2,2-DiMethyl-propanoic Acid [(1R,5S)-4-Hydroxy-6,6-diMethylbicyclo[3.1.1]hept-2-en-2-yl]Methyl Ester synthesis
- Product Name:2,2-DiMethyl-propanoic Acid [(1R,5S)-4-Hydroxy-6,6-diMethylbicyclo[3.1.1]hept-2-en-2-yl]Methyl Ester
- CAS Number:374559-42-9
- Molecular formula:C15H24O3
- Molecular Weight:252.35
![2,2-DIMETHYL-PROPIONIC ACID (1R,5R)-6,6-DIMETHYL-4-OXO-BICYCLO[3.1.1]HEPT-2-EN-2-YLMETHYL ESTER](/CAS/GIF/76163-96-7.gif)
76163-96-7
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374559-42-9
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Yield:374559-42-9 91%
Reaction Conditions:
with sodium tetrahydroborate in ethanol at 20;
Steps:
1.3
4-Oxo-myrtenyl pivalate (Ig, 4mmol) was dissolved in ethanol (15ml). NaBH4 (0.2g, 5.3mmol) was added slowly and the resulting suspension was stirred at room temperature for 15 min. The ethanol was evaporated, then ether and water were added. The organic layer was separated, dried and evaporated to give a colorless oil (0.92g, 91%).
References:
WO2010/41253,2010,A1 Location in patent:Page/Page column 21
19894-97-4
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374559-42-9
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3282-30-2
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374559-42-9
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76163-95-6
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374559-42-9
8 suppliers
$165.00/25mg