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Tetraacetylethylenediamine

CAS No.
10543-57-4
Chemical Name:
Tetraacetylethylenediamine
Synonyms
TAED;TEAD;TAEG;Nikon A;Mykon ATC;Mikon ATC;TETRAACETYLENEDIAMINE;TETRACETYLETHYLENEDIAMINE;TETRAACETYLETHYLENEDIAMINE;1,2-Bis(diacetylamino)ethane
CBNumber:
CB4401238
Molecular Formula:
C10H16N2O4
Molecular Weight:
228.24
MDL Number:
MFCD00014967
MOL File:
10543-57-4.mol
MSDS File:
SDS
Last updated:2024-04-15 18:41:30

Tetraacetylethylenediamine Properties

Melting point 149-154 °C
Boiling point 140 °C (1.5002 mmHg)
Density 0.9
refractive index 1.4550 (estimate)
Flash point 140 °C
pka -1.23±0.70(Predicted)
form Granular Powder
color Off-white to beige
Water Solubility slightly soluble
Merck 14,9028
BRN 1795711
InChIKey BGRWYDHXPHLNKA-UHFFFAOYSA-N
CAS DataBase Reference 10543-57-4(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII P411ED0N2B
NIST Chemistry Reference N,n,n',n'-tetraacetylethylenediamine(10543-57-4)
EPA Substance Registry System Tetraacetylethylenediamine (10543-57-4)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319
Precautionary statements  P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313
Safety Statements  22-24/25
WGK Germany  1
TSCA  Yes
HS Code  29241900
NFPA 704
1
0 0

Tetraacetylethylenediamine price More Price(12)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 86545 N,N,N′,N′-Tetraacetylethylenediamine technical, ≥90% (CHN) 10543-57-4 50g $76.1 2024-03-01 Buy
Sigma-Aldrich 86545 N,N,N′,N′-Tetraacetylethylenediamine technical, ≥90% (CHN) 10543-57-4 250g $206 2024-03-01 Buy
TCI Chemical T0946 N,N,N',N'-Tetraacetylethylenediamine >98.0%(GC) 10543-57-4 25g $68 2024-03-01 Buy
TCI Chemical T0946 N,N,N',N'-Tetraacetylethylenediamine 10543-57-4 100G $266 2024-03-01 Buy
Alfa Aesar L04353 N,N,N',N'-Tetraacetylethylenediamine, 99% 10543-57-4 50g $50.1 2021-12-16 Buy
Product number Packaging Price Buy
86545 50g $76.1 Buy
86545 250g $206 Buy
T0946 25g $68 Buy
T0946 100G $266 Buy
L04353 50g $50.1 Buy

Tetraacetylethylenediamine Chemical Properties,Uses,Production

Chemical Properties

Tetraacetylethylenediamine is off-white to beige granular powder

Uses

Tetraacetylethylenediamine (TAED) is a bleaching activator which is mainly used in detergents and additives for laundry washing and dishwashing. Typical concentrations of TAED range between 1.4% and 13% in these products. A small amount of the produced TAED is also used in bleaching of paper, textiles and for the generation of Peracetic acid.
Peroxide bleach activator for household detergents, paper pulp.

Uses

N,N,N',N'-Tetraacetylethylenediamine is used as a peroxide bleach activator in household detergents and for paper pulp. It also serves as an important component of laundry detergents and bleaches, where it is used as an activator for active oxygen bleaching agents such as sodium perborate, sodium percarbonate, sodium perphosphate and sodium persulfate. It reacts with the perhydroxyl anion HO2- in the presence of aqueous alkaline solution to prepare triacetylethylenediamine and diacetylethylenediamine with the release of peracetic acid, which is a fast acting bleaching agent.

Definition

ChEBI: Tetraacetylethylenediamine is a dicarboximide.

Preparation

Tetraacetylethylenediamine (TAED) is produced in a two stage process from ethylenediamine (ED) and acetic anhydride (Ac2O). ED is first diacetylated to DAED. In the second step DAED is subsequently converted with Ac2O via TriAED into TAED (Clariant, 1999). TAED is crystallized out of the reaction mixture, filtered, washed and dried, and if necessary also granulated. The raw materials used occur almost quantitatively in the product. Byproducts are not formed.
TAED was prepared by acetylation of diacetylethylenediamine (DAED) with acetic anhydride in a 5 L reactor coupled with a packed distillation column, 2.5 cm in inside diameter and 1 m in length. The reaction temperature was set at 135 °C and the reflux ratio at 6. The molar ratio of acetic anhydride to DAED was varied from 3 to 5. A TAED yield as high as 80% was obtained, higher by 15% than in the absence of distillation.

Health Hazard

TAED is of very low toxicity by all exposure routes examined. Up to 2 g/kg BW there is no acute toxicity. TAED is practically non-irritating to skin and eyes and there is no evidence of a sensitizing potential by skin contact. The only effect after repeated oral and dermal dosing was reversible centrilobular hypertrophy in the liver at high doses due to the induction of metabolizing enzymes. In a 90-day whole body inhalation study no adverse effects in the rat lung, respiratory tract or nasal mucosa were observed. Biokinetic data showed that TAED is rapidly absorbed from the rat intestine and largely metabolized via diacetylation to TriAED and DAED which are excreted in the urine.

871-78-3
108-24-7
10543-57-4
Synthesis of Tetraacetylethylenediamine from N,N'-DIACETYLETHYLENEDIAMINE and Acetic anhydride

Tetraacetylethylenediamine Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 337)Suppliers
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Hebei Guanlang Biotechnology Co., Ltd.
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Hebei Mojin Biotechnology Co., Ltd
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Hebei Yanxi Chemical Co., Ltd.
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Hebei Saisier Technology Co., LTD
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Ouhuang Engineering Materials (Hubei) Co., Ltd
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Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21691 55
Hefei TNJ Chemical Industry Co.,Ltd.
+86-0551-65418679 +86-18949832763 info@tnjchem.com China 2989 55

Related Qustion

View Lastest Price from Tetraacetylethylenediamine manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Tetraacetylethylenediamine pictures 2024-04-26 Tetraacetylethylenediamine
10543-57-4
US $60.00-23.00 / kg 1kg 99% 600tons Hebei Dangtong Import and export Co LTD
Tetraacetylethylenediamine pictures 2024-04-26 Tetraacetylethylenediamine
10543-57-4
US $10.00-1.00 / kg 1kg 99% 300tons Hebei Dangtong Import and export Co LTD
Tetraacetylethylenediamine pictures 2024-04-18 Tetraacetylethylenediamine
10543-57-4
US $18.00 / kg 1kg 99.8% 10000ton Ouhuang Engineering Materials (Hubei) Co., Ltd
n,n’-1,2-ethanediylbis[n-acetyl-acetamid N,N’-1,2-ethanediylbis[N-acetyl-Acetamide N,N’-1,2-ethanediylbis[N-acetylacetamide] N,N’-ethylenebis[N-acetylacetamide] N-Acetyl-N-[2-(diacetylamino)ethyl]acetamide TetraAcetylEthyleneDiamine(Taed) Mykon ATC Nikon A 1,2-Bis(diacetylamino)ethane Tetraacetylethylenediamine,90% Tetraacetylethylenediamine,99.5+% TETRAACETYLENEDIAMINE N,N'-Ethylenbis-(N-acetylacetamid) 1,2-Bis-(diacetamido)-ethane N,N'-(ethane-1,2-diyl)bis(N-acetylacetaMide) N,N,N',N'-Tetraacetylethylenediamine technical, >=90% (CHN) N,N,N',N'-Tetraacetylethylenediamine≥ 90% (HPLC) TETRACETYLETHYLENEDIAMINE TETRAACETYLETHYLENEDIAMINE N,N'-ETHYLENEBIS(DIACETAMIDE) N,N,N',N'-TETRAACETYLETHYLENEDIAMINE Acetamide, N,N'-1,2-ethanediylbis[N-acetyl- TAED Tetraacetylethylenediamine Tetraacetylethylenediamine ISO 9001:2015 REACH Mikon ATC Detergents Tetraacetylethylenediamine TEAD TAED TAEG N,N,N',N'-Tetraacetylethylenediamine 10543-57-4 C10H16O4N2 Nitrogen Compounds Organic Building Blocks Protected Amines Building Blocks Daily Chemical Usage bc0001