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Chloroform-d

Chloroform-d structure

CAS No.: 865-49-6

Chemical Name:: Chloroform-d

Synonyms: deuterated chloroform;CHLOROFORM-D1;Deuteriochloroform;Deuterotrichloromethane;Methane-d, trichloro-;Chloroform-d, 99.8 atom % D, anhydrous;CHLOROFORM-D, 99.8 ATOM % D(CONTAINS 1%V/V TMS);Chloroform-d,for NMR,100.0 atom % D, packagedin 0.50 ml ampules;oroform-d;d,ChloroforM

CBNumber:: CB2103569

Molecular Formula:: CCl3D

Molecular Weight:: 120.38

MDL Number:: MFCD00000827

MOL File:: 865-49-6.mol

MSDS File:: SDS

Last updated:2024-04-22 11:58:20

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Chloroform-d Properties

Melting point	−64 °C(lit.)
Boiling point	60.9 °C(lit.)
Density	1.500 g/mL at 25 °C(lit.)
vapor pressure	211 hPa (20 °C)
refractive index	n20/D 1.444(lit.)
Flash point	62°C
storage temp.	Store at +2°C to +8°C.
solubility	Miscible with organic solvents, ethyl acetate and acetone.
form	Liquid
color	White to beige
Specific Gravity	1.505
Sensitive	Moisture Sensitive
BRN	1697633
Exposure limits	ACGIH: TWA 10 ppm OSHA: Ceiling 50 ppm(240 mg/m3) NIOSH: IDLH 500 ppm; STEL 2 ppm(9.78 mg/m3)
Stability	Stable. Incompatible with strong bases, alkali metals, aluminium, magnesium, strong oxidizing agents.
InChIKey	HEDRZPFGACZZDS-MICDWDOJSA-N
LogP	1.5-1.6 at 20-23℃ and pH9
Surface tension	72.3mN/m at 998.5mg/L and 20℃
CAS DataBase Reference	865-49-6(CAS DataBase Reference)
FDA UNII	P1NW4885VT
EPA Substance Registry System	Chloroform-d (865-49-6)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS06,GHS08

Signal word

Danger

Hazard statements

H302-H315-H319-H331-H336-H351-H361d-H372

Precautionary statements

P201-P301+P312-P302+P352-P304+P340+P311-P305+P351+P338-P308+P313

Hazard Codes

Xn,T

Risk Statements

22-38-40-48/20/22-48/20-36/38-20/22-63

Safety Statements

36/37

RIDADR

UN 1888 6.1/PG 3

WGK Germany

HazardClass

6.1

PackingGroup

III

HS Code

28459000

Toxicity

LD50 orally in Rabbit: 695 mg/kg LD50 dermal Rabbit > 3980 mg/kg

NFPA 704

	1
3		1

Chloroform-d price More Price(102)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	151823	Chloroform-d 99.8 atom % D	865-49-6	10x0.6ml	$38.4	2024-03-01	Buy
Sigma-Aldrich	151823	Chloroform-d 99.8 atom % D	865-49-6	10x0.75ml	$40.2	2024-03-01	Buy
Sigma-Aldrich	1.03420	Chloroform-D1 deuteration degree min. 99.8% for NMR spectroscopy (stabilized with silver) MagniSolv?	865-49-6	25mL	$43.4	2024-03-01	Buy
Sigma-Aldrich	1.03420	Chloroform-D1 deuteration degree min. 99.8% for NMR spectroscopy (stabilized with silver) MagniSolv?	865-49-6	100mL	$109	2024-03-01	Buy
Sigma-Aldrich	1.03420	Chloroform-D1 deuteration degree min. 99.8% for NMR spectroscopy (stabilized with silver) MagniSolv?	865-49-6	500mL	$449	2024-03-01	Buy

Product number	Packaging	Price	Buy
151823	10x0.6ml	$38.4	Buy
151823	10x0.75ml	$40.2	Buy
1.03420	25mL	$43.4	Buy
1.03420	100mL	$109	Buy
1.03420	500mL	$449	Buy

Chloroform-d Chemical Properties,Uses,Production

Water peak

The position of the water peak in different deuterated reagents is not the same. The water peak of heavy water is about 4.67 ppm. There is a trend that the more water the low field.
Chloroform-D is less soluble with water and the water content is low, so its water peak near 1.59 ppm. Deuterated acetone is about 2.8 ppm and the deuterated dimethylsulfoxide has a water peak of about 3.4 ppm. If water is added to deuterated acetone, the water peak will gradually move to a low field and eventually stop at about 4.7 ppm.

Application

Reagents for nuclear magnetic instruments

Chemical Properties

colourless liquid

Uses

Chloroform-d may be used in the synthesis of dichlorofluoromethane-d (DCFM).

Uses

Labelled Chloroform, generally in trimethylsilane solution, used in NMR spectroscopy as a solvent. Unlabelled chloroform has been used an an anaesthetic due to its action on the central nervous system .

Uses

Chloroform-d is widely used in the organic solvent for the NMR analysis.

Definition

ChEBI: Deuterated chloroform is a deuterated compound that is an isotopologue of chloroform in which the hydrogen atom is replaced with deuterium. Commonly used as a solvent in proton NMR spectroscopy. It has a role as a non-polar solvent, a NMR solvent and a NMR chemical shift reference compound. It is a deuterated compound and a member of chloromethanes.

General Description

Chloroform-d (Deuterochloroform, CDCl₃), deuterated chloroform, is a 100% isotopically enriched NMR (Nuclear Magnetic Resonance) solvent. It is widely employed in high resolution NMR studies due to its high chemical and isotopic purity. Quantitaive infrared spectral investigations of carbon-deuterium stretching bands of chloroform-d in various organic solvents have been reported. Raman difference spectroscopic studies of mixtures of chloroform-d and liquid chloroform have been conducted to evaluate frequency shifts in the in the ν₁ and ν₂ bands of CHCl₃ and CDCl₃.

Chloroform-d Preparation Products And Raw materials

Raw materials

Preparation Products

4-AMINO-3-FORMYLPYRIDINE

Chloroform-d Suppliers

Global( 209)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Peric Technology Co.,Ltd	+86-0310-7183483 +8615030098277	jiake718@aliyun.com	China	36	58
Hangzhou ICH Biofarm Co., Ltd	+undefined8613073685410	sales@ichemie.com	China	985	58
Henan Fengda Chemical Co., Ltd	+86-371-86557731 +86-13613820652	info@fdachem.com	China	7845	58
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21691	55
career henan chemical co	+86-0371-86658258	sales@coreychem.com	China	29914	58
Chongqing Chemdad Co., Ltd	+86-023-61398051 +8613650506873	sales@chemdad.com	China	39916	58
CONIER CHEM AND PHARMA LIMITED	+8618523575427	sales@conier.com	China	49390	58
Richest Group Ltd	18017061086	oled@richest-group.com	CHINA	5601	58
SHANGHAI T&W PHARMACEUTICAL CO., LTD.	+86-021-61551413 +8618813727289	contact@trustwe.com	China	5738	58
Hubei Ipure Biology Co., Ltd	+8613367258412	ada@ipurechemical.com	China	10326	58

Supplier	Advantage
Peric Technology Co.,Ltd	58
Hangzhou ICH Biofarm Co., Ltd	58
Henan Fengda Chemical Co., Ltd	58
Henan Tianfu Chemical Co.,Ltd.	55
career henan chemical co	58
Chongqing Chemdad Co., Ltd	58
CONIER CHEM AND PHARMA LIMITED	58
Richest Group Ltd	58
SHANGHAI T&W PHARMACEUTICAL CO., LTD.	58
Hubei Ipure Biology Co., Ltd	58

View Lastest Price from Chloroform-d manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2023-12-24	Chloroform-d 865-49-6	US $100.00-1.00 / KG	1KG	99%	g-kg-tons, free sample is available	Henan Fengda Chemical Co., Ltd
2023-11-01	Chloroform-D 865-49-6	US $0.00 / kg	200kg	99%	plenty of stock	Hangzhou ICH Biofarm Co., Ltd
2023-03-31	Chloroform-d 865-49-6	US $30.00 / kg	1kg	99%	20 tons	Hebei Duling International Trade Co. LTD

Chloroform-d
865-49-6
US $100.00-1.00 / KG
99%
Henan Fengda Chemical Co., Ltd

Chloroform-D
865-49-6
US $0.00 / kg
99%
Hangzhou ICH Biofarm Co., Ltd

Chloroform-d
865-49-6
US $30.00 / kg
99%
Hebei Duling International Trade Co. LTD

Chloroform-d Spectrum

Chloroform-d(865-49-6)MS Chloroform-d(865-49-6)¹HNMR Chloroform-d(865-49-6)¹³CNMR Chloroform-d(865-49-6)IR1 Chloroform-d(865-49-6)Raman

865-49-6(Chloroform-d)Related Search:

Ethyl (2,4,6-trimethylbenzoyl) phenylphosphinate 5α-Cholestane NMR REF STD, 0.0485M TRIPHENYLPHOSPHATE IN CHLOROFORM-D, 99.9 ATOM % D,NMR REF STD, 0.0485M TRIPHENYLPHOSPHATEIN CHLOROFORM-D,99.8 ATOM % D PHENOL:CHLOROFORM:ISOAMYLALCOHOL 49.5:49 .5:1,PHENOL:CHLOROFORM:ISOAMYL ALC. 125:24:1, FOR MOL. BIOLOGY BETA-SITOSTEROL 1X1ML CHLOROFORM 100UG/M L

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DEUTERIUM HYDRIDE 0.1% ETHYLBENZENE IN CHLOROFORM-D (540 PP TUBE) 30% MENTHOL IN CHLOROFORM-D

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Chloroform-d, contains 0.03 v/v% TMS, 99.8+ atom % D, AcroSeal, for NMR ChloroforM-d, for NMR, 99.8 atoM % D, packaged in 0.75 Ml aMpoules CHLORAL HYDRATE SOLUTION PHE CONGO RED PAPER PHE COPPER EDETATE SOLUTION PHE GC TEMPASE 2X MASTER MIX I 2500R GC TEMPASE 2X MASTER MIX I 500R GC TEMPASE 2X MASTER MIX II 500R Chloroform-d, 99.8% Isotopic, contains 1% TMS Chloroform-d, 100% Isotopic, contains 0.03% TMS Chloroform-d, 99.8% Isotopic, contains 0.03% TMS CHLOROFORM-D, "100%", 99.96 ATOM % D, CO CHLOROFORM-D, >=99.8 ATOM % D, CONTA CHLOROFORM-D, 99.8 ATOM % D, CONTAINS 0& Chloroform-D1 with TMS (1 vol.%), deuteration degree min. 99.5 % for NMR spectroscopy (stabilized with silver) MagniSolv Chloroform-D1 deuteration degree min. 99.8% for NMR spectroscopy (stabilized with silver) MagniSolv Chloroform-D1 0.03 vol.% TMS, deuteration degree min. 99.8% for NMR spectroscopy (stabilized with silver) MagniSolv Chloroform-D1 deuteration degree min. 99.8% for NMR spectroscopy MagniSolv Chloroform-D1 deuteration degree min. 99.96% for NMR spectroscopy MagniSolv Chloroform-d, Isotopic Chloroform - D1, Stabilized with silver Chloroform - D1, 0.03 vol.% TMS, Stabilized with silver Chloroform-d, 100.0 atom % D Trichloro(2H)methane trichloro-deuterio-methane CHLOROFORM-D >99.95 (ATOM % D) STAB. CHLOROFORM-D, "100" (MIN. 99.96 ATOM % D)(1PK=10 X 0.75ML) CHLOROFORM-D, "100" (MIN. 99.96 ATOM % D)(1PK=10 X 0.25ML) CHLOROFORM-D, 99.8 ATOM % D, STABILIZEDWITH 0.5 WT% SILVER FOIL (CONTAINS 0.03%( CHLOROFORM-D, "100" (MIN. 99.96 ATOM % D) CONTAINS 0.03% V/V TMS(1PK=10 X 0.75ML CHLOROFORM-D, 99.9 ATOM % D (CONTAINS 0.03% V/V TMS) CHLOROFORM-D, 99.8 ATOM % D (CONTAINS 0.03% V/V TMS) CHLOROFORM-D, "100" (MIN. 99.96 ATOM % D) CONTAINS 0.03% V/V TMS Chloroform-D,IsotopicPurity>99Atom%D Chloroform-d, isotopic purity Chloroform-d,100%D(Isotopic),contains0.03%v/vTMS Chloroform-d,99.8%(Isotopic),contains0.03%v/vTMS Chloroform-d, 100 atom % D, packaged in 0.75 ml ampules, for NMR Chloroform-d, 100.0 atom % D, for NMR Chloroform-d, 100.0 atom % D, packaged in 0.50 ml ampules, for NMR Chloroform-d, 99.6+ atom % D, for NMR Chloroform-d, 99.8 atom % D, contains 1 v/v% TMS, for NMR Chloroform-d, 99.8 atom % D, for NMR Chloroform-d, 99.8 atom % D, packaged in 0.75 ml ampules, for NMR Chloroform-d, 99.8 atom % D, packaged in 1 ml ampules, for NMR Chloroform-d, 99.8 atom % D, stabilized with silver foil, for NMR Chloroform-d, 99.8% D, stabilized with silver foil, 1 v/v% TMS, for NMR Chloroform-d, 99.8+ atom % D, contains 0.03 v/v% TMS, for NMR Chloroform-d, 99.8+% D, stab. with silver foil, 0.03 v/v% TMS, for NMR ChloroformD>99.96%10x0.75ml ChloroformD>99.96%+0.03%tms ChloroformD>99.8%+0.03%tms ChloroformD>99.8%10x0.75ml ChloroformD>99.8%5x10ml ChloroformD>99.96%10x0.6ml ChloroformD>99.96% ChloroformD>99.96%10x0.75ml(+0.03%tms) Chloroform-d,for NMR,99.8+ atom % D, contains0.03 v/v% TMS