ChemicalBook >> CAS DataBase List >>2,2'-DIBROMO-1,1'-BINAPHTHYL

2,2'-DIBROMO-1,1'-BINAPHTHYL

CAS No.
74866-28-7
Chemical Name:
2,2'-DIBROMO-1,1'-BINAPHTHYL
Synonyms
SKL192;JACS-74866-28-7;Binaphthalene dibromide;2,2'-diboromo-binaphthyl;2,2`-DibroMo-1,1`-Binaphtyl;1,1'-Bi(2-bromonaphthalene);2,2'-Dibromo-1,1'-binapthyl;2,2'-DIBROMO-1,1'-DINAPHTHYL;2,2'-DIBROMO-1,1'-BINAPHTHYL;2,2'-Dibromo-1,1'-binaphthyl
CBNumber:
CB8270540
Molecular Formula:
C20H12Br2
Molecular Weight:
412.12
MDL Number:
MFCD00188005
MOL File:
74866-28-7.mol
MSDS File:
SDS
Last updated:2023-06-08 17:06:35

2,2'-DIBROMO-1,1'-BINAPHTHYL Properties

Melting point 178-183 °C
Boiling point 178-183°C
Density 1.614±0.06 g/cm3(Predicted)
Flash point 178-183°C
storage temp. Sealed in dry,Room Temperature
solubility soluble in Toluene
form Powder
color white to off-white
Water Solubility Sparingly Soluble in water.
CAS DataBase Reference 74866-28-7(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302-H413
Precautionary statements  P273-P301+P312+P330
Hazard Codes  Xn
Risk Statements  36/37/38-22
Safety Statements  26-36/37/39
WGK Germany  3
HS Code  2903.99.8001
NFPA 704
1
2 0

2,2'-DIBROMO-1,1'-BINAPHTHYL price More Price(19)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 676438 2,2′-Dibromo-1,1′-binaphthyl 96% 74866-28-7 1g $78.7 2024-03-01 Buy
TCI Chemical D4221 2,2'-Dibromo-1,1'-binaphthyl >96.0%(GC) 74866-28-7 1g $59 2024-03-01 Buy
TCI Chemical D4221 2,2'-Dibromo-1,1'-binaphthyl >96.0%(GC) 74866-28-7 5g $216 2024-03-01 Buy
Alfa Aesar H26987 (±)-2,2'-Dibromo-1,1'-binaphthyl, 96% 74866-28-7 1g $72.65 2024-03-01 Buy
Alfa Aesar H26987 (±)-2,2'-Dibromo-1,1'-binaphthyl, 96% 74866-28-7 5g $234.65 2024-03-01 Buy
Product number Packaging Price Buy
676438 1g $78.7 Buy
D4221 1g $59 Buy
D4221 5g $216 Buy
H26987 1g $72.65 Buy
H26987 5g $234.65 Buy

2,2'-DIBROMO-1,1'-BINAPHTHYL Chemical Properties,Uses,Production

Uses

The synthesis of this class of compounds relies on the lithiation of racemic 2,2'-dibromo-1,1'-binaphthyl with t-BuLi followed by addition of Ph 2 PCl.

Purification Methods

Purify the binaphthyl by chromatography through a silica gel column (70-230mesh) using hexane as eluent. It gives pale yellow crystals from EtOH with m 187.3-187.9o. The R-(+)-enantiomer [86688-08-6] crystallises from hexane with m 157-157.5o and [] D +32.9o (c 1, pyridine) [Brown et al. J Org Chem 50 4345 1985]. [Okamoto et al. J Am Chem Soc 103 69711981, Beilstein 5 III 2465.]

2,2'-DIBROMO-1,1'-BINAPHTHYL Preparation Products And Raw materials

Global( 127)Suppliers
Supplier Tel Email Country ProdList Advantage
Henan Fengda Chemical Co., Ltd
+86-371-86557731 +86-13613820652 info@fdachem.com China 16803 58
ATK CHEMICAL COMPANY LIMITED
+undefined-21-51877795 ivan@atkchemical.com China 32686 60
career henan chemical co
+86-0371-86658258 sales@coreychem.com China 29914 58
Hubei xin bonus chemical co. LTD
86-13657291602 linda@hubeijusheng.com CHINA 22968 58
Chongqing Chemdad Co., Ltd
+86-023-61398051 +8613650506873 sales@chemdad.com China 39916 58
Alchem Pharmtech,Inc.
8485655694 sales@alchempharmtech.com United States 63711 58
CONIER CHEM AND PHARMA LIMITED
+8618523575427 sales@conier.com China 49390 58
Antai Fine Chemical Technology Co.,Limited
18503026267 info@antaichem.com CHINA 9641 58
Zhengzhou Alfa Chemical Co.,Ltd
+8618530059196 sale04@alfachem.cn China 12567 58
Dayang Chem (Hangzhou) Co.,Ltd.
571-88938639 +8617705817739 info@dycnchem.com CHINA 52867 58

View Lastest Price from 2,2'-DIBROMO-1,1'-BINAPHTHYL manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
(+/-)-2,2-Dibromo-1,1-Binaphthyl pictures 2024-01-14 (+/-)-2,2-Dibromo-1,1-Binaphthyl
74866-28-7
US $5.00-0.50 / KG 1KG 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
 2,2'-DIBROMO-1,1'-BINAPHTHYL pictures 2019-07-06 2,2'-DIBROMO-1,1'-BINAPHTHYL
74866-28-7
US $8.80 / KG 1KG 97%-99% 100kg Career Henan Chemical Co
2,2'-DIBROMO-1,1'-BINAPHTHYL 2,2'-DIBROMO-1,1'-DINAPHTHYL RACEMIC-2,2'-DIBROMO-1,1'-BINAPHTHYL 2,2'-Dibromo-1,1'-binapthyl racemic-2,2'-Dibromo-1,1'-binaphthyl,99% 1,1'-Bi(2-bromonaphthalene) 2,2'-Dibromo-1,1'-binaphthalene rac-2,2'-Dibromo-1,1'-binaphthyl, rac-2,2'-Dibromo-1,1'-binaphthyl,99% racemic-2,2'-Dibromo-1,1'-binaphthyl, min. 96% 2,2`-DibroMo-1,1`-Binaphtyl 2-broMo-1-(2-broMonaphthalen-1-yl)naphthalene 2,2'-Dibromo-1,1'-binaphthyl 96% 2,2'-diboromo-binaphthyl JACS-74866-28-7 2,2'-Dibromo-1,1'-binaphthyl> 1,1'-Binaphthalene, 2,2'-dibromo- ()-2,2-Dibromo-1,1-binaphthyl 2,2'-Dibromo-1,1'-binaphthyl (rac) SKL192 (+/-)-2,2-Dibromo-1,1-Binaphthyl (+/-)-2,2-Dibromo-l,l-Binaphthyl Binaphthalene dibromide 2,2'-Dibromo-1,1'-binaphthyl 2-bromo-1-(2-bromo-1-naphthyl)naphthalene 74866-28-7 燙20H12Br2 C20H12Br2 Aryl C13 to C37+ Halogenated Hydrocarbons