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| | Chromium(III) acetylacetonate Basic information | | Uses |
| | Chromium(III) acetylacetonate Chemical Properties |
| Melting point | 210 °C(lit.) | | Boiling point | 340 °C(lit.) | | density | 1,35 g/cm3 | | vapor pressure | 0Pa at 20℃ | | Fp | >200°C | | storage temp. | Store below +30°C. | | solubility | 11g/l | | form | Crystalline Powder, Crystals, and/or Chunks | | color | Purple to maroon | | Specific Gravity | 1.35 | | PH | 6 (1g/l, H2O, 20℃) | | Water Solubility | 11 g/L (20 ºC) | | Hydrolytic Sensitivity | 1: no significant reaction with aqueous systems | | BRN | 4148971 | | Exposure limits | NIOSH: IDLH 25 mg/m3; TWA 0.5 mg/m3 | | LogP | 0.4 at 20℃ | | NIST Chemistry Reference | Chromium, tris(2,4-pentanedionato-o,o')-(21679-31-2) | | EPA Substance Registry System | Chromium(III) acetylacetonate (21679-31-2) |
| Hazard Codes | Xi | | Risk Statements | 36/37/38 | | Safety Statements | 22-26-36-37/39 | | WGK Germany | 2 | | RTECS | GB7575000 | | TSCA | Yes | | HS Code | 29420000 | | Toxicity | LD50 orally in Rabbit: 3360 mg/kg LD50 dermal Rabbit 6350 mg/kg |
| | Chromium(III) acetylacetonate Usage And Synthesis |
| Uses | Chromium(III) acetylacetonate is a useful research chemical. | | Chemical Properties | PURPLE CRYSTALLINE POWDER | | Uses | Catalyst in the oxidation of methacrylic esters by hydrogen peroxide, MOCVDChromium(III) 2,4-pentanedionate is used in the reduction of detonation of nitromethane. It is also used in NMR spectroscopy as a relaxation agent due to its solubility in nonpolar organic solvents and its paramagnetism. Further, it is involved in the modification of the surface properties of solid polyurethanes. | | Uses | Chromium(III) acetylacetonate may be used as an active site in the formation of redox systems for the fabrication of flow batteries. It may also be used as a precursor for chromium nitride based metallic coatings. | | General Description | Chromium(III) acetylacetonate is an acidopentamminechromium (111) salt, which is a crystalline material that can be prepared by treatment of precipitated hydrous chromium(III) oxide with acetylacetone. | | Flammability and Explosibility | Not classified | | Safety Profile | Moderately toxic by
ingestion. Mildly toxic by s h contact.
When heated to decomposition it emits
acrid smoke and irritating fumes. See also
CHROMIUM COMPOUNDS. | | Purification Methods | Purify it by dissolving 6g in hot *C6H6 (20mL) and adding 75mL of pet ether slowly. Cool to room temperature then chill on ice, filter off and dry in air to give 2.9g. It also crystallises from EtOH. It is soluble in heptane, *C6H6, toluene and pentane-2,4-dione at 20-40o. It forms a 1:2 complex with CHCl3. [Fernelius & Blanch Inorg Synth V 130 1957, Steinbach & Burns J Am Chem Soc 80 1839 1958, Beilstein 1 H 782, 1 II 836, 1 IV 3673.] |
| | Chromium(III) acetylacetonate Preparation Products And Raw materials |
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