ChemicalBook CAS DataBase List 4-Trimethylsilanylaniline

4-Trimethylsilanylaniline synthesis

9synthesis methods

Product Name:4-Trimethylsilanylaniline
CAS Number:17889-23-5
Molecular formula:C9H15NSi
Molecular Weight:165.31

4405-33-8 Synthesis

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Yield:17889-23-5 94%

Reaction Conditions:

with hydrogen;palladium 10% on activated carbon in ethanol; under 760.051 Torr;

Steps:

3; 5.B

4- (Trimethylsilyl) aniline 4-(Trimethylsilyl)-1-nitrobenzene, Ex 5, Step A (1.63 g, 8.35 mmol) dissolved in ethanol (50 ml) was added 5% palladium on charcoal (500 mg, 0.23 mmol), and stirred under 1 atm of hydrogen pressure overnight. The mixture was then filtered through a pad of Celite and concentrated under reduced pressure, giving 1.3 g (94%) of the title compound.

References:

WO2005/80328,2005,A1 Location in patent:Page/Page column 12; 34