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1,4-Diamino anthraquinone

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CAS:128-95-0
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Products Intro: Product Name:1,4-Diamino anthraquinone
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Products Intro: Product Name:TIANFU-CHEM CAS NO.128-95-0 1,4-Diamino anthraquinone
CAS:128-95-0
Purity:99% Package:25KG;5KG;1KG

1,4-Diamino anthraquinone manufacturers

  • Disperse Violet 1
  • Disperse Violet 1  pictures
  • $1058.00 / 25kg
  • 2024-04-24
  • CAS:128-95-0
  • Min. Order: 25kg
  • Purity: 99%
  • Supply Ability: 10 tons
1,4-Diamino anthraquinone Basic information
Product Name:1,4-Diamino anthraquinone
Synonyms:1,4-diamino-10-anthracenedione;1,4-Diamino-9,10-anthraquinone;1,4-Diaminoanthra-9,10-quinone;1,4-Diaminoanthrachinon;1,4-diamino-anthraquinon;1,4-diaminoanthraquinone(ci61100);CIBACET VIOLET 2R;CELANTHRENE RED VIOLET R
CAS:128-95-0
MF:C14H10N2O2
MW:238.24
EINECS:204-922-6
Product Categories:Building Blocks;C13 to C14;Carbonyl Compounds;Chemical Synthesis;Ketones;Organic Building Blocks;Indazoles;Solvent Dyestuff;Amines;Aromatics;Intermediates & Fine Chemicals;Pharmaceuticals;Protein Kinase Inhibitors and Activators;Amine Monomers;Monomers;Primary Amines;Aminoanthraquinones;Anthraquinones;Highly Purified Reagents;Other Categories;Refined Products by Sublimation;Intermediates of Dyes and Pigments
Mol File:128-95-0.mol
1,4-Diamino anthraquinone Structure
1,4-Diamino anthraquinone Chemical Properties
Melting point 265-269 °C(lit.)
Boiling point 380.84°C (rough estimate)
density 1.44 g/cm3 (20℃)
vapor pressure <1 hPa (25 °C)
refractive index 1.6500 (estimate)
Fp 340 °C
storage temp. Keep in dark place,Inert atmosphere,Room temperature
solubility Soluble in benzene, pyridine, the difficulties, slightly soluble in hot aniline acetate, ethanol.
pka1.17±0.20(Predicted)
form Solid
color Dark Violet to Black
PH7 (H2O, 20℃)
Water Solubility 228.7ug/L(25 ºC)
BRN 2216556
Stability:Light Sensitive
LogP3.000
CAS DataBase Reference128-95-0(CAS DataBase Reference)
NIST Chemistry Reference1,4-Diaminoanthraquinone(128-95-0)
EPA Substance Registry System1,4-Diaminoanthraquinone (128-95-0)
Safety Information
Risk Statements 22
Safety Statements 22-36/37
WGK Germany 2
RTECS CB6300000
Autoignition Temperature>400 °C
TSCA Yes
HS Code 29223990
ToxicityLD50 orally in Rabbit: 5790 mg/kg
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
1,4-Diamino anthraquinone Usage And Synthesis
Chemical PropertiesViolet powder
Chemical Properties1,4-Diaminoanthraquinones (DAAQs) are an active substance. Because of its quinone function (reduction), two amine functions (oxidation) and aromatic base structures are combined that stabilize the reduced and oxidized species via electron delocalization. Therefore, they have five different electrochemical oxidation states: a neutral state, two reduced states, and two oxidized states. However, their practical availability is limited due to their low solubility in commonly used polar organic solvents.
UsesAs an anthraquinone derivative, 1,4-Diamino anthraquinone is a potent and selective protein kinase CK1 delta inhibitor. Studies suggest that it has potential solar cell applications. 1,4-Diamino anthraquinone can be used in studies as a potential competitive non-peptidic inhibitor of HIV-1 proteinase.
UsesUse as the intermediate of synthetic dyes. Use anthraquinone reductive dyes and dispersal dyes and acid dyes and intermediates. Itself to disperse dyestuffs purple. 1,4-Diaminoanthraquinone oxidized with different metal atoms gives rise to conducting coordination polymers consisting of difunctional ligand molecules linked by metal atoms. 1, 4-diaminoanthraquinone has solar cell applications. A hybrid Si/poly (1, 4-diaminoanthraquinone) photoconductive diode for optical sensor applications. Acts as the sequential incorporation of the mediator in electrochemical sensing of glucose on a gold electrode.
Synthesis1,4-Diaminoanthraquinone is prepared by hydroxyl replacement from 1,4-dihydroxyanthraquinone via the 2,3-dihydro compound and subsequent oxidation of the intermediate 2,3-dihydro-1,4- diaminoanthraquinone .
Purification MethodsPurify the anthraquinone by thin-layer chromatography on silica gel using toluene/acetone (9:1) as eluent. The main band is scraped off and extracted with MeOH. The solvent is evaporated, and the quinone is dried in a drying pistol [Land et al. J Chem Soc, Faraday Trans 1 72 2091 1976]. It crystallises from EtOH (m 269o) in dark violet crystals. Store it in sealed ampoules in the dark. [Beilstein 14 H 197, 14 II 113, 14 III 437, 14 IV 458.]
Properties and Applications

Standard

Ironing Fastness

Light Fastness

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Fading

Stain

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Stain

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ISO

4

2

5-6

5

5

4-5

5

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