ChemicalBook >> CAS DataBase List >>Propenoyl Chloride

Propenoyl Chloride

CAS No.
814-68-6
Chemical Name:
Propenoyl Chloride
Synonyms
prop-2-enoyl chloride;oyL;2-PROPENOYL CHLORIDE;acrylyl chloride;ACRYLIC ACID CHLORIDE;Propenoyl chloride;chloridkyselinyakrylove;Acryloyl chloride, 97%, for synthesis, stabilized with p-Hydroxyanisole;ACRYLOYL CHLORIDE;propenoylchloride
CBNumber:
CB00124293
Molecular Formula:
C3H3ClO
Molecular Weight:
90.51
MDL Number:
MFCD00000731
MOL File:
814-68-6.mol
Last updated:2024-04-19 15:36:20

Propenoyl Chloride Properties

Melting point 76 °C(Solv: isopropyl ether (108-20-3))
Boiling point 72-76 °C (lit.)
Density 1.114 g/mL at 25 °C (lit.)
vapor density >1 (vs air)
vapor pressure 1.93 psi ( 20 °C)
refractive index n20/D 1.435(lit.)
Flash point 61 °F
storage temp. 2-8°C
solubility Chloroform (Soluble), Methanol (Slightly)
form Oil
color Colourless to Pale Yellow
Water Solubility Miscible with water.
Sensitive Moisture & Light Sensitive
BRN 635744
Exposure limits ACGIH: TWA 5 mg/m3 (Skin)
NIOSH: TWA 5 mg/m3
Stability Stable, but reacts violently with water. Incompatible with alcohols, oxidizing agents, strong bases. Light-sensitive. Highly flammable.
InChIKey HFBMWMNUJJDEQZ-UHFFFAOYSA-N
CAS DataBase Reference 814-68-6(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII 8K23O56TG5
NIST Chemistry Reference 2-Propenoyl chloride(814-68-6)
EPA Substance Registry System Acrylyl chloride (814-68-6)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS02,GHS05,GHS06
Signal word  Danger
Hazard statements  H225-H290-H302-H314-H330
Precautionary statements  P210-P280-P301+P312-P303+P361+P353-P304+P340+P310-P305+P351+P338
Hazard Codes  F,T+
Risk Statements  11-14-26-34
Safety Statements  16-26-28-36/37/39-45-7/9
RIDADR  UN 3383 6.1/PG 1
WGK Germany  3
RTECS  AT7350000
8-10
TSCA  Yes
HazardClass  3
PackingGroup  II
HS Code  29161980
NFPA 704
3
4 2
W

Propenoyl Chloride price More Price(14)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 549797 Acryloyl chloride 97.0%, contains <210ppm MEHQ as stabilizer 814-68-6 5g $76.2 2024-03-01 Buy
Sigma-Aldrich 549797 Acryloyl chloride 97.0%, contains <210ppm MEHQ as stabilizer 814-68-6 500g $646 2024-03-01 Buy
Alfa Aesar L10363 Acryloyl chloride, 96%, stab. with 400ppm phenothiazine 814-68-6 10g $40.5 2021-12-16 Buy
Alfa Aesar L10363 Acryloyl chloride, 96%, stab. with 400ppm phenothiazine 814-68-6 50g $60.6 2021-12-16 Buy
Sigma-Aldrich A24109 Acryloyl chloride ≥97%, contains ~400ppm phenothiazine as stabilizer 814-68-6 5g $66.7 2024-03-01 Buy
Product number Packaging Price Buy
549797 5g $76.2 Buy
549797 500g $646 Buy
L10363 10g $40.5 Buy
L10363 50g $60.6 Buy
A24109 5g $66.7 Buy

Propenoyl Chloride Chemical Properties,Uses,Production

Toxicity

Propenoyl Chloride is a skin irritant, with pulmonary edema in more severe exposures. Other signs and symptoms of acute exposure may include headache, dizziness, and weakness. Gastrointestinal effects may include nausea, vomiting, diarrhea, and stomach ulceration.

Physical properties

Propenoyl Chloride is a colorless liquid, although aged samples appear yellow. It belongs to the acid chlorides group of compounds.

Preparation

Acryloyl chloride can be efficiently prepared by treating acrylic acid with benzoyl chloride:

CH2=CHCO2H + C6H5COCl → CH2=CHCOCl + C6H5CO2H

Chemical Reactivity

Propenoyl Chloride undergoes the reactions common for acid chlorides. For example, it reacts readily with water, producing acrylic acid. When treated with sodium salts of carboxylic acids, the anhydride is formed. Reactions with alcohols and amines gives esters and amides, respectively. It acylates organozinc compounds.

Global( 433)Suppliers
Supplier Tel Email Country ProdList Advantage
Henan Fengda Chemical Co., Ltd
+86-371-86557731 +86-13613820652 info@fdachem.com China 16805 58
Ouhuang Engineering Materials (Hubei) Co., Ltd
+8617702722807 admin@hbouhuang.com China 2991 58
Capot Chemical Co.,Ltd.
571-85586718 +8613336195806 sales@capotchem.com China 29797 60
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21691 55
Shanghai Time Chemicals CO., Ltd.
+86-021-57951555 +8617317452075 jack.li@time-chemicals.com China 1807 55
Zjartschem
+86-571-8723 8903 jocelynpan@zjarts.com jocelynpan@zjarts.com CHINA 993 58
Tianjin Zhongxin Chemtech Co., Ltd.
+86-022-66880623 +8618622897568 sales@tjzxchem.com China 559 58
Shanxi Naipu Import and Export Co.,Ltd
+86-13734021967 +8613734021967 kaia@neputrading.com China 1011 58
career henan chemical co
+86-0371-86658258 sales@coreychem.com China 29914 58
SHANDONG ZHI SHANG CHEMICAL CO.LTD
+86 18953170293 sales@sdzschem.com China 2931 58

View Lastest Price from Propenoyl Chloride manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Titanium chloride-aluminum chloride pictures 2021-07-13 Titanium chloride-aluminum chloride
12003-13-3
US $15.00-10.00 / KG 1KG 99%+ HPLC Monthly supply of 1 ton Zhuozhou Wenxi import and Export Co., Ltd
Titanium chloride-aluminum chloride pictures 2021-07-10 Titanium chloride-aluminum chloride
12003-13-3
US $15.00-10.00 / KG 1KG 99%+ HPLC Monthly supply of 1 ton Zhuozhou Wenxi import and Export Co., Ltd
Titanium chloride-aluminum chloride pictures 2021-07-02 Titanium chloride-aluminum chloride
12003-13-3
US $15.00-10.00 / KG 1KG 99%+ HPLC Monthly supply of 1 ton Zhuozhou Wenxi import and Export Co., Ltd
ACRYLOYL CHLORIDE STAB. WITH 2 6-DI-TER ACRYLOYL CHLORIDE, STAB. Acryloylchloride,96% Acryloyl chloride, 96%, stab. with 400ppm phenothiazine Acryloyl Chloride (stabilized with MEHQ) Acryloyl Chloride (stabilized with Phenothiazine) Acryloyl Chloride, Stab. With 400Ppm Phenothiazine ACRYLOYL CHLORIDE, 97.0% Acryloyl chloride,2-Propenoyl chloride ACRYLOYL CHLORIDE ACRYLOYL CHLORIDE (STABILISED WITH PHENO Chlorid kyseliny akrylove propenoylchloride Acryloyl chloride, stabilized with 400 ppM phenothiazine ACRYLOYL CHLORIDE, 96%, STABILIZED Acryloyl Chloride (stabilized with Phenothiazine)> Ibandronate Sodium Impurity J Ibandronate Impurity 17 Acryloyl chloride ISO 9001:2015 REACH Acryloyl chloride, 97%, stabilized with p-Hydroxyanisole Acryloyl chloride, 97%, stabilized with 400 ppm phenothiazine Acryloyl chloride, 97%, stabilized with 400 ppm p-Hydroxyanisole Acrylyl chloride manufacturer kf-wang(at)kf-chem.com acrylyl chloride ACRYLIC ACID CHLORIDE 2-PROPENOYL CHLORIDE chloridkyselinyakrylove Propenoyl chloride Acryloyl chloride, 97%, for synthesis, stabilized with p-Hydroxyanisole prop-2-enoyl chloride oyL Acrylonyl chloride, HYPERICUM PERFORATUM OIL 68917-49-7 Acryloyl chloride (6CI, 8CI) Acryloyl chloride,99.5% Acryloyl Chloride, stabilized with Phenothiazine), ≥ 95.0% 814-68-6 CH2CHCOCl C3H3OCl Building Blocks Carbonyl Compounds Acid Halides Organic Building Blocks ACID CHLORIDES Industrial/Fine Chemicals Halogen compounds 814-68-6