ChemicalBook >> CAS DataBase List >>Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
- CAS No.
- 35138-22-8
- Chemical Name:
- Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
- Synonyms
- Bis(cycloocta-1,5-dien)rho;ooctadiene)rhodium(Ⅰ)tetrafL;(1Z,5Z)-cycloocta-1,5-diene,rhodium;BIS(1,5-CYCLOOCTADIENE)RHODIUM(I) TETRA&;BIS(1,5-CYCLOOCTADIENE)RHODIUM TETRAFLUOROBORATE;BIS(1,5-CYCLOOCTADIEN)RHODIUM(I) TETRAFLUOROBORATE;BIS(1,5-CYCLOOCTADIENE)RHODIUM(I) TETRAFLUOROBORATE;BIS(CYCLOOCTA-1,5-DIEN)RHODIUM(I)-TETRAFLUOROBORATE;Bis(1,5-cyclooctadiene)rhodium(Ⅰ) tetrafluoroborate;Bis(cycloocta-1,5-diene)rhodium(I) tetrafluoroborate
- CBNumber:
- CB6666011
- Molecular Formula:
- C16H24BF4Rh
- Molecular Weight:
- 406.07
- MDL Number:
- MFCD00075045
- MOL File:
- 35138-22-8.mol
Last updated:2023-05-15 10:43:20
| Melting point | 210 °C |
|---|---|
| Density | 0.42 g/cm3 (20℃) |
| storage temp. | Inert atmosphere,Store in freezer, under -20°C |
| solubility | Chloroform (Slightly), Methanol (Slightly) |
| form | Powder |
| color | Red |
| PH | 7 (5g/l, H2O, 20℃) |
| Water Solubility | insoluble |
| Sensitive | Slightly air & moisture sensitive |
| Exposure limits |
ACGIH: TWA 1 mg/m3 NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3 |
| InChIKey | IEMMJJILGGBYNZ-GSLAGHMSSA-M |
| CAS DataBase Reference | 35138-22-8(CAS DataBase Reference) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS02,GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H228-H315-H317-H319-H335 | |||||||||
| Precautionary statements | P210-P240-P241-P280-P302+P352-P305+P351+P338 | |||||||||
| Hazard Codes | F,Xi | |||||||||
| Risk Statements | 11-34 | |||||||||
| Safety Statements | 16-45-36/37/39-26 | |||||||||
| RIDADR | UN 2921 | |||||||||
| WGK Germany | 2 | |||||||||
| Hazard Note | Irritant | |||||||||
| TSCA | No | |||||||||
| HazardClass | 8 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 28439000 | |||||||||
| NFPA 704 |
|
Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate price More Price(42)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 14694 | Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate | 35138-22-8 | 100mg | $124 | 2024-03-01 | Buy |
| TCI Chemical | B3961 | Bis(1,5-cyclooctadiene)rhodium(I) Tetrafluoroborate | 35138-22-8 | 1g | $653 | 2024-03-01 | Buy |
| TCI Chemical | B3961 | Bis(1,5-cyclooctadiene)rhodium(I) Tetrafluoroborate | 35138-22-8 | 100mg | $114 | 2024-03-01 | Buy |
| Alfa Aesar | 044031 | Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate | 35138-22-8 | 1g | $600 | 2023-06-20 | Buy |
| Alfa Aesar | 044031 | Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate | 35138-22-8 | 5g | $2600 | 2023-06-20 | Buy |
Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate Chemical Properties,Uses,Production
Uses
- Convenient catalyst precursor, for example, with (R,R)QuinoxP* for asymmetric alkylations and hydrogenations.
- Catalyst precursor with chiral biaryl bisphosphine ligands for [2+2+2] enantioenriched cycloadditions.
Chemical Properties
dark red
Uses
Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate is useful for hydrogenation, isomerization reactions and is also employed as a precursor for asymmetric hydrogenations. Furthermore, it is used in the synthesis of cationic COD-Rhodium complexes with phosphine ligands. In addition, it shows an important application for enantioselective hydrogenation and hydrosilylation.
Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate Preparation Products And Raw materials
Raw materials
1of2
Preparation Products
Global( 234)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29797 | 60 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 15928 | 58 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21691 | 55 |
| Nanjing Dolon Biotechnology Co.,Ltd. | 18905173768 | sales@dolonchem.com | CHINA | 2972 | 58 |
| Hubei Jusheng Technology Co.,Ltd. | 18871490254 | linda@hubeijusheng.com | CHINA | 28180 | 58 |
| Wuhan Pengo Technology.,Ltd. | +86-27-81330736 +86-13628634921 | sunny.w@boronicgroup.com | CHINA | 171 | 58 |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49390 | 58 |
| career henan chemical co | +86-0371-86658258 15093356674; | factory@coreychem.com | China | 29826 | 58 |
| Antai Fine Chemical Technology Co.,Limited | 18503026267 | info@antaichem.com | CHINA | 9641 | 58 |
| SIMAGCHEM CORP | +86-13806087780 | sale@simagchem.com | China | 17367 | 58 |
View Lastest Price from Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2020-11-16 | Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
35138-22-8
|
US $20.00 / KG | 1KG | 99% | 10000KG | Longyan Tianhua Biological Technology Co., Ltd | |
 |
2020-01-09 | Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
35138-22-8
|
US $9.80 / KG | 1g | ≥99% | 100kg | Career Henan Chemical Co |
-
- Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
35138-22-8
- US $20.00 / KG
- 99%
- Longyan Tianhua Biological Technology Co., Ltd
-
- Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
35138-22-8
- US $9.80 / KG
- ≥99%
- Career Henan Chemical Co
35138-22-8(Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate)Related Search:
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1of4
Bis(1,5-cyclooctadiene)rhodiuM(I) tetrafluoroborate,98% [Rh(COD)2]BF4
Bis(1,5-cyclooctadiene)rhodium(Ⅰ) tetrafluoroborate
Bis(cycloocta-1,5-diene)rhodium(I) tetrafluoroborate
(1Z,5Z)-cycloocta-1,5-diene,rhodium,tetrafluoroborate
RHODIUM(I) TETRAFLUOROBORATE 1,5-CYCLOOCTADIENE COMPLEX
Bis(cycloocta-1,5-dien)rhodium(I)-tetrafluoroborat for synthesis
BIS(CYCLOOCTA-1,5-DIEN)RHODIUM(I)-TETRAFLUOROBORATE
BIS(1,5-CYCLOOCTADIENE)RHODIUM(I) TETRAFLUOROBORATE
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BIS(1,5-CYCLOOCTADIENE)RHODIUM(I) TETRA&
Bis(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate,98+%
Bis(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate Also available as trifluoromethanesulfonate and hexafluorophosphate
Bis(1,5-cyclooctadiene)rhodiuM(I) tetrafluoroborate 1GR
ooctadiene)rhodium(Ⅰ)tetrafL
Bis(1,5-cyclooctadiene)rhodiuM(I) tetrafluoroborate, [Rh(COD)2]BF4
(1Z,5Z)-cycloocta-1,5-diene,rhodium
Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate ISO 9001：2015 REACH
Bis(cycloocta-1,5-dien)rho
Rhodium(1+), bis[(1,2,5,6-η)-1,5-cyclooctadiene]-, tetrafluoroborate(1-) (1:1)
bis[(1,2,5,6-η)-1,5-cyclooctadiene]-Rhodium(1+) tetrafluoroborate(1-) (1:1)
Bis[(1,2,5,6-n)-1,5-cyclooctadiene]-rhodium tetrafluoroborate
35138-22-8
2C8H12BF4Rh
C16H24BF4Rh
C16H24RhBF4
RhC8H122BF
RhCOD2BF4
RhC8H122BF4
C8H6O4XH2O
Catalysis and Inorganic Chemistry
Rh
organometallic complex