2-Bromoaniline
- CAS No.
- 615-36-1
- Chemical Name:
- 2-Bromoaniline
- Synonyms
- O-BROMOANILINE;2-Bromoanilines;2-bromobenzenamine;1-Amino-2-bromobenzene;2-BromoaniL;2-BROMOANILINE;BROMOANILINE(2-);Aniline, o-bromo-;AKOS BBS-00003650;2-bromo-benzenamin
- CBNumber:
- CB4140711
- Molecular Formula:
- C6H6BrN
- Molecular Weight:
- 172.02
- MDL Number:
- MFCD00007632
- MOL File:
- 615-36-1.mol
- MSDS File:
- SDS
Melting point | 24-28 °C (lit.) |
---|---|
Boiling point | 229 °C (lit.) |
Density | 1.52 g/mL at 25 °C (lit.) |
refractive index | 1.617-1.619 |
Flash point | >230 °F |
storage temp. | 2-8°C |
solubility | 0.949g/l |
form | Liquid After Melting |
pka | 2.53(at 25℃) |
color | Clear yellow to red-brown |
Water Solubility | Insoluble in water. |
BRN | 742062 |
InChIKey | AOPBDRUWRLBSDB-UHFFFAOYSA-N |
CAS DataBase Reference | 615-36-1(CAS DataBase Reference) |
FDA UNII | VTP98DS78E |
NIST Chemistry Reference | Benzenamine, 2-bromo-(615-36-1) |
EPA Substance Registry System | Benzenamine, 2-bromo- (615-36-1) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS07,GHS08,GHS09 |
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Signal word | Warning | |||||||||
Hazard statements | H302+H312+H332-H373-H410 | |||||||||
Precautionary statements | P273-P280-P301+P312-P302+P352+P312-P304+P340+P312-P314 | |||||||||
Hazard Codes | T,Xn | |||||||||
Risk Statements | 23/24/25-33-52/53-36/37/38-20/21/22-24/25 | |||||||||
Safety Statements | 36/37-45-61-36/37/39-26 | |||||||||
RIDADR | UN 2811 6.1/PG 3 | |||||||||
WGK Germany | 3 | |||||||||
F | 8-23 | |||||||||
Hazard Note | Toxic | |||||||||
TSCA | Yes | |||||||||
HazardClass | 6.1 | |||||||||
PackingGroup | III | |||||||||
HS Code | 29214210 | |||||||||
NFPA 704 |
|
2-Bromoaniline price More Price(38)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | B56420 | 2-Bromoaniline 98% | 615-36-1 | 5g | $14.56 | 2024-03-01 | Buy |
Sigma-Aldrich | B56420 | 2-Bromoaniline 98% | 615-36-1 | 25g | $71.9 | 2024-03-01 | Buy |
TCI Chemical | B0541 | 2-Bromoaniline >98.0%(GC)(T) | 615-36-1 | 25g | $44 | 2024-03-01 | Buy |
TCI Chemical | B0541 | 2-Bromoaniline >98.0%(GC)(T) | 615-36-1 | 250g | $254 | 2024-03-01 | Buy |
Alfa Aesar | A11788 | 2-Bromoaniline, 98% | 615-36-1 | 25g | $58.65 | 2024-03-01 | Buy |
2-Bromoaniline Chemical Properties,Uses,Production
Description
O-bromoaniline, m-bromoaniline and p-bromoaniline corresponds to the three isomers of bromoaniline. All of them three are toxic with its toxicity being more severe than chloroanilines. It can be all via percutaneous absorption, being hemolytic and able to cause bladder cancer. It is mainly used for dye raw materials, such as azo dyes, quinazoline dyes and so on. Heating together with glycerol, concentrated sulfuric acid and o-bromonitrobenzene can generate 8-bromoquinoline.
The preparation of the three isomers is as follows:
- Take the corresponding nitroaniline as raw material, have it reacted with sodium nitrite in sulfuric acid, leading to the formation of diazonium salt, followed by reaction with hydrobromic acid under the action of cuprous bromide, leading to the formation of nitrobromobenzene, further subjecting to iron powder reaction in the bromic acid to generate the above three isomers.
- Take benzene as raw material, under the action of iron powder, have it reacted with bromine to generate bromobenzene. It is then reacted with mixed acid (the mixture of sulfuric acid and nitric acid) to generate o-nitrobenzene and p-nitro bromobenzene (orthoaccounts of 35%; paraaccounts of 65%), so that the two are separated, followed by the same process as method one to generate o-bromoaniline and p-bromoaniline.
- Take bromoacetanilide as raw material, put it into sodium hydroxide solution; apply water vapor reflux to obtain the bromoaniline.
Chemical Properties
It appears as white needle crystal with a melting point of 32 ° C, boiling point of 229 ° C, 138-141 ° C (6.38-6.92 kPa), 110.5 ° C (2.53 kPa), relative density of 1.578 (20/4 ° C) and a refractive index of 1.6133. It is soluble in alcohol and ether, but can’t be dissolved in water.
Uses
Organic synthesis intermediates
Chemical Properties
CLEAR YELLOW TO RED-BROWN LIQUID AFTER MELTING
Uses
2-Bromoaniline is used as a corrosion inhibitor, emulsifying and antiseptic agents. It is used in the rubber industry, e.g. diphenylguanidines, phenylenediamines mercaptobenzothiazoles, aniline ketones and etc.
2-Bromoaniline Preparation Products And Raw materials
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Changzhou Zechong Biopharma Co., Ltd. | +undefined18621330623 | sales@zechongchem.com | China | 28 | 58 |
Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 20293 | 58 |
Frapp's ChemicalNFTZ Co., Ltd. | +86 (576) 8169-6106 | sales@frappschem.com | China | 885 | 50 |
Springchem New Material Technology Co.,Limited | +86-021-62885108 +8613917661608 | info@spring-chem.com | China | 2068 | 57 |
Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29798 | 60 |
Yancheng Longshen Chemical Co.,Ltd. | +86-0515-88706880; +8618352073383 | sales@longshenchem.com | China | 79 | 55 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21667 | 55 |
ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 32836 | 60 |
career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29888 | 58 |
Zhejiang ZETian Fine Chemicals Co. LTD | +8618957127338 | stella@zetchem.com | China | 2136 | 58 |
View Lastest Price from 2-Bromoaniline manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2023-12-24 | 2-Bromoaniline
615-36-1
|
US $100.00-1.00 / KG | 1KG | 99% | g-kg-tons, free sample is available | Henan Fengda Chemical Co., Ltd | ||
2023-04-29 | 2-Bromoaniline
615-36-1
|
US $0.00-0.00 / KG | 1KG | 99% | 20 mt | Hebei Guanlang Biotechnology Co., Ltd. | ||
2023-01-31 | 2-Bromoaniline
615-36-1
|
US $0.00 / Kg/Bag | 1Kg/Bag | 99% | 20ton | Hebei Mojin Biotechnology Co., Ltd |
- 2-Bromoaniline
615-36-1
- US $100.00-1.00 / KG
- 99%
- Henan Fengda Chemical Co., Ltd
- 2-Bromoaniline
615-36-1
- US $0.00-0.00 / KG
- 99%
- Hebei Guanlang Biotechnology Co., Ltd.
- 2-Bromoaniline
615-36-1
- US $0.00 / Kg/Bag
- 99%
- Hebei Mojin Biotechnology Co., Ltd