- 2-Chlorobenzaldehyde
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- $1.00 / 1g
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2024-09-20
- CAS:89-98-5
- Min. Order: 1g
- Purity: 99%
- Supply Ability: 1000kg
- 2-Chlorobenzaldehyde
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- $0.00 / 200KG
-
2024-09-20
- CAS:89-98-5
- Min. Order: 1KG
- Purity: 99%
- Supply Ability: 500mt/year
- 2-Chlorobenzaldehyde
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- $10.50 / 1KG
-
2024-09-19
- CAS:89-98-5
- Min. Order: 1KG
- Purity: 99%
- Supply Ability: 10 ton
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| 2-Chlorobenzaldehyde Basic information |
| 2-Chlorobenzaldehyde Chemical Properties |
Melting point | 9-11 °C (lit.) | Boiling point | 209-215 °C (lit.) | density | 1.248 g/mL at 25 °C (lit.) | vapor density | 4.84 (vs air) | vapor pressure | 1.27 mm Hg ( 50 °C) | refractive index | n20/D 1.566(lit.) | Fp | 190 °F | storage temp. | Store in RT | solubility | 1.8g/l | form | Liquid | color | Clear colorless to light yellow | PH | 2.9 (H2O)(saturated aqueous solution) | Water Solubility | 0.1-0.5 g/100 mL at 24 ºC | Sensitive | Air Sensitive | BRN | 385877 | Stability: | Stable. Combustible. Incompatible with strong oxidizing agents, strong bases, iron, strong reducing agents. Moisture and light-sensitive. | LogP | 2.44 at 25℃ | CAS DataBase Reference | 89-98-5(CAS DataBase Reference) | NIST Chemistry Reference | Benzaldehyde, 2-chloro-(89-98-5) | EPA Substance Registry System | 2-Chlorobenzaldehyde (89-98-5) |
Hazard Codes | C,Xi | Risk Statements | 34 | Safety Statements | 26-45 | RIDADR | UN 3265 8/PG 3 | WGK Germany | 1 | RTECS | CU5075000 | F | 8-9-23 | Autoignition Temperature | 746 °F | Hazard Note | Irritant | TSCA | Yes | HazardClass | 8 | PackingGroup | III | HS Code | 29130000 | Hazardous Substances Data | 89-98-5(Hazardous Substances Data) | Toxicity | LD50 orally in Rabbit: 2160 mg/kg |
| 2-Chlorobenzaldehyde Usage And Synthesis |
Chemical Properties | 2-Chlorobenzaldehyde is a colorless to yellowish liquid with a penetrating odor. Insoluble in water, soluble in benzene, alcohol and ether. 2-Chlorobenzaldehyde is considerably more resistant to oxidation than benzaldehyde. When it is heated with sodium sulfite solution under pressure, benzaldehyde-2-sulfonic acid forms. | Uses | 2-Chlorobenzaldehyde can be used to make alcohols, acids, and dyes; used in the rubber, tanning, and
paper industries; used as an intermediate for optical
brighteners, agricultural chemicals, and pharmaceuticals.It can also be used to prepare triphenyl methane and related dyes, organic intermediate. | Uses | 2-Chlorobenzaldehyde has been used in generation of small focused library of diversely functionalized dihydropyrimidine derivatives via one-pot three-component Biginelli cyclocondensation of β-ketoesters, aldehydes and thioureas. | Preparation | 2-Chlorobenzaldehyde is produced mainly by chlorination of 2-chlorotoluene to form 2-chlorobenzal chloride, which is then subjected to acid hydrolysis. Metal salts, such as iron(III) chloride, are used as catalysts. The hydrolysis can also be accomplished using formic acid without a catalyst. 2-Chlorobenzaldehyde can also be produced by oxidation of 2-chlorobenzyl chloride with N-oxides of tertiary amines or with dilute nitric acid. https://pubchem.ncbi.nlm.nih.gov/compound/2-Chlorobenzaldehyde | Application | 2-Chlorobenzaldehyde is used acid zinc plating brightener, also be used for organic synthesis, agricultural pesticide and pharmaceutical industries. It is used to synthesize the acaricides clofentezine and flutenzine. 2-Chlorobenzaldehyde undergoes alkynylation with phenylacetylene in the presence of catalytic ligands and dimethylzinc at 0°C to form binaphthyl-derived amino alcohols. | Synthesis Reference(s) | Tetrahedron Letters, 34, p. 8037, 1993 DOI: 10.1016/S0040-4039(00)61444-2 | General Description | 2-chlorobenzaldehyde is a clear colorless to yellowish liquid. (NTP, 1992) | Air & Water Reactions | 2-Chlorobenzaldehyde is moisture and light sensitive. Slightly water soluble. | Reactivity Profile | 2-Chlorobenzaldehyde reacts with iron and strong oxidizers, strong bases and strong reducing agents. | Health Hazard | Symptoms of exposure to 2-Chlorobenzaldehyde may include skin, eye
and upper respiratory tract irritation. This
compound may cause skin, eye and respiratory tract irritation. When
heated to decomposition it emits toxic fumes. | Fire Hazard | 2-Chlorobenzaldehyde is combustible. | Safety Profile | Poison by
intraperitoneal and intravenous routes.
When heated to decomposition it emits
toxic fumes of Cl-. See also ALDEHYDES
and CHLORIDES. | Purification Methods | Wash it with 10% Na2CO3 solution, then fractionally distil it in the presence of a small amount of catechol as stabiliser. [Beilstein 7 H 233, 7 IV 561.] |
| 2-Chlorobenzaldehyde Preparation Products And Raw materials |
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