- Ethyl 4-bromobenzoate
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- $15.00 / 1KG
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2021-08-12
- CAS:5798-75-4
- Min. Order: 1KG
- Purity: 99%+ HPLC
- Supply Ability: Monthly supply of 1 ton
- Ethyl 4-bromobenzoate
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- $1.00 / 1KG
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2019-07-06
- CAS:5798-75-4
- Min. Order: 1KG
- Purity: 99%
- Supply Ability: Customized
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| | Ethyl 4-bromobenzoate Basic information |
| | Ethyl 4-bromobenzoate Chemical Properties |
| Hazard Codes | Xi,N | | Risk Statements | 36/37/38-51/53 | | Safety Statements | 24/25-61 | | RIDADR | UN 3082 9 / PGIII | | WGK Germany | 3 | | Hazard Note | Irritant | | TSCA | Yes | | HS Code | 29163990 |
| | Ethyl 4-bromobenzoate Usage And Synthesis |
| Chemical Properties | clear colorless to yellow liquid | | Uses | Ethyl 4-bromobenzoate undergoes reduction with potassium diisobutyl-t-butoxyaluminum hydride (PDBBA) at 0°C to yield aldehydes. Reaction of ethyl 4-bromobenzoate and substituted benzyl chloride with zinc dust and a Pd catalyst is reported. | | Synthesis Reference(s) | Synthetic Communications, 22, p. 1851, 1992 DOI: 10.1080/00397919208021316
Synthesis, p. 191, 1983 | | General Description | Ethyl 4-bromobenzoate is an ester having electron-withdrawing substituent. It undergoes reduction with potassium diisobutyl-t-butoxyaluminum hydride (PDBBA) at 0°C to yield aldehydes. Reaction of ethyl 4-bromobenzoate and substituted benzyl chloride with zinc dust and a Pd catalyst is reported. |
| | Ethyl 4-bromobenzoate Preparation Products And Raw materials |
| Raw materials | Benzoic acid, 4-[[(trifluoromethyl)sulfonyl]oxy]-, ethyl ester-->2-(4-Bromophenyl)-2-oxoacetic acid-->4-Bromobenzyl alcohol-->(4-BROMO-PHENYL)-OXO-ACETALDEHYDE-->Benzenediazonium, 4-(ethoxycarbonyl)-, tetrafluoroborate(1-)-->1-CARBETHOXYIMIDAZOLE-->potassium ethyl oxalate-->4-BROMOBENZALDEHYDE DIETHYL ACETAL | | Preparation Products | ETHYL 4-ACETYLBENZOATE-->4-ETHYNYL-BENZOIC ACID-->ETHYL 4-(5-FORMYL-2-FURYL)BENZOATE-->2-(4-bromophenyl)-1,3,4-oxadiazole-->ETHYL 4-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZOATE-->4,4'-Bis(hydroxymethyl)biphenyl-->Ethyl 4-etoxybenzoate-->1,1,1-Trifluoro-2-hexanone |
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