| Identification | More | [Name]
Stannic chloride pentahydrate | [CAS]
10026-06-9 | [Synonyms]
STANNIC CHLORIDE
STANNIC CHLORIDE 5H2O
STANNIC CHLORIDE, 5-HYDRATE
STANNIC CHLORIDE PENTAHYDRATE
Tetrachloro-stannane
TIN (IV) CHLORIDE
TIN(IV) CHLORIDE 5H2O
TIN(IV) CHLORIDE-5-HYDRATE
TIN(IV) CHLORIDE PENTAHYDRATE
TIN TETRACHLORIDE PENTAHYDRATE
Stannane,tetrachloro-,pentahydrate
stannicchloride,crystal
tetrachlorostannanepentahydrate
tin(iv)chloride,pentahydrate(1:4:5)
Stannic chloride hydrated
Stonmicchloride pentaihgdrate
Tin tetrachloride hydrated
Tin(Ⅳ) chloride pentahydrate
Tin(IV) chloride hydrate
TIN(IV) CHLORIDE-5-HYDRATE EXTRA PURE | [EINECS(EC#)]
231-588-9 | [Molecular Formula]
Cl4H10O5Sn | [MDL Number]
MFCD00149864 | [Molecular Weight]
350.6 | [MOL File]
10026-06-9.mol |
| Chemical Properties | Back Directory | [Appearance]
Stannic chloride is a white to yellow powder with a faint odor of HCl. | [Melting point ]
56 °C
| [density ]
2.040 | [solubility ]
very soluble in H2O; soluble in ethanol | [form ]
lumps
| [color ]
Light Yellow | [Stability:]
Stable, but may decompose in contact with moisture or water. Incompatible with strong acids. | [Water Solubility ]
soluble | [Merck ]
14,8774 | [InChIKey]
KHMOASUYFVRATF-UHFFFAOYSA-J | [Uses]
Substitute for anhydrous stannic chloride where the presence of water is not objectionable | [CAS DataBase Reference]
10026-06-9(CAS DataBase Reference) | [EPA Substance Registry System]
10026-06-9(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
C | [Risk Statements ]
R34:Causes burns.
R52/53:Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S7/8:Keep container tightly closed and dry .
S61:Avoid release to the environment. Refer to special instructions safety data sheet . | [RIDADR ]
UN 2440 8/PG 3
| [WGK Germany ]
3
| [RTECS ]
XP8870000
| [HazardClass ]
8 | [PackingGroup ]
III | [HS Code ]
28273990 | [Safety Profile]
A poison by
intraperitoneal and intravenous routes.
Mutation data reported. A corrosive liquid.
When heated to decomposition it emits
toxic vapors of tin and Cl-. |
| Hazard Information | Back Directory | [General Description]
Stannic chloride pentahydrate is a white colored solid. STANNIC CHLORIDE, PENTAHYDRATE(10026-06-9) is soluble in water. STANNIC CHLORIDE, PENTAHYDRATE(10026-06-9) is toxic by ingestion, inhalation and skin absorption. STANNIC CHLORIDE, PENTAHYDRATE(10026-06-9) is used to make perfumes and dyes. | [Reactivity Profile]
Acidic salts, such as STANNIC CHLORIDE, are generally soluble in water. The resulting solutions contain moderate concentrations of hydrogen ions and have pH's of less than 7.0. They react as acids to neutralize bases. These neutralizations generate heat, but less or far less than is generated by neutralization of inorganic acids, inorganic oxoacids, and carboxylic acid. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible. Many of these compounds catalyze organic reactions. | [Air & Water Reactions]
Soluble in water. Reacts with water to form Hydrochloric Acid in dense white fumes [Merck 11th ed. 1989]. | [Hazard]
Toxic material | [Health Hazard]
TOXIC; inhalation, ingestion or skin contact with material may cause severe injury or death. Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution. | [Potential Exposure]
Hydrated stannic chloride is used for fixing certain textile dyes, and for treating silk to give weight to the fabric. | [Fire Hazard]
Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.). Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. | [First aid]
Move victim to fresh air. Call 911 or emergency medical service. Give artificial respiration if victim is not breathing. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Administer oxygen if breathing is difficult. Remove and isolate contaminated clothing and shoes. In case of contact with substance, immediately flush skin or eyes with running water for at least 20 minutes. For minor skin contact, avoid spreading material on unaffected skin. Keep victim warm and quiet. Effects of exposure (inhalation, ingestion, or skin contact) to substance may be delayed. Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves. Medical observation is recommended for 24 to 48 hours after breathing overexposure, as pulmonary edema may be delayed. As first aid for pulmonary edema, a doctor or authorized paramedic may consider administering a drug or other inhalation therapy. | [Shipping]
UN2440 Stannic chloride, pentahydrate, Hazard class: 8; Labels: 8-Corrosive material. | [Incompatibilities]
Reacts violently with water, forming corrosive hydrochloric acid and tin oxide fumes. Reacts with turpentine, alcohols, and amines, causing fire and explosion hazard. Attacks many metals; some forms of plastics, rubber, and coatings. Reacts with moist air to form hydrochloric acid and dense white fume. | [Chemical Properties]
Stannic chloride is a white to yellow powder with a faint odor of HCl. | [Chemical Properties]
White solid. Soluble in water or alcohol. |
| Questions And Answer | Back Directory | [Physical Properties]
Colorless fuming liquid; corrosive; density 2.234 g/mL; freezes at –33°C; boils at 114.15°C; critical temperature 318.75°C; critical pressure 37.98 atm; critical volume 351 cm3/mol; soluble in cold water, evolving heat; decomposed by hot water; soluble in alcohol, benzene, toluene, chloroform, acetone and kerosene.
The pentahydrate is a yellowish-white crystalline solid or small, fused lumps; faint odor of HCl; density 2.04 g/cm3; decmposes at 56°C; very soluble in water; soluble in ethanol.
| [Uses]
Tin(IV) chloride is a mordant for dying fabrics; a stabilizer for perfume in soap; used in weighting silk; in ceramic coatings; in manufacturing blue print papers; and to produce fuchsin. Also, tin(IV) chloride is used in preparing many organotin compounds.
| [Preparation]
Tin(IV) chloride is prepared by reacting tin or tin(II) chloride with chlorine:
Sn + 2Cl2 → SnCl4
SnCl2 + Cl2 → SnCl4
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