1,5-Diphenyl-3-thiocarbazon
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- CAS-Nr.
- 60-10-6
- Bezeichnung:
- 1,5-Diphenyl-3-thiocarbazon
- Englisch Name:
- Dithizone
- Synonyma:
- DIPHENYLTHIOCARBAZONE;dithizon;Dithizone (min. 98%);1,5-diphenyl-3-thiocarbazone;(E)-1,5-diphenylthiocarbazone;Diazenecarbothioic acid, 2-phenyl-, 2-phenylhydrazide;Ditizon;DITHIZONE;usafek-3092;DITHIZONE(P)
- CBNumber:
- CB5753569
- Summenformel:
- C13H12N4S
- Molgewicht:
- 256.33
- MOL-Datei:
- 60-10-6.mol
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1,5-Diphenyl-3-thiocarbazon Eigenschaften
- Schmelzpunkt:
- 168 °C (dec.) (lit.)
- Siedepunkt:
- 376.1±25.0 °C(Predicted)
- Dichte
- 1.2578 (rough estimate)
- Brechungsindex
- 1.5700 (estimate)
- storage temp.
- no restrictions.
- Löslichkeit
- Chloroform (Slightly), DMSO (Slightly), Methanol (Slightly)
- pka
- pK1:4.50;pK2:15 (25°C)
- Aggregatzustand
- Crystalline
- Farbe
- Black powder
- Wasserlöslichkeit
- Soluble in ethanol, chloroform, dimethylsulfoxide, and pyridine. Insoluble in water.
- Merck
- 14,3377
- BRN
- 748838
- Stabilität:
- Stable. Incompatible with strong oxidizing agents.
- CAS Datenbank
- 60-10-6(CAS DataBase Reference)
- EPA chemische Informationen
- Diazenecarbothioic acid, phenyl-, 2-phenylhydrazide (60-10-6)
1,5-Diphenyl-3-thiocarbazon Chemische Eigenschaften,Einsatz,Produktion Methoden
R-Sätze Betriebsanweisung:
R22:Gesundheitsschädlich beim Verschlucken.
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
S-Sätze Betriebsanweisung:
S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
Chemische Eigenschaften
dark brown or black crystals
Verwenden
Dithizone is an organosulfur compound that acts as a chelating agent and forms complexes with metals such as lead and mercury. Dithizone is used to assess the purity of human pancreatic islet preparations used for transplantation into patients with type 1 diabetes.
Allgemeine Beschreibung
Dithizone (Diphenylthiocarbazone) is used as chelating agent for zinc. It is widely used for the liquid-liquid and solid phase extraction of various metals since it forms stable complexes with the metals.
läuterung methode
The crude dithizone is dissolved in CCl4 to give a concentrated solution. This is filtered through a sintered glass funnel and shaken with 0.8M aqueous ammonia to extract dithizonate ion. The aqueous layer is washed with several portions of CCl4 to remove undesirable materials. The aqueous layer is acidified with dilute H2SO4 to precipitate pure dithizone. This is dried in a vacuum. When only small amounts of dithizone are required, purification by paper chromatography is convenient. [Cooper & Hibbits J Am Chem Soc 75 5084 1933.] Instead of CCl4, CHCl3 can be used, and the final extract, after washing with water, can be evaporated in air at 40-50o and dried in a desiccator. It complexes with Cd, Hg, Ni and Zn. [Beilstein 16 H 26, 16 IV 18.]
1,5-Diphenyl-3-thiocarbazon Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
1,5-Diphenyl-3-thiocarbazon Anbieter Lieferant Produzent Hersteller Vertrieb Händler.
Global( 348)Lieferanten
60-10-6(1,5-Diphenyl-3-thiocarbazon)Verwandte Suche:
- Diazenecarbothioicacid,phenyl-,2-phenylhydrazide
- diphenylthio-carbazon
- diphenylthiocarbazone(dithizone)
- phenylazo-thioformicaciphenylhydrazide
- phenyl-diazenecarbothioicaci2-phenylhydrazide
- Phenyldiazinecarbothioicacid2-phenylhydrazide
- usafek-3092
- Dithizone,Diphenylthiocarbazone
- DIPHENYLTHIOCARBAZONE, REAG
- Dithizone ACS Diphenylthiocarbazone ACS
- DITHIZONE FOR ANALYSIS (1,5-DIPHENYLT
- N',2-Diphenyldiazenecarbothiohydrazide 98+%
- Dithizone ACS reagent, >=85.0%
- Dithizone Practical Grade
- Dithizone puriss. p.a., ACS reagent, for spectrophotometric det. of Cd, Cu, Hg, Pb, Zn, >=99.0% (CHN)
- Dithizone, ACS, 85.0% min.
- N',2-Diphenyldiazenecarbothiohydrazide
- LABOTEST-BB LT00452751
- 3-anilino-1-phenylimino-thiourea
- DITHIZONE(P)
- Ditizon
- DITHIZONE REAGENT (ACS)
- FORMICACID,(PHENYLAZO)THIO-,2-PHENYLHYDRAZIDE
- DIPHENYLTHLOCARBAZONE
- DITHIZONE
- DITHIZONE STANDARD SOLUTION
- DITHIZONE, STOCK SOLUTION I
- 1,5-DIPHENYLTHIOCARBAZONE
- DIPHENYLTHIOCARBAZONE, A.C.S. REAGENT
- DITHIZONE R. G., REAG. PH. EUR.
- DITHIZONE, ACS
- DithizoneGr98-100%
- DithizoneA.R.
- Dithizone-(1,5-Diphenylthiocarbazone)
- Dithizone,ACS,85+%
- Dithizone,98%
- Dithizone, Reagent
- (Phenylazo)(2-phenylhydrazono)methanethiol
- Diphenylthiocarbazone,for analysis ACS
- DITHIZONE(RG)(CALL)
- TIMTEC-BB SBB008744
- ZERENEX ZX005906
- (phenylazo)thio-formicaci2-phenylhydrazide
- (Phenylazo)thioformicacid2-phenylhydrazzide
- 1,5-diphenyl-3-formazanthio
- 1-phenyl-4-(phenylimino)-3-thio-semicarbazid
- (PHENYLAZO)THIOFORMIC ACID 2-PHENYLHYDRAZIDE
- DITHIZONE Extra Pure
- 1-anilino-3-phenyliminothiourea
- 3-(phenylamino)-1-(phenylimino)thiourea
- Dithizone (SQ), Qualigens
- Dithizone pure, 70%
- Dithizone extrapure AR, ACS, ExiPlus, Multi-Compendial, 85%
- Dithizone extrapure AR, 85%
- Dithizone, for analysis (1,5-diphenylthiocarbazone) Reag.
- Diphenylthiocaxbazone
- Dithizone,>85%
- Dithizone, 78%, for analysis
