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ChemicalBook CAS DataBase List Boron nitride

Boron nitride synthesis

8synthesis methods
Boron nitride is prepared by heating boric oxide with ammonia:
B2O3 + 2NH3 → 2BN + 3H2O
Alternatively, the compound can be prepared by heating boric oxide or boric acid with ammonium chloride or an alkali metal cyanide. Purified product can be obtained by high temperature reaction of boron halide with ammonia:
BCl3 + NH3 → BN + 3HCl
Boron nitride can also be made from the elements by heating boron and nitrogen at red heat.
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Yield:10043-11-5 99%

Reaction Conditions:

with multi-walled carbon nanotubes in solid;byproducts: CO, H2, H2O; mixt. of multi-walled carbon nanotubes and H3BO3 taken in quartz tube, NH3 gas passed through with 10 sccm flow rate at 200 °C 2 h, temp.slowly raised to 1000 °C for 3 h;

References:

Deepak;Vinod;Mukhopadhyay;Govindaraj;Rao [Chemical Physics Letters,2002,vol. 353,# 5-6,p. 345 - 352]

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