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| VANADIUM(II) CHLORIDE Basic information |
| VANADIUM(II) CHLORIDE Chemical Properties |
Melting point | 910(subl.) | Boiling point | 910°C | density | 3.09 g/mL at 25 °C(lit.) | solubility | reacts with H2O; soluble in ethanol,ethyl ether | form | green hexagonal plates | color | green hexagonal, hexane plates | Water Solubility | decomposed in hot H2O; soluble alcohol, ether [HAW93] | Crystal Structure | CdI2 type | crystal system | Three sides | Space group | P3m1 | Lattice constant | a/nm | b/nm | c/nm | α/o | β/o | γ/o | V/nm3 | 0.3601 | 0.3601 | 0.5835 | 90 | 90 | 120 | 0.0655 |
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Hazard Codes | C | Risk Statements | 20/21/22-34-22 | Safety Statements | 26-27-36/37/39-45 | RIDADR | UN 3260 8/PG 2 | WGK Germany | 3 | RTECS | YW1575000 | F | 3-10 | HazardClass | 8 | PackingGroup | III | HS Code | 2827398590 |
| VANADIUM(II) CHLORIDE Usage And Synthesis |
Chemical Properties | apple green; hexagonal plates; strong reducing agent; preparation: heating VCl3 in N2 atmospheric, followed by sublimation in N2 atmospheric; used to purify HCl by removing arsenic [HAW93] | Synthesis | Rapid disproportionation of VCl3 according to the above equation
can be achieved at 800°C in a stream of high-purity N2. The VCl4 is carried away by the N2 stream (4 bubbles/sec), while the VCl2
remains in the reactor tube. The temperature should not exceed
850°C, to avoid loss of VCl2 by sublimation. The reaction is fairly
fast; for example, the reaction of 20 g. of VCl3 takes 2 hours. | Solubility in organics |
Insoluble in alcohol or ether.
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| VANADIUM(II) CHLORIDE Preparation Products And Raw materials |
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