Kupfer(I)-chlorid Chemische Eigenschaften,Einsatz,Produktion Methoden
R-Sätze Betriebsanweisung:
R22:Gesundheitsschädlich beim Verschlucken.
R50/53:Sehr giftig für Wasserorganismen, kann in Gewässern längerfristig schädliche Wirkungen haben.
R51/53:Giftig für Wasserorganismen, kann in Gewässern längerfristig schädliche Wirkungen haben.
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
S-Sätze Betriebsanweisung:
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S61:Freisetzung in die Umwelt vermeiden. Besondere Anweisungen einholen/Sicherheitsdatenblatt zu Rate ziehen.
S60:Dieses Produkt und sein Behälter sind als gefährlicher Abfall zu entsorgen.
S22:Staub nicht einatmen.
Chemische Eigenschaften
white or pale grey powder
Physikalische Eigenschaften
White cubic crystal which turns blue when heated at 178°C; density 4.14 g/cm3; the mineral nantokite (CuCl) has density 4.14 g/cm3, hardness 2.5 (Mohs), refractive index 1.930; melts at 430°C becoming a deep, green liquid; vaporizes around 1,400°C; vapor pressure 5 torr at 645°C and 400 torr at 1250°C; low solubility in water (decomposes partially); Ksp 1.72x10-7; insoluble in ethanol and acetone; soluble in concentrated HCl and ammonium hydroxide.The space lattice of CuCl belongs to the cubic system, and its zinc-blende structure has a lattice
constant of a=0.541 nm and Cu–Cl=0.235 nm below 407°C, and it belongs to the hexagonal
system and has a wurtzite structure at 407°C–422°C.
The reflection peaks at room temperature are positioned at λ: 58 and 65.4 mm. The transmission
peak is located at λ: 18.5 mm. The absorption spectrum near the absorption edge λ: 370.0 nm at liquid He temperature shows
many structures because of exciton absorption.
Verwenden
Copper(I) chloride (CuCl) or cuprous chloride is a white powder used as an absorbing agent
for carbon dioxide gas in enclosed breathing areas such as space vehicles.
synthetische
Copper(I) chloride is prepared by reduction of copper(II) chloride in solution: 2CuCl2 + H2 2CuCl + 2HCl Alternatively, it can be prepared by boiling an acidic solution of copper(II) chloride with copper metal, which on dilution yields white CuCl: Cu + CuCl2 2CuCl Copper(I) chloride dissolved in concentrated HCl absorbs carbon monoxide under pressure forming an adduct, CuCl(CO). The complex decomposes on heating releasing CO. Copper(I) chloride is slightly soluble in water. However, in the presence of Cl- ion, it forms soluble complexes of discrete halogeno anions such as, CuCl2-, CuCl3 2-, and CuCl4 3-. Formation of complexes and organocopper derivatives as outlined below are not confined only to copper(I) chloride, but typify Cu+ in general. Reaction with ethylenediamine (en) in aqueous potassium chloride solution forms Cu(II)-ethylenediamine complex, while Cu+ ion is reduced to its metallic state: 2CuCl + 2en → [Cuen2]2+ + 2Cl- + Cu° It dissolves in acetonitrile, CH3CN forming tetrahedral complex ion [Cu(CH3CN)4]+ which can be precipitated with large anions such as ClO4 - or PF6- . Reactions with alkoxides of alkali metals produce yellow copper(I) alkoxides. For example, reaction with sodium ethoxide yield copper(I) ethoxide, a yellow compound that can be sublimed from the product mixture: CuCl + NaOC2H5 → CuOC2H5 + NaCl Copper(I) chloride forms complexes with ethylene and other alkenes in solutions that may have compositions such as [Cu(C2H4)(H2O)2]+ or [Cu(C2H4)(bipy)]+. (bipy = bipyridyl) Reactions with lithium or Grignard reagent yield alkyl or aryl copper(I) derivatives, respectively. Such organocopper compounds containing Cu-Cu bonds are formed only by Cu+ and not Cu2+ ions.
Definition
ChEBI: An inorganic chloride of copper in which the metal is in the +1 oxidation state.
Allgemeine Beschreibung
The structure of copper(I) chloride is similar to zinc-blende crystal at room temperature; the structure is wurtzite at 407 °C and at higher temperatures it forms copper(I) chloride vapor as per mass spectroscopy.
Hazard
Copper(I) chloride is moderately toxic by ingestion and possibly other routes of entry into the body. The oral LD
50 in mouse is reported to be 347 mg/kg; and subcutaneous LD
50 in guinea pigs is 100 mg/kg.
Versand/Shipping
UN2802 Copper chloride, Hazard class: 8; Labels: 8-Corrosive material.
läuterung methode
Wash the solid with ethanol and diethyl ether, then dry it and store it in a vacuum desiccator [.sterl.f Acta Chem Scand 4 375 1950]. Alternatively, to an aqueous solution of CuCl2.2H2O is added, with stirring, an aqueous solution of anhydrous sodium sulfite. The colourless product is dried at 80o for 30minutes and stored under N2. Cu2Cl2 can be purified by zone-refining [Hall et al. J Chem Soc, Faraday Trans 1 79 343 1983]. [Glemser & Sauer in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol II p 1005 1965.]
Inkompatibilitäten
Contact with strong acids forms monovalent copper salts and toxic hydrogen chloride gas. Forms shock-sensitive and explosive compounds with potassium, sodium, sodium hypobromite, nitromethane, acetylene. Keep away from moisture and alkali metals. Attacks metals in the presence of moisture. Reacts with moist air to form cupric chloride dihydrate. May attack some metals, paints, and coatings. May be able to ignite combustible materials.
Kupfer(I)-chlorid Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
5-[4-FLUORO-3-(TRIFLUOROMETHYL)PHENYL]-2-FURALDEHYDE
Natrium-1-amino-9,10-dihydro-9,10-dioxo-4-(2,4,6-trimethylanilino)anthracen-2-sulfonat
5-[2-CHLORO-4-(TRIFLUOROMETHYL)PHENYL]-2-FURALDEHYDE
Clonazepam
2-Bromchlorbenzol
4-Chlor-3-nitrotoluol
2-Chlor-1,3-dinitrobenzol
3,5-DICHLORO (1H)INDAZOLE
DI-T-BUTYLMETHYLPHOSPHINE
7-CHLOROQUINOLINE
Chlortoluol (m)
Dichlor(methyl)silan
4-Chlor-N-methylanilin
Bis(trimethylsilyl)acetylen
2-(4'-Chlorbenzyl)pyridin
5-[2,6-DICHLORO-4-(TRIFLUOROMETHYL)PHENYL]-2-FURALDEHYDE
Acryloylchlorid
3-(P-CHLOROPHENYL)-3-(2-PYRIDYL)PROPYLALDEHYDE DIETHYL ACETAL
2-(3-(4-Amino-9,10-dihydro-3-sulfo-9,10-dioxoanthracen-4-yl)aminobenzolsulfonyl)vinyl)dinatriumsulfat
Phenyl-m-tolylether
2,4,5-Trifluorophenylacetic acid
3-CHLOROTHIOPHENE-2-CARBOXAMIDE
Dinatrium-4,4'-[methylenbis(4,1-phenylenimino)]bis[1-amino-9,10-dihydro-9,10-dioxoanthracen-2-sulfonat]
5-[4-(TRIFLUOROMETHOXY)PHENYL]-2-FURALDEHYDE
3-CHLORO-2-METHYLBENZONITRILE
N,N,N',N'-Tetramethyl-p-phenylendiamindihydrochlorid
1,4-Dichlornaphthalin
2-Chloro-3-methyl-5-bromopyridine
2,3-Dichlorobenzaldehyde
Dinatrium-[29H,31H-phthalocyanindisulfonato(4-)-N29,N30,N31,N32]cuprat(2-)
5-Chloro-2-fluorobenzoic acid
4-Chlor-2-(4-methoxyphenyl)anthranilsure
1,3-Dichlorbut-2-en
Hexansäure-2-propenylester
2,4,6-Trimethoxybenzaldehyd
5-(4-Bromophenyl)furfural
2-Chloro-5-iodopyridine
16,23-Dihydronaphth[2',3':6,7]indolo[2,3-c]dinaphtho[2,3-a:2'3'-i]carbazol-5,10,15,17,22,24-hexon
Chlor(methyl)silan
Dibenzo[def,mno]chrysen-6,12-dion
