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Diphenylphosphine

Diphenylphosphine Suppliers list
Company Name: Henan Tianfu Chemical Co.,Ltd.
Tel: 0371-55170693
Email: info@tianfuchem.com
Products Intro: CAS:829-85-6
Purity:99% Package:500G;1KG;5KG;25KG
Company Name: Henan DaKen Chemical CO.,LTD.
Tel: +86-371-55541817
Email: inquiry@dakenchem.com
Products Intro: Product Name:Diphenylphosphine
CAS:829-85-6
Purity:98.0% Package:100grams;500grams;1kg;5kg;10kg;25kg
Company Name: Beijing Donghualituo Techonlogy Development Co.,Ltd.  Gold
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Products Intro:Product Name:Diphenylphosphine
CAS:829-85-6
Company Name: Shanghai Chang-Gen Chemical Technology Co., Ltd.  Gold
Tel:+86 (21) 6910-6824
Email:sales@shcgchem.com
Products Intro:CAS:829-85-6
Purity:98% Package:1800.00RMB/1KG
Company Name: BeiJing Greenchem Technology Co.,Ltd.  Gold
Tel:010-82156189;010-60281050;13811208955
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Products Intro:Product Name:Diphenylphosphine
CAS:829-85-6
Purity:98%
Diphenylphosphine Basic information
Organophosphorus compound Uses
Product Name:Diphenylphosphine
Synonyms:PHOSPHINE, DIPHENYL;DIPHENYLPHOSPHINE;AURORA KA-1107;Diphenyl-phosphane;Diphenylphosphin;Diphenyl phospine;Diphenylphosphine,99%;Diphenylphosphine,99%(10wt%inhexane)
CAS:829-85-6
MF:C12H11P
MW:186.19
EINECS:212-591-4
Product Categories:Catalysis and Inorganic Chemistry;Phosphorus Compounds;Phosphorus Precursors;organophosphorus ligand;organophosphine ligand;Pyrazoles
Mol File:829-85-6.mol
Diphenylphosphine Structure
Diphenylphosphine Chemical Properties
Boiling point 280 °C(lit.)
density 1.07 g/mL at 25 °C(lit.)
vapor pressure 2 mm Hg ( 110 °C)
refractive index n20/D 1.625(lit.)
Fp -18°C (Hexane)
storage temp. 2-8°C
form liquid
color colorless
Water Solubility Miscible with ethanol, ether, benzene, concentrated hydrochloric acid. Immiscible with water.
Sensitive Air & Moisture Sensitive
InChIKeyGPAYUJZHTULNBE-UHFFFAOYSA-N
CAS DataBase Reference829-85-6(CAS DataBase Reference)
NIST Chemistry ReferencePhosphine, diphenyl-(829-85-6)
Safety Information
Hazard Codes F,Xi
Risk Statements 17-36/37/38
Safety Statements 26-36
RIDADR UN 2845 4.2/PG 1
WGK Germany 3
8-10-13-23
HazardClass 4.2
PackingGroup I
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
Diphenylphosphine Usage And Synthesis
Organophosphorus compoundDiphenylphosphine is commonly used in laboratory as organic phosphorus compound, it is unpleasant odor colorless liquid, and it is pungent, it is easily oxidized in air and can cause spontaneous combustion, it is sensitive to air and light, it need the protection of nitrogen. It can be used as precursor to synthesize some organic phosphine ligand. By deprotonation, it can be converted to diphenylphosphine compound: Ph2PH + nBuLi → Ph2PLi + nBuH, such as 1,2-bis (diphenylphosphino) ethane and 1,3-bis (diphenylphosphino) propane phosphine ligands etc, Wittig-Horner reagents and the synthesis of quaternary phosphonium salt is usually by means of diphenylphosphino alkylation to achieve.
Diphenylphosphine such as sodium and lithium diphenylphosphine and diphenylphosphine compound can add to carbon heteroatom double bond as nucleophile. For example, in the condition of concentrated hydrochloric acid at 100℃, diphenylphosphine can add to aldehyde carbon atoms of benzaldehyde: Ph2PH + PhCHO → Ph2P (O) CH2Ph, when compares with tertiary phosphine, alkalinity of diphenylphosphine is weaker. The pKa of conjugate acid diphenylphosphine is 0.03: Ph2PH2 + → Ph2PH + H +
Preparation: Lithium diphenylphosphine can generated by inexpensive triphenylphosphine and the with the cancellation of water can obtain diphenylphosphine: (1) PPh3 + 2 Li → LiPPh2 + LiPh (2) LiPPh2 + H2O → Ph2PH + LiOH.
The above information is edited by the chemicalbook of Wang Xiaodong.
UsesIt can be used the intermediates of organic, catalysts.
Chemical PropertiesClear colorless to slightly yellow liquid
Usessuzuki reaction
UsesDiphenylphosphine is used in the synthesis of aminophosphines for application as catalysts. It is also used in the preparation of chiral palladacycles with N-heterocyclic carbene ligands as catalysts.
Tag:Diphenylphosphine(829-85-6) Related Product Information
(CYCLOPENTADIENYLIDENE)TRIPHENYLPHOSPHORANE 1,3-Bis(diphenylphosphino)propane TETRAPHENYLBIPHOSPHINE TRIPHENYLPHOSPHINE DIBROMIDE Diphenylphosphinic acid BIS(PENTAFLUOROPHENYL)PHENYLPHOSPHINE Triphenylphosphine oxide 1,2-Bis(diphenylphosphino)ethane (FORMYLMETHYLENE)TRIPHENYLPHOSPHORANE 1,4-Bis(diphenylphosphino)butane Diphenylphosphine Chlorodiphenylphosphine Diphenyldimethoxysilane 1,5-Diphenylcarbazide Ethyl diphenylphosphinite Dichlorodiphenylsilane Diphenylthiocarbazide 1,3-Diphenyl-2-thiourea