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Potassium thioacetate

CAS No.
10387-40-3
Chemical Name:
Potassium thioacetate
Synonyms
Potassium ethanethioate;MeCOSK;KTAA;Kaliumthioacetat;Potassium thioacete;Potassium Thioacetic;Potassium thioacetat;Potassium thioactate;Potasium thioacetate;POTASSIUM THIOACETATE
CBNumber:
CB9316520
Molecular Formula:
C2H3KOS
Molecular Weight:
114.21
MDL Number:
MFCD00137704
MOL File:
10387-40-3.mol
MSDS File:
SDS
Last updated:2024-04-09 22:15:29

Potassium thioacetate Properties

Melting point 173-176 °C (lit.)
Density 1.58 g/cm3
storage temp. Inert atmosphere,Room Temperature
solubility soluble
form Crystalline Powder, Crystals or Chunks
color White to light brown
Water Solubility soluble
Sensitive Air Sensitive & Hygroscopic
Hydrolytic Sensitivity 4: no reaction with water under neutral conditions
BRN 3595448
CAS DataBase Reference 10387-40-3(CAS DataBase Reference)
FDA UNII ZY58K327HN
EPA Substance Registry System Ethanethioic acid, potassium salt (10387-40-3)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P280a-P304+P340-P305+P351+P338-P405-P501a
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36-37/39
RIDADR  UN 3335
WGK Germany  3
3-9-13-23
TSCA  Yes
HazardClass  9
HS Code  29309070
NFPA 704
0
2 0

Potassium thioacetate price More Price(36)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 241776 Potassium thioacetate 98% 10387-40-3 25g $64 2024-03-01 Buy
Sigma-Aldrich 241776 Potassium thioacetate 98% 10387-40-3 100g $166 2024-03-01 Buy
TCI Chemical T2030 S-Potassium Thioacetate >97.0%(T) 10387-40-3 25g $54 2024-03-01 Buy
TCI Chemical T2030 S-Potassium Thioacetate >97.0%(T) 10387-40-3 250g $269 2024-03-01 Buy
Alfa Aesar L05405 Potassium thioacetate, 98% 10387-40-3 25g $57.5 2024-03-01 Buy
Product number Packaging Price Buy
241776 25g $64 Buy
241776 100g $166 Buy
T2030 25g $54 Buy
T2030 250g $269 Buy
L05405 25g $57.5 Buy

Potassium thioacetate Chemical Properties,Uses,Production

Chemical Properties

white to light brown crystalline powder, crystals

Uses

Potassium thioacetate is used for palladium mediated coupling with aryl halides and triflates leading to S-arylthioacetates and derivatives. It is also used as a reagent in the conversion of halides to thiols.

Uses

Potassium Thioacetate is the potassium salt of Thioacetic Acid, a commonly used reagent in organic synthesis for the introduction of thiol groups in molecules.

Application

Potassium thioacetate is an organosulfur compound and a salt with the formula CH3COS−K+. This white, water-soluble solid is used as a reagent for preparing thioacetate esters and other derivatives . It acts as a sulfur source in the synthesis of sulfur-containing organic compounds for the synthesis of heterocycles, polymers, transition-metal ligands, nanoparticles, bioactive compounds and macromolecular inclusion complexes. It is also used for palladium mediated coupling with aryl halides and triflates leading to S-arylthioacetates and derivatives and it is also used as a reagent in the conversion of halides to thiols.

Reactions

Thioacetate is also a class of sulfur-containing nucleophiles, of which potassium thioacetate is the most widely used reagent. Potassium thioacetate reacts with organic halides to form thioesters, which are often used as thiol-protecting groups.In the classical reaction, potassium thioacetate replaces the bromine atom to form a thiol in which the thioester formed in the first step is subjected to a nucleophilic addition elimination reaction to obtain a thiol via hydrolysis, alcoholysis or ammonolysis. Unlike the thiol formation from bromine and thiourea, this method is not strictly limited to polystyrenes. It can also be extended to poly(meth)acrylate systems. It is important that there is no observation of ester hydrolysis during the process.

507-09-5
10387-40-3
Synthesis of Potassium thioacetate from Thioacetic acid
Global( 405)Suppliers
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Hebei Mojin Biotechnology Co., Ltd
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View Lastest Price from Potassium thioacetate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Potassium thioacetate pictures 2024-04-09 Potassium thioacetate
10387-40-3
US $0.00-0.00 / Kg 1Kg 99.9% 200tons airuikechemical co., ltd.
Potassium thioacetate pictures 2023-09-21 Potassium thioacetate
10387-40-3
US $0.00 / kg 1kg 99.0% 500 Taixing Foreign Trade Nanjing Co., Ltd.
Potassium thioacetate pictures 2023-08-24 Potassium thioacetate
10387-40-3
US $100.00 / KG 1KG 99% 5000KG Hebei Mojin Biotechnology Co., Ltd
Potassium Thioacetic Potassium thioacete Acetic acid, thio-, potassium salt Potassium thioethanoate Potassium thioacetate,98% Potasium thioacetate Potassium thioacetat PotassiuM thioacetate, 98% 25GR PotassiuM thioacetate, 98% 5GR potassium 2-thioxoacetate MERCAPTOACETIC ACID, POTASSIUM SALT KTAA Ethanethioic acid potassium salt Ethanethioic acid potassium salt, Thioacetic acid potassium salt, Thiolacetic acid potassium salt THIOACETIC ACID S-POTASSIUM SALT THIOACETIC ACID POTASSIUM THIOACETIC ACID POTASSIUM SALT thiolacetic acid potassium salt TIOACETIC ACID POTASSIUM SALT POTASSIUM THIOLACETATE POTASSIUM THIOACETATE POTASSIUM THIOACETIC ACID S-POTASSIUM THIOACETATE Potassium thioacetate/Thioacetic acid potassium salt Potassium thioacetate ISO 9001:2015 REACH Kaliumthioacetat Potassium thioaccetate MeCOSK Potassium ethanethioate Potassium thioactate 10387-40-3 10387-10-3 C2H3KOS C2H3OSK C2H4OSK CH3COSK Inorganic Salts Synthetic Reagents Pharmaceutical intermediates 10387-40-3