| Identification | More | [Name]
2-(Trifluoromethyl)benzyl bromide | [CAS]
395-44-8 | [Synonyms]
2-(TRIFLUOROMETHYL)BENZYL BROMIDE
ALPHA'-BROMO-ALPHA,ALPHA,ALPHA-TRIFLUORO-O-XYLENE
O-(TRIFLUOROMETHYL)BENZYL BROMIDE
TIMTEC-BB SBB006692
Benzene, 1-(bromomethyl)-2-(trifluoromethyl)-
α′-Bromo-α,α,α-trifluoro-o-xylene
1-(bromomethyl)-2-(trifluoromethyl)benzene
à'-bromo-à,à,à-trifluoro-o-xylene
2-(Trifluoromethyl)benzyl bromide 98%
2-(Trifluoromethyl)benzylbromide98%
a'-Bromo-a,a,a-trifluoro-o-xylene | [EINECS(EC#)]
206-901-7 | [Molecular Formula]
C8H6BrF3 | [MDL Number]
MFCD00013558 | [Molecular Weight]
239.03 | [MOL File]
395-44-8.mol |
| Chemical Properties | Back Directory | [Appearance]
Colorless to light yellow liqui | [Melting point ]
34-35 °C
| [Boiling point ]
72 °C (7.5 mmHg)
| [density ]
1.571 g/mL at 25 °C(lit.) | [refractive index ]
1.496-1.499
| [Fp ]
83 °C
| [storage temp. ]
Inert atmosphere,2-8°C | [form ]
powder to lump to clear liquid | [color ]
White or Colorless to Light yellow | [Specific Gravity]
1.571 | [Sensitive ]
Lachrymatory | [BRN ]
2256977 | [InChIKey]
TXVVVEUSVBLDED-UHFFFAOYSA-N | [CAS DataBase Reference]
395-44-8(CAS DataBase Reference) | [NIST Chemistry Reference]
2-Trifluoromethylbenzyl bromide(395-44-8) |
| Safety Data | Back Directory | [Hazard Codes ]
C,Xi | [Risk Statements ]
R34:Causes burns. | [Safety Statements ]
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S25:Avoid contact with eyes .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . | [RIDADR ]
1760 | [WGK Germany ]
3 | [Hazard Note ]
Corrosive/Lachrymatory | [HazardClass ]
8 | [PackingGroup ]
III | [HS Code ]
29039990 |
| Hazard Information | Back Directory | [Chemical Properties]
Colorless to light yellow liqui | [Preparation]
A solution of 30 ml of phosphorus tribromide in 60 ml of absolute toluene was added dropwise at 20°-30° C. to a solution of 14 g of o-trifluoromethylbenzyl alcohol in 80 ml of absolute toluene. Subsequently, the reaction mixture was stirred at room temperature for 2 hours, the toluene was distilled under reduced pressure, the residue was dissolved in methylene chloride, treated with water and the mixture was adjusted to pH 8.0 with potassium hydrogen carbonate. The aqueous phase was extracted three times with CH2Cl2 and the organic phases were washed twice with water and once with saturated NaCl solution, dried over Na2 SO4 and evaporated under reduced pressure. 2-(Trifluoromethyl)benzyl bromide was obtained as the residue. |
|
|