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6236-71-1

Bicyclo[2.2.1]heptane-2,3-dione synthesis

2synthesis methods
-

Yield:278-74-0 64 % Turnov.

Reaction Conditions:

with dihydrogen peroxide;dmtacn Mn complex immobilized on amorphous SiO2 in acetonitrile at -0.15; for 5 h;Epoxidation;dihydroxylation;

References:

De Vos, Dirk E.;De Wildeman, Stefaan;Sels, Bert F.;Grobet, Piet J.;Jacobs, Pierre A. [Angewandte Chemie - International Edition,1999,vol. 38,# 7,p. 980 - 983]