ChemicalBook--->CAS DataBase List--->620-40-6

620-40-6

620-40-6 Structure

620-40-6 Structure
IdentificationMore
[Name]

Tribenzylamine
[CAS]

620-40-6
[Synonyms]

AURORA KA-4701
N,N-Bis(phenylmethyl)benzenemethanamine
N,N,N-TRIBENZYLAMINE
TRIBENZYLAMINE
Benzenemethanamine,N,N-bis(phenylmethyl)-
n,n-bis(phenylmethyl)-benzenemethanamin
N,N-Dibenzyl(phenyl)methanamine
TRIBENZYLAMINE 99+%
(N,N-Dibenzylaminomethyl)benzene
N,N-Bisbenzylbenzenemethanamine
N,N-Dibenzylbenzenemethaneamine
[EINECS(EC#)]

210-638-3
[Molecular Formula]

C21H21N
[MDL Number]

MFCD00004773
[Molecular Weight]

287.4
[MOL File]

620-40-6.mol
Chemical PropertiesBack Directory
[Appearance]

white to light cream powder
[Melting point ]

91-94 °C (lit.)
[Boiling point ]

380-390 °C
[density ]

0.991g/cm3
[vapor pressure ]

0Pa at 25℃
[refractive index ]

1.8240 (estimate)
[Fp ]

>230 °F
[storage temp. ]

Store below +30°C.
[form ]

Powder
[pka]

6.90±0.50(Predicted)
[color ]

White to light cream
[PH]

6.5-9.0 (10g/l, H2O, 20℃)suspension
[Water Solubility ]

insoluble
[Sensitive ]

Air Sensitive
[BRN ]

2214682
[InChIKey]

MXHTZQSKTCCMFG-UHFFFAOYSA-N
[LogP]

4.313 (est)
[CAS DataBase Reference]

620-40-6(CAS DataBase Reference)
[NIST Chemistry Reference]

Benzenemethanamine, N,N-bis(phenylmethyl)-(620-40-6)
[EPA Substance Registry System]

620-40-6(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

Xi,Xn
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
R22:Harmful if swallowed.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S37/39:Wear suitable gloves and eye/face protection .
[RIDADR ]

1325
[WGK Germany ]

3
[F ]

9-34
[TSCA ]

Yes
[HazardClass ]

4.1
[PackingGroup ]

III
[HS Code ]

29214980
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Benzamide,N,N-bis(phenylmethyl)--->N,N-dibenzyl-1-phenylmethanamine oxide-->Benzaldehyde-->Benzyl chloride-->Benzonitrile-->Dibenzylamine-->Benzyl alcohol
[Preparation Products]

ROKITAMYCIN
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

N,N-Bis(phenylmethyl)benzenemethanamine(620-40-6).msds
Hazard InformationBack Directory
[Chemical Properties]

white to light cream powder
[Uses]

Tribenzylamine (TBA) is a tertiary amine which can be used :
  • As a nitrogen group source for the reactions involving C?N bond formation.
  • For the synthesis of imine i.e. N?benzylidene benzylamine by aerobic oxidative condensation.
  • As an extractant for the separation and determination of Cr(VI) and Cr(III) from wastewater.

TBA can also undergo debenzylation in the presence of ceric ammonium nitrate (CAN) to form dibenzylamine.
[Synthesis Reference(s)]

The Journal of Organic Chemistry, 46, p. 1759, 1981 DOI: 10.1021/jo00321a056
Tetrahedron Letters, 21, p. 3385, 1980 DOI: 10.1016/S0040-4039(00)78695-3
[Flammability and Explosibility]

Notclassified
[Purification Methods]

Crystallise the amine from absolute EtOH or pet ether. Dry it in a vacuum over P2O5 at room temperature. The hydrochloride has m 226-228o (from EtOH) and the picrate has m 191o (from H2O or aqueous EtOH). [Beilstein 12 IV 2183.]
Spectrum DetailBack Directory
[Spectrum Detail]

Tribenzylamine(620-40-6)MS
Tribenzylamine(620-40-6)IR1
Tribenzylamine(620-40-6)IR2
Tribenzylamine(620-40-6)IR3
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Tribenzylamine, 99+%(620-40-6)
[Alfa Aesar]

Tribenzylamine, 99+%(620-40-6)
[Sigma Aldrich]

620-40-6(sigmaaldrich)
[TCI AMERICA]

Tribenzylamine,>99.0%(GC)(T)(620-40-6)
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