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ABIETIC ACID

CAS No.
514-10-3
Chemical Name:
ABIETIC ACID
Synonyms
Abietate;ROSIN ACID;ABIETIC ACID, TECH., 70%;OdoM;NSC 25149;abieticaci;SYLVIC ACID;ABIETIC ACID;abietinicacid;l-abieticacid
CBNumber:
CB1381555
Molecular Formula:
C20H30O2
Molecular Weight:
302.45
MDL Number:
MFCD03423567
MOL File:
514-10-3.mol
MSDS File:
SDS
Last updated:2023-05-25 18:01:00

ABIETIC ACID Properties

Melting point 139-142 °C (lit.) 150-165 °C
alpha D24 -106° (c = 1 in abs alc)
Boiling point 440℃
Density 1.06
refractive index 1.4800 (estimate)
Flash point 208℃
storage temp. 2-8°C
solubility Soluble in alcohols, acetone and ethers
pka pK1:7.62 (25°C)
form Crystals and Chunks
color Yellow-brownish
Odor at 100.00?%. mild acetic
optical activity [α]20/D 85±10°, c = 1% in ethanol
Water Solubility Soluble in acetone, petroleum ether, diethyl ether and ethanol. Insoluble in water.
Sensitive Air Sensitive
Merck 14,7
BRN 2221451
Exposure limits NIOSH: TWA 0.1 mg/m3
Stability Stable. Combustible. Incompatible with strong oxidizing agents.
LogP 6.460
CAS DataBase Reference 514-10-3(CAS DataBase Reference)
Indirect Additives used in Food Contact Substances ABIETIC ACID
EWG's Food Scores 1
FDA UNII V3DHX33184
EPA Substance Registry System Abietic acid (514-10-3)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS07,GHS09
Signal word  Warning
Hazard statements  H315-H319-H335-H400
Precautionary statements  P261-P264-P271-P273-P302+P352-P305+P351+P338
Hazard Codes  Xi,N
Risk Statements  36/37/38-50-50/53
Safety Statements  26-36
RIDADR  UN 3077 9/PG 3
WGK Germany  3
RTECS  TP8580000
10-23
TSCA  Yes
HazardClass  9
PackingGroup  III
HS Code  29162090
Toxicity LD50 ivn-mus: 180 mg/kg
NFPA 704
0
2 1

ABIETIC ACID price More Price(27)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 00010 Abietic acid technical, ~75% (GC) 514-10-3 25g $97.6 2024-03-01 Buy
Sigma-Aldrich 00010 Abietic acid technical, ~75% (GC) 514-10-3 100g $171 2024-03-01 Buy
TCI Chemical A0001 Abietic Acid >80.0%(GC) 514-10-3 25g $52 2024-03-01 Buy
TCI Chemical A0001 Abietic Acid >80.0%(GC) 514-10-3 500g $363 2024-03-01 Buy
Alfa Aesar 042582 Abietic acid, 90+% 514-10-3 250mg $100 2024-03-01 Buy
Product number Packaging Price Buy
00010 25g $97.6 Buy
00010 100g $171 Buy
A0001 25g $52 Buy
A0001 500g $363 Buy
042582 250mg $100 Buy

ABIETIC ACID Chemical Properties,Uses,Production

Description

Abietic acid is probably a major allergen of colophony, by way of oxidation products. Its detection in a material indicates that allergenic components of colophony are present.

Chemical Properties

yellow resinous powder, crystals or chunks

Uses

manufacture of esters (ester gums), e.g., methyl ester, vinyl and glyceryl esters for use in lacquers and varnishes; manufacture of "metal resinates", soaps, plastics, and paper sizes; assists growth of lactic and butyric acid bacteria; component in tall oil used as deodorizing agent in cooling fluids; major component of rosin used in the production of varnishes, printing inks, paper, soldering fluxes, greases, cutting fluids, glue tackifiers, adhesives, surface coatings, polish, shoes, insulations, waxes, cosmetics (mascara, rouge, eye shadow), topical medicaments, violin bow rosin, day, athletic grip aid, pine oil deansers; component in dental impression materials and periodontal packings

Uses

Abietic acid is used to make ester gums in lacquers, varnishes and soaps. It is also used in metal resonates and plastics. Further, it is utilized in musical instruments to make them less slippery. It acts as a precursor to natural product synthesis. In addition to this, it is used to depackage integrated circuits from their epoxy coatings.

Uses

Abietic Acid is the primary component of resin acid found commonly in rosin. Abietic Acid exhibited potent testosterone 5α-reductase inhibitory activity in vitro.

Definition

ChEBI: An abietane diterpenoid that is abieta-7,13-diene substituted by a carboxy group at position 18.

General Description

Yellowish resinous powder.

Reactivity Profile

ABIETIC ACID reacts exothermically with bases, both organic (for example, the amines) and inorganic. Can react with active metals to form gaseous hydrogen and a metal salt. Such reactions are slow if the solid acid remains dry. Can react with cyanide salts to generate gaseous hydrogen cyanide. The reaction is slow for dry, solid carboxylic acids. Insoluble carboxylic acids react with solutions of cyanides to cause the release of gaseous hydrogen cyanide. Flammable and/or toxic gases and heat are generated by the reaction of carboxylic acids with diazo compounds, dithiocarbamates, isocyanates, mercaptans, nitrides, and sulfides. Carboxylic acids, especially in aqueous solution, also react with sulfites, nitrites, thiosulfates (to give H2S and SO3), dithionites (SO2), to generate flammable and/or toxic gases and heat. Their reaction with carbonates and bicarbonates generates a harmless gas (carbon dioxide) but still heat. Like other organic compounds, carboxylic acids can be oxidized by strong oxidizing agents and reduced by strong reducing agents. These reactions generate heat. A wide variety of products is possible. Like other acids, carboxylic acids may initiate polymerization reactions; like other acids, they often catalyze (increase the rate of) chemical reactions.

Health Hazard

ACUTE/CHRONIC HAZARDS: Slight fire hazard, slight explosive hazard as dust. Low toxicity.

Fire Hazard

Combustible.

Contact allergens

Abietic acid is probably the major allergen of colophony, along with dehydroabietic acid, by way of oxidation products. Its detection in a material indicates that allergenic components of colophony are present

Safety Profile

Poison by intravenous route.Combustible. Slight explosion hazard as dust. Whenheated to decomposition it emits acrid smoke andirritating fumes.

Purification Methods

Filter, dry it in a vacuum (over KOH or CaSO4) and store it in an O2-free atmosphere. It can also be purified via the anhydride, tritylabietate and the potassium, piperidine and brucine salts. max : nm(log ): 2343(4.3), 241(4.4), 2505(4.2), 235(4.34) and 240(4.36) in Et. [Harris & Sanderson Org Synth Coll Vol IV 1 1963, J Am Chem Soc 35 3736 1949, Lambard & Frey Bull Soc Chim Fr 1194 1948, Buchbauer et al. Monatsh Chem 116 1345 1985.] [Beilstein 9 IV 2175.]

13463-98-4
514-10-3
Synthesis of ABIETIC ACID from calcium abietate
Global( 273)Suppliers
Supplier Tel Email Country ProdList Advantage
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21691 55
Shanghai Zheyan Biotech Co., Ltd.
18017610038 zheyansh@163.com CHINA 3620 58
career henan chemical co
+86-0371-86658258 sales@coreychem.com China 29914 58
Chengdu Biopurify Phytochemicals Ltd.
+8618080483897 sales@biopurify.com China 3424 58
Hubei Jusheng Technology Co.,Ltd.
18871490254 linda@hubeijusheng.com CHINA 28180 58
Hubei xin bonus chemical co. LTD
86-13657291602 linda@hubeijusheng.com CHINA 22968 58
Chongqing Chemdad Co., Ltd
+86-023-61398051 +8613650506873 sales@chemdad.com China 39916 58
Shanghai Standard Technology Co., Ltd.
18502101150 ft-sales@nature-standard.com CHINA 1923 58
Wuhan ChemNorm Biotech Co.,Ltd.
+86-27-8439 4403 18971486879 sales@chemnorm.com CHINA 2935 58
Hubei Ipure Biology Co., Ltd
+8613367258412 ada@ipurechemical.com China 10326 58

View Lastest Price from ABIETIC ACID manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Abietic Acid pictures 2023-02-24 Abietic Acid
514-10-3
US $0.00 / mg 20mg ≥98%(HPLC) 100 g Shanghai Standard Technology Co., Ltd.
abietic acid pictures 2023-02-13 abietic acid
514-10-3
US $80.00 / kg 1kg 99% 100MT Hebei baicao biology science and technology co., ltd
Abietic Acid pictures 2022-08-10 Abietic Acid
514-10-3
US $3650.00 / g 5g ≧70.0%(GC) 20T Nacalai Tesque Inc
  • Abietic Acid pictures
  • Abietic Acid
    514-10-3
  • US $0.00 / mg
  • ≥98%(HPLC)
  • Shanghai Standard Technology Co., Ltd.
  • abietic acid pictures
  • abietic acid
    514-10-3
  • US $80.00 / kg
  • 99%
  • Hebei baicao biology science and technology co., ltd
  • Abietic Acid pictures
  • Abietic Acid
    514-10-3
  • US $3650.00 / g
  • ≧70.0%(GC)
  • Nacalai Tesque Inc
(1R,4AR,4BR,10AR)-7-ISOPROPYL-1,4A-DIMETHYL-1,2,3,4,4A,4B,5,6,10,10A-DECAHYDRO-PHENANTHRENE-1-CARBOXYLIC ACID 13-isopropyl-podocarpa-13-dien-15-oicacid 13-isopropylpodocarpa-7,13-dien-15-oicacid ABIETIC ACID MELTING POINT 153-167 C ABIETIC ACID, 90-95% Abieticacid,TechnicalGrade 1-Phenanthrenecarboxylic acid, 1,2,3,4,4a,4b,5,6,10,10a-decahydro-1,4a-dimethyl-7-(1-methylethyl)-, (1R,4aR,4bR,10aR)- ABIETIC ACID(SYLVIC ACID)(RG) ABIETICACIDRESIN SYLVIC ACID (1r-(1alpha,4abeta,4balpha,10aalpha)-1,2,3,4,4a,4b,5,6,10,10a-decahydro-1,4a-d [1theta-(1alpha,4abeta,4balpha,10aalpha)]--7-(1-methylethyl) 1,2,3,4,4a,4b,5,6,10,10a-decahydro-1,4a-dimethyl-7-(1-methylethyl)-,[1R-(1.alpha.,4a.beta.,4b.al1-Phenanthrenecarboxylicacid (-)-Abieta-7,13-dien-18-oic acid 1,2,3,4,4a,4bα,5,6,10,10aα-Decahydro-1β,4aβ-dimethyl-7-(1-methylethyl)phenanthrene-1α-carboxylic acid 13-Isopropylpodocarpa-7,13-dien-18-oic acid Abietic acid, 90+% Abietic acid,85% (1R,4aR,4bR,10aR)-1,2,3,4,4a,4b,5,6,10,10a-Decahydro-1,4a-diMethyl-7-(1-Methylethyl)-1-phenanthrenecarboxylic Acid NSC 25149 OdoM Rosin Acid Sylvic Acid ABIETIC ACID(SYLVIC ACID)(SH) ABIETIC ACID, PRACT ABIETIC ACID(SYLVIC ACID)(P) 1,2,3,4,4a,4b,5,6,10,10a-cahydro-1,4a-diMethyl-7-(1-Methylethyl)-1-phenanthrenecarboxylic acid Abietic acid, 85% 25GR 7,13-abietadien-18-oicacid abietinicacid imethyl-7-(1-methylethyl-)-1-phenanthrenecarboxylicacid kyselinaabietova l-abieticacid abietic acid, technical 13-Isopropyodocarpa-7,13-dien-15-oic acid Abietic acid ;13-Isopropyodocarpa-7,13-dien-15-oic acid;Sylvic acid;13-iso-Propylpodocarpa-7,13-dien-15-oic acid colopholicacid colophonic acid Abietic acid technical, ~75% (GC) AbieticAcid,75% (1R,4aR,4bR,10aR)-1,4a-Dimethyl-7-(propan-2-yl)-1,2,3,4,4a,4b,5,6,10,10a-decahydrophenanthrene ABIETIC ACID 1-Phenanthrenecarboxylicacid, 1,2,3,4,4α,4β,5,6,10,10α-decahydro-1,4α-dimethyl-7-(1-methylethyl)-,(1R,4αR,4βR,10αR)- (1R,4AR,4BR,10AR)-1,4A-DIMETHYL-7-PROPAN-2-YL-2,3,4,4B,5,6,10,10A-OCTAHYDROPHENANTHRENE-1-CARBOXYLIC ACID abieticaci Abietic Acid, >95% 1-Phenanthrenecarboxylicacid, 1,2,3,4,4α,4β,5,6,10,10α-decahydro-1,4α-dimethyl-7-(1-methylethyl)-,(1R,4αR,4βR,10αR)- ABIETIC ACID, TECH., 70% ROSIN ACID Abietate ABIETIC ACID(SYLVIC ACID) 514-10-3 514103 C19H29COOH Chiral Building Blocks Asymmetric Synthesis Complex Molecules Terpenes Terpenes (Others)