-[(E)-[(1R,3aS,7aR)-octahydro-1-[(1S)-2-iodo-1-Methylethyl]-7a-Methyl-4H-inden-4-ylidene]Methyl]benzo[c]thiophene 2,2-Dioxide](/CAS/20200515/GIF/344798-32-9.gif)
344798-32-9
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18162-48-6
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$9.00/5g
![(6S)-6-[[tert-ButyldiMethylsilyloxy]-1,3,4,5,6,7-hexahydro-1-[(E)-[(1R,3aS,7aR)-octahydro-1-[(1S)-2-iodo-1-Methylethyl]-7a-Methyl-4H-inden-4-ylidene]Methyl]benzo[c]thiophene 2,2-Dioxide](/CAS/20200515/GIF/344798-32-9.gif)
344798-32-9
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50-14-6
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$28.00/1g
![(6S)-6-[[tert-ButyldiMethylsilyloxy]-1,3,4,5,6,7-hexahydro-1-[(E)-[(1R,3aS,7aR)-octahydro-1-[(1S)-2-iodo-1-Methylethyl]-7a-Methyl-4H-inden-4-ylidene]Methyl]benzo[c]thiophene 2,2-Dioxide](/CAS/20200515/GIF/344798-32-9.gif)
344798-32-9
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87680-65-7
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![(6S)-6-[[tert-ButyldiMethylsilyloxy]-1,3,4,5,6,7-hexahydro-1-[(E)-[(1R,3aS,7aR)-octahydro-1-[(1S)-2-iodo-1-Methylethyl]-7a-Methyl-4H-inden-4-ylidene]Methyl]benzo[c]thiophene 2,2-Dioxide](/CAS/20200515/GIF/344798-32-9.gif)
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