- GLYCINE ANHYDRIDE
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- $0.00 / 1kg
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2022-11-24
- CAS:106-57-0
- Min. Order: 1kg
- Purity: 99%
- Supply Ability: 100tons
- GLYCINE ANHYDRIDE
-
- $1.00 / 1g
-
2019-12-25
- CAS:106-57-0
- Min. Order: 1g
- Purity: 99%
- Supply Ability: 1000KGS
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| | GLYCINE ANHYDRIDE Basic information |
| Product Name: | GLYCINE ANHYDRIDE | | Synonyms: | PIPERAZINE-2,5-DIONE;2,5-Dioxopiperazin;2,5-Dioxopiperazine lactam;2,5-Piperazindion;alpha,gamma-Diacipiperazine;Cyclic(glycylglycyl);Cyclo(glycylglycyl);Cyclodiglycine | | CAS: | 106-57-0 | | MF: | C4H6N2O2 | | MW: | 114.1 | | EINECS: | 203-411-5 | | Product Categories: | | | Mol File: | 106-57-0.mol |  |
| | GLYCINE ANHYDRIDE Chemical Properties |
| Melting point | >300 °C (lit.) | | Boiling point | 213.59°C (rough estimate) | | density | 1.3565 (rough estimate) | | refractive index | 1.4487 (estimate) | | storage temp. | Store below +30°C. | | solubility | 142g/l | | pka | 12.88±0.20(Predicted) | | form | Crystalline Powder | | color | White to slightly yellow | | Water Solubility | Soluble in water (142mg/L). | | Merck | 14,7466 | | BRN | 112112 | | InChIKey | BXRNXXXXHLBUKK-UHFFFAOYSA-N | | CAS DataBase Reference | 106-57-0(CAS DataBase Reference) | | EPA Substance Registry System | 2,5-Piperazinedione (106-57-0) |
| Safety Statements | 24/25 | | WGK Germany | 3 | | RTECS | TL6325250 | | TSCA | Yes | | HS Code | 29335990 |
| | GLYCINE ANHYDRIDE Usage And Synthesis |
| Chemical Properties | white to slightly yellow crystalline powder | | Uses | 2,5-Piperazinedione, can be used as an intermediate in the preparation of various pharmaceutical and biologically active compounds. It can be used in the synthesis of dipeptide isosteres by cross-metathesis. | | Definition | ChEBI: A cyclic peptide that is piperazine in which the hydrogens at positions 2 and 5 are replaced by oxo groups. | | Synthesis Reference(s) | Journal of the American Chemical Society, 87, p. 4646, 1965 DOI: 10.1021/ja00948a047 | | Purification Methods | Recrystallise glycine anhydride from H2O (plates) and it can be sublimed (slowly) at 260o or at 140-170o/0.5mm. The dihydrochloride has m 129-130o and is prepared by dissolving it in conc HCl and adding EtOH to crystallisation point; dry it in a vacuum. The bis-1-naphthylurethane has m 232o(dec), and the diperchlorate has m 117o (hygroscopic). [MS: Johnstone J Chem Soc, Perkin Trans 1 1297 1975, NMR: Blaha & Samek Collect Czech Chem Commun 32 3780 1967, Sauborn J Phys Chem 36 179 1932, Corey J Am Chem Soc 60 1599 1938, Beilstein 24 IV 1070.] |
| | GLYCINE ANHYDRIDE Preparation Products And Raw materials |
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