ChemicalBook >> CAS DataBase List >>Ethyl methyl carbonate

Ethyl methyl carbonate

CAS No.
623-53-0
Chemical Name:
Ethyl methyl carbonate
Synonyms
Methylethylcarbonate;EthylMethylCarbonate(Emc);Carbonic acid ethyl methyl;Carbonic acid methyl ethyl;Ethoxyacetic acid, methyl ester;Carbonic acid methyl ethyl ester;ETHYL METHYL CARBONATE;Ethyl Methyl Carbonate >Ethyl Methyl carbonate 98%;METHYL ETHYL CARBONATE (EMC)
CBNumber:
CB3459272
Molecular Formula:
C4H8O3
Molecular Weight:
104.1
MDL Number:
MFCD00191398
MOL File:
623-53-0.mol
MSDS File:
SDS
Last updated:2024-01-16 18:38:52

Ethyl methyl carbonate Properties

Melting point -14.5℃
Boiling point 107 °C
Density 1.006 g/mL at 25 °C
vapor pressure 43hPa at 25℃
refractive index n20/D 1.378
Flash point 23°C
storage temp. 2-8°C
form clear liquid
color Colorless to Almost colorless
Viscosity 0.69mm2/s
Water Solubility 46.8-47.1g/L at 20℃
InChI InChI=1S/C4H8O3/c1-3-7-4(5)6-2/h3H2,1-2H3
InChIKey JBTWLSYIZRCDFO-UHFFFAOYSA-N
SMILES C(OC)(=O)OCC
LogP 0.972 at 40℃
CAS DataBase Reference 623-53-0(CAS DataBase Reference)
FDA UNII OU358HAE25
NIST Chemistry Reference C2H5OCOOCH3(623-53-0)
EPA Substance Registry System Carbonic acid, ethyl methyl ester (623-53-0)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS02
Signal word  Danger
Hazard statements  H225
Precautionary statements  P210
Hazard Codes  Xi
Risk Statements  10-36/37/38
Safety Statements  16-36/37-26
RIDADR  3272
WGK Germany  3
HazardClass  3
PackingGroup  III
HS Code  29209090
NFPA 704
2
0 0

Ethyl methyl carbonate price More Price(12)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 752002 Ethyl methyl carbonate 98% 623-53-0 10ml $98.4 2024-03-01 Buy
Sigma-Aldrich 752002 Ethyl methyl carbonate 98% 623-53-0 50ml $186 2024-03-01 Buy
TCI Chemical C1342 Ethyl Methyl Carbonate >98.0%(GC) 623-53-0 10mL $59 2024-03-01 Buy
TCI Chemical C1342 Ethyl Methyl Carbonate >98.0%(GC) 623-53-0 25mL $116 2024-03-01 Buy
Sigma-Aldrich 809934 Ethyl methyl carbonate 99.9%, acid <10 ppm, H2O <10ppm 623-53-0 25g $272 2024-03-01 Buy
Product number Packaging Price Buy
752002 10ml $98.4 Buy
752002 50ml $186 Buy
C1342 10mL $59 Buy
C1342 25mL $116 Buy
809934 25g $272 Buy

Ethyl methyl carbonate Chemical Properties,Uses,Production

Description

Ethyl methyl carbonate (EMC) is an asymmetric aliphatic organic carbonate. It is a colorless transparent liquid widely used as an excellent solvent for lithium-ion battery electrolytes. EMC increases the solubility of lithium ions improving the capacity density and power of batteries. This compound has excellent thermal conductivity and low electrical resistance, extending the working temperature range of electrolytes, improving lithium batteries' safety, and prolonging their service life. EMC is usually obtained by metal oxide-catalyzed transesterification over dimethyl carbonate and diethyl carbonate. High percentage yields are obtained if the reaction is carried out in liquid or vapor phase[1].

Uses

Non-aqueous solvent for Li-ion batteries

Uses

EMC is majorly utilized as a co-solvent in the nonaqueous electrolyte. It enhances the energy density and discharge capacity of lithium-ion batteries.

Uses

Alkyl carbonates find applications as solvents for lithium ion battery electrolytes and the use of high quality battery grade electrolytes having extremely low water (<10 ppm) and acid (<10 ppm) contents are critical for achieving high electrochemical performance.

General Description

This product has been enhanced for energy efficiency.

Advantages

Ethyl methyl carbonate enables the largest reversible capacity, best cycle stability, highest cycle Coulombic efficiency, lowest onset potential, smallest polarization, lowest self-discharge rate, and best rate performance from graphite compared to dimethyl carbonate and diethyl carbonate. Ethyl methyl carbonate forms a thinner layer of cathode electrolyte interface on the graphite surface with fewer Li–F and ROCO2Li species than with dimethyl carbonate and diethyl carbonate[2].

References

[1] Guido N. Rimondino , Fabio E. Malanca, Jesús A. Vila . “Atmospheric oxidation of ethyl methyl carbonate: Kinetics and reaction mechanism.” Journal of Photochemistry and Photobiology A-chemistry 444 (2023): Article 114994.
[2] Yao Wang. “Unlocking the True Capability of Graphite-Based Dual-Ion Batteries with Ethyl Methyl Carbonate Electrolyte.” ACS Applied Energy Materials 2 10 (2019): 7512–7517.

616-38-6
105-58-8
623-53-0
Synthesis of Ethyl methyl carbonate from Dimethyl carbonate and Diethyl carbonate
Global( 314)Suppliers
Supplier Tel Email Country ProdList Advantage
Shandong Dexiang International Trade Co., Ltd
15662695772;+8615662691337 sales006@dexiangchemical.com China 998 58
Jinan Finer Chemical Co., Ltd
+86-531-88989536 +86-15508631887 sales@finerchem.com China 2967 58
Hebei Mojin Biotechnology Co., Ltd
+8613288715578 sales@hbmojin.com China 12456 58
Henan Bao Enluo International TradeCo.,LTD
+86-17331933971 +86-17331933971 deasea125996@gmail.com China 2503 58
Zibo Hangyu Biotechnology Development Co., Ltd
+86-0533-2185556 +8617865335152 Mandy@hangyubiotech.com China 11013 58
Henan Fengda Chemical Co., Ltd
+86-371-86557731 +86-13613820652 info@fdachem.com China 7845 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21691 55
Hangzhou FandaChem Co.,Ltd.
008657128800458; +8615858145714 fandachem@gmail.com China 9348 55
career henan chemical co
+86-0371-86658258 sales@coreychem.com China 29914 58
Hubei Jusheng Technology Co.,Ltd.
18871490254 linda@hubeijusheng.com CHINA 28180 58

View Lastest Price from Ethyl methyl carbonate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Ethyl methyl carbonate pictures 2024-04-26 Ethyl methyl carbonate
623-53-0
US $2.00 / KG 1KG 99.9% 5000mt Jinan Finer Chemical Co., Ltd
Ethyl methyl carbonate pictures 2024-01-16 Ethyl methyl carbonate
623-53-0
US $0.10-0.30 / kg 1kg 99.99% 20 tons Zibo Hangyu Biotechnology Development Co., Ltd
Ethyl methyl carbonate pictures 2023-12-23 Ethyl methyl carbonate
623-53-0
US $50.00-1.00 / KG 1KG 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
carbonicacidethylestermethylester CARBONIC ACID ETHYL METHYL ESTER ETHYL METHYL CARBONATE METHYL ETHYL CARBONATE (EMC) Carbonic acid methyl=ethyl ester Ethyl Methyl carbonate 98% Ethyl methyl carbonate 99.9%, acid <10 ppm, H2O <10ppm Ethyl Methyl Carbonate > Ethoxyacetic acid, methyl ester Methylethylcarbonate EthylMethylCarbonate(Emc) Carbonic acid ethyl methyl Carbonic acid methyl ethyl Carbonic acid methyl ethyl ester CARBONICACIDETHYLMEChemicalbookTHYLESTER BENZYL CYNO ETHYL METHYL CARBONATE 623-53-0 CH3OCOOC2H5 Lithium-ion battery electrolyte solvent Battery Electrolyte Materials Alternative Energy Electrolytes Lithium-Ion Batteries Materials Science Solvents CARBONATES bc0001 623-53-0