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103-03-7

103-03-7 Structure

103-03-7 Structure
IdentificationMore
[Name]

1-PHENYLSEMICARBAZIDE
[CAS]

103-03-7
[Synonyms]

1-CARBAMYL-2-PHENYLHYDRAZINE
1-PHENYLSEMICARBAZIDE
CRYOGENINE
KRYOGENIN
1-carbamoyl-2-phenyl-hydrazin
1-Carbamoyl-2-phenylhydrazine
1-Phenylhydrazinecarboxamide
2-phenyldiazenecarboxamide
2-Phenylhydrazide carbamic acid
2-phenylhydrazide,carbamicacid
2-phenyl-hydrazinecarboxamid
2-phenylhydrazinecarboxamide
Carbamic acid, 2-phenylhydrazide
carbamicacid,2-phenylhydrazide
Carbaphen
Cryogenine (pharmaceutical)
cryogenine(pharmaceutical)
Febrimin
Fenylsemikarbazid
Hydrazine, 1-carbamoyl-2-phenyl-
[EINECS(EC#)]

203-072-3
[Molecular Formula]

C7H9N3O
[MDL Number]

MFCD00007942
[Molecular Weight]

151.17
[MOL File]

103-03-7.mol
Chemical PropertiesBack Directory
[Melting point ]

171-174 °C (lit.)
[Boiling point ]

273.17°C (rough estimate)
[density ]

1.2100 (rough estimate)
[refractive index ]

1.5860 (estimate)
[storage temp. ]

Keep in dark place,Inert atmosphere,Room temperature
[solubility ]

acetone: very soluble(lit.)
[form ]

powder to crystal
[pka]

11.16±0.43(Predicted)
[color ]

White to Light yellow
[BRN ]

743311
[CAS DataBase Reference]

103-03-7(CAS DataBase Reference)
[IARC]

3 (Vol. 12, Sup 7) 1987
[EPA Substance Registry System]

Phenicarbazide (103-03-7)
Safety DataBack Directory
[Hazard Codes ]

Xn
[Risk Statements ]

R22:Harmful if swallowed.
[Safety Statements ]

S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
[WGK Germany ]

3
[RTECS ]

FD0575000
[TSCA ]

Yes
[HS Code ]

29280090
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Urea-->NITROSOPHENYLUREA-->Hydrazinecarboxamide, 2-(1-methylethylidene)-1-phenyl--->ethyl cyanate-->1,5-Diphenylcarbazide-->3,5-DIMETHYLPYRAZOLE-1-CARBOXAMIDE-->4-Fluorobenzhydrazide-->Urethane-->Phenylhydrazine hydrochloride-->PHENYLURETHANE-->1-Methyl-1-nitrosourea-->Phenylhydrazine
[Preparation Products]

Triazophos-->3-Hydroxy-1-phenyl-1,2,4-triazole
Hazard InformationBack Directory
[Uses]

1-Phenylsemicarbazide was used in the synthesis of a series of alkyl(aryl/heteroaryl) substituted 3-trifluoromethyl-1H-1-phenylpyrazoles and alkyl 3-carboxylate analogs by the cyclocondensation reactions with 4-alkoxy-1,1,1-trihaloalk-3-en-2-ones.
[Definition]

ChEBI: Phenicarbazide is a member of phenylhydrazines.
[Brand name]

Antipyretic dellepsoids d26.
[World Health Organization (WHO)]

Phenicarbazide, which has analgesic and antipyretic activity, was introduced in the 1970s. It has been withdrawn in at least one country on grounds of its adverse effect profile and it appears to have fallen into disuse in others.
[Purification Methods]

Crystallise it from water and dry it in a vacuum over KOH. [Beilstein 15 H 287, 15 II 106, 15 III 184, 15 IV 180.]
Spectrum DetailBack Directory
[Spectrum Detail]

1-PHENYLSEMICARBAZIDE(103-03-7)MS
1-PHENYLSEMICARBAZIDE(103-03-7)13CNMR
1-PHENYLSEMICARBAZIDE(103-03-7)IR1
1-PHENYLSEMICARBAZIDE(103-03-7)IR2
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

1-Phenylsemicarbazide, 99%(103-03-7)
[Alfa Aesar]

1-Phenylsemicarbazide, 99%(103-03-7)
[Sigma Aldrich]

103-03-7(sigmaaldrich)
[TCI AMERICA]

1-Phenylsemicarbazide,>98.0%(T)(103-03-7)
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