| Identification | More | [Name]
3-Chloro-4-methylaniline | [CAS]
95-74-9 | [Synonyms]
1-AMINO-3-CHLORO-4-METHYLBENZENE
2-CHLORO-4-AMINOTOLUENE
2-CHLORO-4-TOLUIDINE
3-amino-2-chlorotoluene
3-CHLORO-4-METHYLANILINE
3-chloro-4-methyl-benzenamine
3-CHLORO-P-TOLUIDINE
3-cpt
4-AMINO-2-CHLOROTOLUENE
AKOS BBS-00003549
CPT
O-CHLORO-P-TOLUIDINE
OCPT
TIMTEC-BB SBB004152
1-amino-3-chloro-4-methylenzene[qr]
2-chloro-4-aminotoluene[qr]
3-chloro-4-methylaniline[qr]
3-chloro-4-methyl-benzenamin
3-chloro-4-methylbenzenamine[qr]
3-chloro-p-toluidin | [EINECS(EC#)]
202-446-3 | [Molecular Formula]
C7H8ClN | [MDL Number]
MFCD00007773 | [Molecular Weight]
141.6 | [MOL File]
95-74-9.mol |
| Chemical Properties | Back Directory | [Appearance]
The chloromethylanilines are colorless or
white crystalline solids or liquids, some have a mild
fishy odor. | [Melting point ]
25 °C | [Boiling point ]
237-238 °C(lit.)
| [density ]
1.17 | [refractive index ]
n20/D 1.584(lit.)
| [Fp ]
212 °F
| [storage temp. ]
2-8°C | [pka]
pK1: 4.05(+1) (25°C) | [Specific Gravity]
1.167 | [Stability:]
Stable. Combustible. Incompatible with strong oxidizing agents, acid chlorides, acids, acid anhydrides, chloroformates, reducing agents. | [Water Solubility ]
1 g/L (20 ºC) | [BRN ]
636511 | [CAS DataBase Reference]
95-74-9(CAS DataBase Reference) | [NIST Chemistry Reference]
Benzenamine, 3-chloro-4-methyl-(95-74-9) | [EPA Substance Registry System]
95-74-9(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
T,N,Xn | [Risk Statements ]
R24/25:Toxic in contact with skin and if swallowed .
R36/38:Irritating to eyes and skin .
R43:May cause sensitization by skin contact.
R50/53:Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
R36/37/38:Irritating to eyes, respiratory system and skin .
R22:Harmful if swallowed. | [Safety Statements ]
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
S60:This material and/or its container must be disposed of as hazardous waste .
S36/37:Wear suitable protective clothing and gloves .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . | [RIDADR ]
UN 2239 6.1/PG 3
| [WGK Germany ]
2
| [RTECS ]
XU5111000
| [TSCA ]
Yes | [HazardClass ]
6.1 | [PackingGroup ]
III | [HS Code ]
29214300 | [Safety Profile]
Poison by ingestion,
intravenous, and intraperitoneal routes.
Mutation data reported. When heated to
decomposition it emits toxic fumes of Cl
and NOx. See also other chloro toluidme
entries. | [Hazardous Substances Data]
95-74-9(Hazardous Substances Data) |
| Hazard Information | Back Directory | [General Description]
Brown solid with a mild odor. | [Reactivity Profile]
3-CHLORO-P-TOLUIDINE(95-74-9) may be sensitive to prolonged exposure to air and light. This chemical may react with oxidizing agents. 3-CHLORO-P-TOLUIDINE(95-74-9) is incompatible with acids, acid chlorides, acid anhydrides and chloroformates. 3-CHLORO-P-TOLUIDINE(95-74-9) is also incompatible with reducing agents. | [Air & Water Reactions]
May be sensitive to prolonged exposure to air and light. Insoluble in water. | [Potential Exposure]
Most of the isomers are used in dyestuff manufacture. The 3-chloro-para isomer is used to kill
birds. It is marketed as pelleted bait for control of bird
populations. | [Fire Hazard]
This chemical is combustible. | [First aid]
If this chemical gets into the eyes, remove any
contact lenses at once and irrigate immediately for at least
15 minutes, occasionally lifting upper and lower lids. Seek
medical attention immediately. If this chemical contacts the
skin, remove contaminated clothing and wash immediately
with soap and water. Seek medical attention immediately.
If this chemical has been inhaled, remove from exposure,
begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if
heart action has stopped. Transfer promptly to a medical
facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce
vomiting. Do not make an unconscious person vomit.
| [Shipping]
UN2239 Chlorotoluidines, solid, Hazard Class:
6.1; Labels: 6.1-Poisonous materials. UN3429
Chlorotoluidines, liquid, Hazard Class: 6.1; Labels: 6.1-
Poisonous materials | [Incompatibilities]
Incompatible with oxidizers, strong
acids; chloroformates, and acid anhydrides, isocyanates,
aldehydes forming fire and explosive hazards. | [Chemical Properties]
brown solid | [Chemical Properties]
The chloromethylanilines are colorless or
white crystalline solids or liquids, some have a mild
fishy odor. | [Uses]
2-Chloro-4-aminotoluene has been used in the preparation of 2-chloro-4-cyanotoluene by Sandmeyer reaction with cuprous cyanide. | [Definition]
ChEBI: A monochloroaniline that is p-toluidine in which one of the hydrogens that is meta to the amino group is replaced by a chlorine. |
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