Cyclohexanemethanol, 4-ethenyl-2-hydroxy-α,α,4-trimethyl-5-(1-methylethenyl)-, (1S,2S,4S,5S)- synthesis

2synthesis methods

Product Name:Cyclohexanemethanol, 4-ethenyl-2-hydroxy-α,α,4-trimethyl-5-(1-methylethenyl)-, (1S,2S,4S,5S)-
CAS Number:64373-81-5
Molecular formula:C15H26O2
Molecular Weight:238.37

6902-91-6
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Cyclohexanemethanol, 4-ethenyl-2-hydroxy-α,α,4-trimethyl-5-(1-methylethenyl)-, (1S,2S,4S,5S)-

64373-81-5
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Yield:-

Steps:

Multi-step reaction with 4 steps
1: bis(benzonitrile)palladium(II) dichloride / toluene / 1 h / Reflux; Inert atmosphere
2: dihydrogen peroxide; sodium hydroxide / methanol; water / 9 h / -45 - 20 °C
3: acetic acid; zinc / tetrahydrofuran / 5 h / 50 °C
4: ammonia; lithium / diethyl ether; ethanol / 0.17 h / -35 °C / Inert atmosphere

References:

Barrero, Alejandro F.;Herrador, M. Mar;Quilez Del Moral, Jose F.;Arteaga, Pilar;Meine, Niklas;Perez-Morales, M. Carmen;Catalan, Julieta V. [Organic and Biomolecular Chemistry,2011,vol. 9,# 4,p. 1118 - 1125]

[4S,(+)]-2-Isopropylidene-4β-isopropenyl-5α-vinyl-5-methylcyclohexanone

20303-60-0
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64373-81-5
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References