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Bis(acetonitrile)dichloropalladium(II)

Reaction
Bis(acetonitrile)dichloropalladium(II)
Bis(acetonitrile)dichloropalladium(II)
CAS No.
14592-56-4
Chemical Name:
Bis(acetonitrile)dichloropalladium(II)
Synonyms
(MeCN)2PdCl2;Bis(acetonitrile)palladiuM(II);bis(acetonitrile)dichloropalladium;PALLADIUM DICHLOROBIS(ACETONITRILE);PALLADIUM-BIS-ACETONITRIL-DICHLORIDE;BIS(ACETONITRILE)PALLADIUM()CHLORIDE;Palladium, bis(acetonitrile)dichloro-;Palladium(II)chloro-bis(acetonitrile);Bis(cyanomethyl)dichloropalladium(IV);Bis(acetonitrile)dichloropalladium(Ⅱ)
CBNumber:
CB8245652
Molecular Formula:
C4H6Cl2N2Pd
Formula Weight:
259.43
MOL File:
14592-56-4.mol

Bis(acetonitrile)dichloropalladium(II) Properties

Melting point:
300 °C
storage temp. 
Room temperature.
solubility 
Soluble in acetonitrile, acetone, chloroform
form 
Fine Crystalline Powder
color 
Orange to rust-brown
Water Solubility 
insoluble
CAS DataBase Reference
14592-56-4(CAS DataBase Reference)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  T,Xn
Risk Statements  23/24/25-36/37/38-20/21/22
Safety Statements  16-27-36/37-45-36-26
RIDADR  UN 3077 9/PG 3
WGK Germany  3
HazardClass  6.1
PackingGroup  III
HS Code  28439090
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H301 Toxic if swalloed Acute toxicity,oral Category 3 Danger P264, P270, P301+P310, P321, P330,P405, P501
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning P264, P270, P301+P312, P330, P501
H311 Toxic in contact with skin Acute toxicity,dermal Category 3 Danger P280, P302+P352, P312, P322, P361,P363, P405, P501
H312 Harmful in contact with skin Acute toxicity,dermal Category 4 Warning P280,P302+P352, P312, P322, P363,P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning P264, P280, P305+P351+P338,P337+P313P
H331 Toxic if inhaled Acute toxicity,inhalation Category 3 Danger P261, P271, P304+P340, P311, P321,P403+P233, P405, P501
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P311 Call a POISON CENTER or doctor/physician.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405 Store locked up.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P501 Dispose of contents/container to..…

Bis(acetonitrile)dichloropalladium(II) price More Price(11)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 225657 Bis(acetonitrile)dichloropalladium(II) 99% 14592-56-4 500mg $47.1 2017-11-08 Buy
Sigma-Aldrich 225657 Bis(acetonitrile)dichloropalladium(II) 99% 14592-56-4 5g $258 2017-11-08 Buy
TCI Chemical B1676 Bis(acetonitrile)palladium(II) Dichloride >98.0%(T) 14592-56-4 1g $72 2017-11-08 Buy
TCI Chemical B1676 Bis(acetonitrile)palladium(II) Dichloride >98.0%(T) 14592-56-4 5g $300 2017-11-08 Buy
Alfa Aesar 10002 Bis(acetonitrile)dichloropalladium(II), Pd 40.5% 14592-56-4 5g $407 2017-11-08 Buy

Bis(acetonitrile)dichloropalladium(II) Chemical Properties,Uses,Production

Reaction

  1. Catalyst for the cyclization of δ-acetylenic carboxylic acids to butenolides.
  2. Catalyst for the aza-Michael reaction of carbamates with enones.
  3. Catalyst for the rearrangement of allylic imidates to allylic amides.
  4. Catalyst for the Nazarov cyclization of α-alkoxy dienones.
  5. Catalyst for the diamination of conjugated dienes.
  6. Three component Michael addition, cyclization, cross-coupling reaction.
  7. C-H activation of indoles.
  8. Catalyst used for the direct C-H arylation of isoxazoles at the 5 position.

Chemical Properties

dark yellow powder

Uses

suzuki reaction

Bis(acetonitrile)dichloropalladium(II) Preparation Products And Raw materials

Raw materials

Preparation Products


Bis(acetonitrile)dichloropalladium(II) Suppliers

Global( 198)Suppliers
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