Tricyclo[3.3.1.13,7]decan-1-ol

Tricyclo[3.3.1.13,7]decan-1-ol Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:

R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.

S-Sätze Betriebsanweisung:

S22:Staub nicht einatmen.
S24/25:Berührung mit den Augen und der Haut vermeiden.
S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.

Beschreibung

1-Adamantanol is a cyclic molecule with a hydroxyl group. It is produced by the oxidation of 2-methyl-2-adamantanol. 1-Adamantanol has been shown to be an effective substrate for bioremediation in wastewater treatment plants and can be used as a precursor to produce trifluoroacetic acid.

Chemische Eigenschaften

white to off-white crystalline powder or needles

Verwenden

1-Adamantanol was used in the preparation of 1,3-adamantanediol. It is used in the manufacture of synthetic adamantane derivatives and adapalene.

läuterung methode

If 2-adamantanol is a suspected impurity, then dissolve the substance (10g) in acetone (100mL) and add Jones's reagent [CrO3 (10.3g) in H2O (30mL)], then conc H2SO4 (8.7mL) is added dropwise (turns green in colour) until excess reagent is present (slight red colour). Stir overnight, decant the acetone solution from the Cr salts and adamantan-2-one, dry (Na2SO4) and evaporate to dryness. The residue (ca 7g) is chromatographed through Al2O3 (250g) and washed with 50% *benzene/pet ether (b 40-60o), then 100% Et2O (to remove any adamantan-2-one present) and the 1-adamantanol is then eluted with 5% MeOH in Et2O. The eluate is evaporated, and the residue is recrystallised from pet ether (b 30-60o) at -70o, m 287.2-288.5o. It also crystallises from MeOH and can be sublimed in vacuo. It has characteristic IR, max 3640, 1114, 1086, 982 and 930cm-1. [Schleyer & Nicholas J Am Chem Soc 83 182 1961.] [Beilstein 6 IV 391.] Alternatively, if free from the 2-isomer, dissolve it in tetrahydrofuran, dilute with H2O to precipitate the alcohol. Collect, dry and sublime it in a vacuum at 130o. [Stetter et al. Chem Ber 92 1629 1959.]

Tricyclo[3.3.1.13,7]decan-1-ol Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte

Tricyclo[3.3.1.13,7]decan-1-ol Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

Firmenname	Telefon	E-Mail	Land	Produktkatalog	Edge Rate
Chengdu Yuanda Chemical Co., Ltd	28-85356300 +8618980937689	sales@ydachem.com	CHINA	94	58
Nanjing Shunxiang Pharmaceutical Technology Co.,Ltd.	+86-86-02586819868 +8613913839793	sales@jinchemical.com	China	23	58
Huzhou Chenxi Environmental Protection Technology Co. , Ltd.	+8616762203950	1034385273@qq.com	China	27	58
Hebei Mojin Biotechnology Co., Ltd	+8613288715578	sales@hbmojin.com	China	12456	58
Hebei Yanxi Chemical Co., Ltd.	+8617531190177	peter@yan-xi.com	China	5993	58
Shaanxi Haibo Biotechnology Co., Ltd	+undefined18602966907	qinhe02@xaltbio.com	China	1000	58
hebei hongtan Biotechnology Co., Ltd	+86-86-1913198-3935 +8617331935328	sales03@chemcn.cn	China	951	58
Capot Chemical Co.,Ltd.	571-85586718 +8613336195806	sales@capotchem.com	China	29797	60
Shanghai Daken Advanced Materials Co.,Ltd	+86-371-66670886	info@dakenam.com	China	15933	58
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21691	55

768-95-6(Tricyclo[3.3.1.13,7]decan-1-ol)Verwandte Suche:

---

• TRICYCLO[3.3.1.1(3,7)]DECAN-1-OL
• TRICYCLO[3.3.1.1]DECAN-1-OL
• 1-HYDROXYDIAMANTANE
• 1-ADA-OH
• 1-ADAMANTANOL
• 1-Adamatanol
• -Adamantyl alcohol
• damantol-(1)
• tricyclo(3.3.1.1(sup3,7))decan-1-ol
• ADAMANTANOL, 1-
• AKOS BC-0650
• 1-Adamantonal
• 1-Adamantanol,98%
• LABOTEST-BB LT00436924
• ADAMANTANOL, 1-(SG)
• (1-Adamantyl) alcohol
• Adamantan-3-ol
• Hydroxyadamantane
• 1-Adamantanol,99%
• Tricyclo[3,3,1,1]3,7 decanol-1
• adamantan-1-ol(SALTDATA: FREE)
• 1-AdaMantanol, 99% 5GR
• 1-ADAMANTANOL FOR SYNTHESIS 10 G
• Adapalene IMpurity H
• Adamantan-1-ol, Tricyclo[3.3.1.1~3,7~]decan-1-ol
• 1-Adamantanol Vetec(TM) reagent grade, 98%
• Tricyclo(3.3.1.1(sup 3,7))decan-1-ol (9CI)
• 1-AdaMantanol ReagentPlus(R), 99%
• 1 - adaMantane alcohol
• 1-Adamanthanol/Adamantan-1-ol
• 1-Adamantano
• 1 Adamentanol (768-95-6)
• 1-Adamantanol >
• 1-HYDROXYADAMANTANE
• 1-AD-OH
• 1-Adamantol
• ADAMANTANOL
• ADAMANTAN-1-OL
• 1-Admantanol
• (3s,5s,7s)-adamantan-1-ol
• 1-Adamantanol (6CI, 7CI, 8CI)
• 1-HYDROXY ADAMANTANE (1-adamantanol)
• HYDROXY ADAMANTANE (1-ADAMANTANOL)
• 768-95-6
• C9 to C30
• Alcohols
• Building Blocks
• Oxygen Compounds
• Organic Building Blocks
• Adamantanes
• Alcohols
• Building Blocks
• C9 to C10
• Chemical Synthesis
• Organic Building Blocks
• Oxygen Compounds
• FINE Chemical & INTERMEDIATES
• Adamantane derivatives