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4-Fluoracetophenon

4-Fluoroacetophenone Struktur
403-42-9
CAS-Nr.
403-42-9
Bezeichnung:
4-Fluoracetophenon
Englisch Name:
4-Fluoroacetophenone
Synonyma:
1-(4-Fluorophenyl)ethan-1-one;1-(4-FLUOROPHENYL)ETHANONE;4-Fluoracetophenon;P-FLUOROACETOPHENONE;4'-FLUOROACETOPHENONE;p-Fluoro;AKOS BBS-00003234;Fluoroacetophenone3;4-FLUOROCETOPHENONE;4-FLUOROACETOPHENONE
CBNumber:
CB6419110
Summenformel:
C8H7FO
Molgewicht:
138.14
MOL-Datei:
403-42-9.mol
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4-Fluoracetophenon Eigenschaften

Schmelzpunkt:
4 °C
Siedepunkt:
77-78 °C10 mm Hg(lit.)
Dichte
1.143 g/mL at 20 °C(lit.)
Brechungsindex
n20/D 1.511(lit.)
Flammpunkt:
160 °F
storage temp. 
Sealed in dry,Room Temperature
Löslichkeit
Chloroform, Ethyl Acetate
Aggregatzustand
Liquid
Wichte
1.138
Farbe
Clear colorless to slightly yellow
BRN 
386013
InChIKey
ZDPAWHACYDRYIW-UHFFFAOYSA-N
CAS Datenbank
403-42-9(CAS DataBase Reference)
NIST chemische Informationen
Ethanone, 1-(4-fluorophenyl)-(403-42-9)
EPA chemische Informationen
4'-Fluoroacetophenone (403-42-9)
Sicherheit
  • Risiko- und Sicherheitserklärung
  • Gefahreninformationscode (GHS)
Kennzeichnung gefährlicher Xi
R-Sätze: 36/37/38
S-Sätze: 26-36-23
WGK Germany  3
TSCA  T
HazardClass  IRRITANT
HS Code  29147090
Bildanzeige (GHS) GHS hazard pictograms
Alarmwort Warnung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H227 Combustible liquid Flammable liquids Category 4 Warnung P210, P280, P370+P378, P403+P235,P501
H315 Verursacht Hautreizungen. Hautreizung Kategorie 2 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P280, P302+P352, P321,P332+P313, P362
H319 Verursacht schwere Augenreizung. Schwere Augenreizung Kategorie 2 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P280, P305+P351+P338,P337+P313P
H335 Kann die Atemwege reizen. Spezifische Zielorgan-Toxizität (einmalige Exposition) Kategorie 3 (Atemwegsreizung) Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" />
Sicherheit
P261 Einatmen von Staub vermeiden.
P305+P351+P338 BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen. Eventuell vorhandene Kontaktlinsen nach Möglichkeit entfernen. Weiter spülen.
P405 Unter Verschluss aufbewahren.

4-Fluoracetophenon Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:

R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.

S-Sätze Betriebsanweisung:

S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.
S23:Gas/Rauch/Dampf/Aerosol nicht einatmen(geeignete Bezeichnung(en) vom Hersteller anzugeben).

Chemische Eigenschaften

Clear colorless to slightly yellow liquid

Verwenden

4-Fluoroacetophenone can be used as organic synthesis intermediates and pharmaceutical intermediates, mainly used in laboratory research and development processes and chemical production processes.

Synthese

Synthesis_403-42-9
General procedure: Oximes (1.0 mmol), Amberlyst-15 (0.02 g), FPA53-NO2(0.02 g), and solvent (1.5 mL) were introduced into a 25-cm-high, 90-mL autoclave with a glass tube inside equipped with magnetic stirrer (Scheme 2). Then the autoclave was charged with oxygen to 0.1 MPa. The reaction mixture was stirred at desirable temperature for special time. Progress of the reaction was monitored by thin-layer chromatography (TLC) or gas chromatography (GC). After the reaction, the resin (Amberlyst-15 and FPA53-NO2) was separated from the reaction mixture by filtration and extracted with 3 mL CH3CN (2 1.5 ml). The solvent was removed under reduced pressure. The residue was further purified by column chromatography on silica gel (300 mesh) with hexane/ethyl acetate to give the corresponding carbonyl compounds.

4-Fluoracetophenon Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte

2-(4-FLUOROPHENYL)-1H-INDOLE-3-CARBALDEHYDE Piperazin-4-ylacetophenon 2-(4-FLUOROBENZOYL)-1-BENZOFURAN-5-CARBALDEHYDE ETHYL 2-AMINO-4-(4-FLUOROPHENYL)THIOPHENE-3-CARBOXYLATE 4-(4-Fluorophenyl)pyrimidine-2-thiol 4-Fluorophenylacetylene 4'-Phenoxyacetophenone 4-Fluor-α-methylbenzylamin 5-(4-FLUOROPHENYL)-3H-THIENO[2,3-D]PYRIMIDIN-4-ONE 2-Brom-1-(4-fluorphenyl)ethan-1-on ALPHA,ALPHA-DIBROMO-4-FLUOROACETOPHENONE 6-(4-FLUOROPHENYL)INDOLE 4-FLUOROBENZOYLACETONITRILE 3-(4-FLUOROPHENYL)-1H-PYRAZOLE-4-CARBALDEHYDE 5-(4-Fluorophenyl)thiophene-2-carboxylic acid 1-(4-Fluorophenyl)-3-(2-thienyl)-2-propen-1-one/alpha-(2-Thienylidene)-4-fluoroacetophenone 2-(4-FLUOROPHENYL)QUINOLINE

4-Fluoracetophenon Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

Global( 632)Lieferanten
Firmenname Telefon E-Mail Land Produktkatalog Edge Rate
Nanjing Sinoda Biological Technology Co., Ltd
+8613401983379
 sales@njmcn.cn CHINA 74 58
Changzhou Ditong Chemical Co.,Ltd
+86-0519-88299272
info@edengenechem.com China 2169 58
Shanghai Longyu Biotechnology Co., Ltd.
+8615821988213
 info@longyupharma.com China 2531 58
Handan Tongyi New Material Technology Co., Ltd
+8617330042575
 ty003@handantongyi.com China 364 58
Hebei Guanlang Biotechnology Co,.LTD 		+8619930503252
 daisy@crovellbio.com China 5964 58
Firsky International Trade (Wuhan) Co., Ltd 		+8615387054039
 admin@firsky-cn.com China 436 58
Henan Fengda Chemical Co., Ltd 		+86-371-86557731 +86-13613820652
 info@fdachem.com China 7845 58
Wuhan Xinhao Biotechnology Co., Ltd 		+86-18120578002 +86-18120578002
 xinhao-6@xinhaoshengwu.com China 350 58
Ouhuang Engineering Materials (Hubei) Co., Ltd 		+8617702722807
 admin@hbouhuang.com China 2259 58
Frapp's ChemicalNFTZ Co., Ltd. 		+86 (576) 8169-6106
sales@frappschem.com China 885 50

403-42-9(4-Fluoracetophenon)Verwandte Suche:

4-Methylacetophenon 4'-Nitroacetophenon 1-[4-(Trifluormethyl)phenyl]ethan-1-on 1-[4-(β-D-Glucopyranosyloxy)phenyl]ethan-1-on 2-Bromacetophenon Acetophenon 3'-Nitroacetophenon 4'-Hydroxyacetophenon 4-Fluorpropiophenon 4'-Fluorbutyrophenon 4-(4-Chlorphenyl)-1-[4-(4-fluorphenyl)-4-oxobutyl]-4-piperidyldecanoat 4-Fluorbenzylalkohol 4-Fluoranisol 4-Fluorphenylessigsaeure o-Mercaptophenol Carboxyferrocen p-(Methylsulfonyl)toluol 2-(4-Fluorbenzoyl)benzoesure
  • Acetophenone, 4'-fluoro-
  • para-Fluoroacetophenone
  • 4-FLUOROCETOPHENONE
  • 4-FLUOROACETOPHENONE
  • AKOS BBS-00003234
  • Fluoroacetophenone color less liq
  • Fluoroacetophenone3
  • 4'-Fluoroacetophenone 1-(4-Fluorophenyl)ethan-1-one 1-(4-Fluorophenyl)ethanone
  • 4-Fluoroacetophenone,99%
  • LABOTEST-BB LT01148215
  • p-Fluoro
  • 4'-Fluoroacetophenone 99%
  • Ethanone, 1-(4-fluorophenyl)-
  • 1-(4-fluorophenyl)-ethanon
  • 1-Acetyl-4-fluorobenzene
  • 4-Acetylphenyl fluoride
  • Methyl 4-fluorophenyl ketone
  • 4-Acetylfluorobenzene
  • 4-Fluorophenyl Methyl ketone
  • 4-Fluorophenylethanal
  • Methyl 4-fluorophenyl
  • Of Fluoroacetophenone
  • 1-(4-Fluorophenyl)ethan-1-one, 1-(4-Fluorophenyl)-1-oxoethane
  • The fluorine acetophenone
  • p-Fluorophenyl methyl ketone
  • 4'-Fluoroacetophenone>
  • 4'-Fluoroacetophenone, 99%, for synthesis
  • Haloperidol Decanoate EP Impurity L
  • Haloperidol Decanoate Impurity 12（Haloperidol Decanoate EP Impurity L）
  • Lidocaine Pharmaceutical Drugs
  • Bromperidol decanoate EP Impurity L
  • TIANFU-CHEM 4-Fluoroacetophenone
  • 4-Fluoroacetophenone pure, 98%
  • P-FLUOROACETOPHENONE
  • 4'-FLUOROACETOPHENONE
  • 1-(4-Fluorophenyl)ethan-1-one
  • 1-(4-FLUOROPHENYL)ETHANONE
  • 4-Fluoracetophenon
  • Haloperidol EP Impurity L
  • Haloperidol Decanoate Impurity L
  • 4-FLOURO ACETOPHENONE
  • 4'-Fluoroacetophenone
  • 403-42-9
  • C7 to C8
  • Carbonyl Compounds
  • Building Blocks
  • Organic Building Blocks
  • Ketones
  • Adehydes, Acetals & Ketones
  • Fluorine Compounds
  • C7 to C8
  • Carbonyl Compounds
  • Ketones
  • Acetophenone series
  • Benzenes
  • Aromatic Acetophenones & Derivatives (substituted)
  • Organics
  • ketone
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