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ChemicalBook CAS DataBase List tert-butyl 3-tert-butylpiperazine-1-carboxylate hydrochloride
886779-61-9

tert-butyl 3-tert-butylpiperazine-1-carboxylate hydrochloride synthesis

4synthesis methods
39684-80-5 Synthesis
tert-Butyl N-(2-bromoethyl)carbamate

39684-80-5
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tert-butyl 3-tert-butylpiperazine-1-carboxylate hydrochloride

886779-61-9
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Yield:-

Steps:

Multi-step reaction with 5 steps
1.1: N,N-dimethyl-formamide / 24 h / 20 °C
2.1: sodium hydride / N,N-dimethyl-formamide / 0 - 20 °C
2.2: 6 h / 0 - 20 °C
3.1: hydrazine / ethanol / 0.33 h / Reflux
4.1: dichloromethane / 20 °C / Molecular sieve; Inert atmosphere
5.1: 2,6-dimethylpyridine; copper(II) bis(trifluoromethanesulfonate) / dichloromethane / 12 h / 20 °C / Inert atmosphere

References:

Luescher, Michael U.;Vo, Cam-Van T.;Bode, Jeffrey W. [Organic Letters,2014,vol. 16,# 4,p. 1236 - 1239]

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