7-HYDROXYHEPTANOIC ACID synthesis
- Product Name:7-HYDROXYHEPTANOIC ACID
- CAS Number:3710-42-7
- Molecular formula:C7H14O3
- Molecular Weight:146.18
629-30-1
270 suppliers
$8.00/1g
3710-42-7
87 suppliers
$24.00/100mg
Yield:3710-42-7 76%
Reaction Conditions:
with dihydrogen peroxide;sodium hydroxide in water at 79.84; for 8 h;Schlenk technique;
Steps:
2.3. Catalytic testing
General procedure: All experiments to test the catalytic activity were performed in a Schlenk tube (50mL vol.) attached to a condenser. The catalytic activity was evaluated for HDO oxidation in basic aqueous media with H2O2 as oxidant to obtain HCA. In a typical reaction procedure, aliphatic diol (0.5mmol) and catalyst (25mg) were weighed and dispersed in deionized water (3.5mL) in a Schenk tube. 30% H2O2 (0.75mL) and 0.5M NaOH (0.75mL) were added to the above mixture, and then the Schlenk tube was mounted on a preheated oil bath at 353K. The mixture was allowed to react for various time intervals with continuous magnetic stirring (500 rpm). After the reaction, a part of the resultant solution was diluted 20 times with an aqueous H2SO4 (10mM) solution, and the catalyst was filtered off using a 0.20μm filter (Milex-LG). The obtained filtrate was analyzed by high performance liquid chromatography (HPLC, WATERS 600) using an Aminex HPX-87H column (Bio-Rad Laboratories, Inc.) attached to a refractive index detector. An aqueous 10mM H2SO4 solution (eluent) was run through the column (maintained at 323K) at a flow rate of 0.5mLmin-1. The conversion and yield(s) were determined with a calibration curve method using commercial products.
References:
Tuteja, Jaya;Nishimura, Shun;Ebitani, Kohki [Catalysis Today,2016,vol. 265,p. 231 - 239]
13175-44-5
80 suppliers
$45.00/50mg
3710-42-7
87 suppliers
$24.00/100mg
539-87-7
14 suppliers
inquiry
3710-42-7
87 suppliers
$24.00/100mg
4286-55-9
303 suppliers
$15.00/10g
124-38-9
130 suppliers
$175.00/23402
3710-42-7
87 suppliers
$24.00/100mg
502-42-1
219 suppliers
$10.00/1g
3710-42-7
87 suppliers
$24.00/100mg