Chemical Safety Data Sheet MSDS / SDS

SODIUM PERCHLORATE MONOHYDRATE

Revision Date:2023-11-29Revision Number:1

SECTION 1: Identification of the substance/mixture and of the company/undertaking

Product identifier

  • Product name: SODIUM PERCHLORATE MONOHYDRATE
  • CBnumber: CB9149027
  • CAS: 7791-07-3
  • EINECS Number: 616-573-0
  • Synonyms: Sodium Perchlorate Monohydrate,Sodium perchlorate hydrate

Relevant identified uses of the substance or mixture and uses advised against

  • Relevant identified uses: For R&D use only. Not for medicinal, household or other use.
  • Uses advised against: none

Company Identification

  • Company: Chemicalbook
  • Address: Building 1, Huihuang International, Shangdi 10th Street, Haidian District, Beijing
  • Telephone: 400-158-6606

SECTION 2: Hazards identification

GHS Label elements, including precautionary statements

  • Symbol(GHS)
  • Signal wordDanger
Precautionary statements
P220 Keep/Store away from clothing/…/combustible materials.
P221 Take any precaution to avoid mixing with combustibles/…
P283 Wear fire/flame resistant/retardant clothing.
P306+P360 IF ON CLOTHING: Rinse Immediately contaminated CLOTHING and SKIN with plenty of water before removing clothes.
P371+P380+P375 in case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion.
Hazard statements
H271 May cause fire or explosion; strong oxidiser
H302 Harmful if swallowed

SECTION 3: Composition/information on ingredients

Substance

  • Product name: SODIUM PERCHLORATE MONOHYDRATE
  • Synonyms: Sodium Perchlorate Monohydrate,Sodium perchlorate hydrate
  • CAS: 7791-07-3
  • EC number: 616-573-0
  • MF: ClH2NaO5
  • MW: 140.46

SECTION 4: First aid measures

Description of first aid measures

General advice
Consult a physician. Show this material safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Flush eyes with water as a precaution.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

Most important symptoms and effects, both acute and delayed

The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11

Indication of any immediate medical attention and special treatment needed

No data available

SECTION 5: Firefighting measures

Extinguishing media

Suitable extinguishing media
Dry powder Dry sand

Special hazards arising from the substance or mixture

Hydrogen chloride gas Sodium oxides

Advice for firefighters

Wear self-contained breathing apparatus for firefighting if necessary.

Further information

Use water spray to cool unopened containers.

NFPA 704

2
0
2
OX
HEALTH 2 Intense or continued but not chronic exposure could cause temporary incapacitation or possible residual injury (e.g. diethyl ether, ammonium phosphate, iodine)
FIRE 0 Materials that will not burn under typical fire conditions, including intrinsically noncombustible materials such as concrete, stone, and sand. Materials that will not burn in air when exposed to a temperature of 820 °C (1,500 °F) for a period of 5 minutes.(e.g. Carbon tetrachloride)
REACT 2 Undergoes violent chemical change at elevated temperatures and pressures, reacts violently with water, or may form explosive mixtures with water (e.g. white phosphorus, potassium, sodium)
SPEC. HAZ. OX

SECTION 6: Accidental release measures

Personal precautions, protective equipment and emergency procedures

Use personal protective equipment. Avoid dust formation. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8.

Environmental precautions

Prevent further leakage or spillage if safe to do so. Do not let product enter drains.

Methods and materials for containment and cleaning up

Sweep up and shovel. Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and place in container for disposal according to local regulations (see section 13). Keep in suitable, closed containers for disposal.

Reference to other sections

For disposal see section 13.

SECTION 7: Handling and storage

Precautions for safe handling

Advice on safe handling

Avoid formation of dust and aerosols.

Advice on protection against fire and explosion

Provide appropriate exhaust ventilation at places where dust is formed.Keep away from sources of ignition - No smoking.

Hygiene measures

Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.

For precautions see section 2.2.

Conditions for safe storage, including any incompatibilities

Storage conditions

Keep container tightly closed in a dry and well-ventilated place. Store in cool place.

Specific end use(s)

Apart from the uses mentioned in section 1.2 no other specific uses are stipulated

SECTION 8: Exposure controls/personal protection

control parameter

Hazard composition and occupational exposure limits
Does not contain substances with occupational exposure limits.

Exposure controls

Personal protective equipment
Eye/face protection

Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Skin protection

Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.

The selected protective gloves have to satisfy the specifications of Regulation (EU) 2016/425 and the standard EN 374 derived from it.

Body Protection

Impervious clothing, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.

Respiratory protection

Where risk assessment shows air-purifying respirators are appropriate use a full- face particle respirator type N100 (US) or type P3 (EN 143) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

Control of environmental exposure

Prevent further leakage or spillage if safe to do so. Do not let product enter drains.

SECTION 9: Physical and chemical properties

Information on basic physicochemical properties

  • Appearancewhite crystalline
  • OdourNo data available
  • Odour ThresholdNo data available d) pH 4,5 - 7,0 at 50 g/l at 25 °C Melting point/freezing point Melting point/range: 472 °C Initial boiling point No data available and boiling range Flash point Not applicable Evaporation rate No data available Flammability (solid, gas) Upper/lower flammability or explosive limits No data available No data available Vapour pressure No data available Vapour density No data available Relative density No data available Water solubility soluble Partition coefficient: n-octanol/water Autoignition temperature Decomposition temperature No data available No data available 482 °C - Viscosity Viscosity, kinematic: No data available Viscosity, dynamic: No data available Explosive properties No data available Oxidizing properties The substance or mixture is classified as oxidizing with the category 1.
  • Melting point/freezing pointMelting point/range: 472 °C
  • Initial boiling point and boiling range130 °C
  • Flash pointNot applicable
  • Evaporation rateNo data available
  • Flammability (solid, gas)No data available
  • Upper/lower flammability or explosive limitsNo data available
  • Vapour pressure No data available
  • Vapour density No data available
  • Relative densityNo data available
  • Water solubilitysoluble
  • Partition coefficient: n-octanol/waterH2O: 100 mg/mL, clear, colorless
  • Autoignition temperatureNo data available
  • Decomposition temperature 482 °C -
  • ViscosityViscosity, kinematic: No data available Viscosity, dynamic: No data available
  • Explosive propertiesNo data available
  • Oxidizing propertiesThe substance or mixture is classified as oxidizing with the

Other safety information

No data available

SECTION 10: Stability and reactivity

Reactivity

No data available

Chemical stability

Stable under recommended storage conditions.

Possibility of hazardous reactions

No data available

Conditions to avoid

No data available

Incompatible materials

Organic materials, Strong acids, Forms shock-sensitive mixtures with certain other materials., Powdered metals, Reducing agents, Magnesium, Strong oxidizing agents

Hazardous decomposition products

In the event of fire: see section 5

SECTION 11: Toxicological information

Information on toxicological effects

Acute toxicity
Acute toxicity estimate Oral - 500,1 mg/kg (Expert judgment)
LD50 Dermal - Rat - male and female - > 2.000 mg/kg (OECD Test Guideline 402)
Remarks: The value is given in analogy to the following substances: Sodium perchlorate
Skin corrosion/irritation
Skin - Rabbit
Result: slight irritation (OECD Test Guideline 404)
Remarks: The value is given in analogy to the following substances: Sodium perchlorate
Serious eye damage/eye irritation
Eyes - Rabbit Result: Irritations
(OECD Test Guideline 405)
Remarks: The value is given in analogy to the following substances: Sodium perchlorate
Respiratory or skin sensitization
(OECD Test Guideline 429) Remarks:
The value is given in analogy to the following substances: Sodium perchlorate
Germ cell mutagenicity
Test Type: Ames test
Test system: Salmonella typhimurium
Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 471
Result: negative
Remarks: The value is given in analogy to the following substances: Sodium perchlorate Test Type: Mutagenicity (mammal cell test): chromosome aberration.
Test system: Human lymphocytes
Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 473
Result: negative
Remarks: The value is given in analogy to the following substances: Sodium perchlorate Test Type: In vitro mammalian cell gene mutation test
Test system: Mouse lymphoma test
Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 476
Result: negative
Remarks: The value is given in analogy to the following substances: Sodium perchlorate
Carcinogenicity
No data available
Reproductive toxicity
Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure
May cause damage to organs through prolonged or repeated exposure. - Thyroid
Aspiration hazard

SECTION 12: Ecological information

Toxicity

Toxicity to fish
static test LC50 - Danio rerio (zebra fish) - > 1.000 mg/l - 96 h (OECD Test Guideline 203)

Remarks: The value is given in analogy to the following substances: Sodium perchlorate


Toxicity to daphnia and other aquatic invertebrates

static test EC50 - Daphnia magna (Water flea) - > 100 mg/l - 48 h (OECD Test Guideline 202)

Remarks: The value is given in analogy to the following substances: Sodium perchlorate


Toxicity to algae
static test EC10 - Pseudokirchneriella subcapitata (green algae) - > 435,7 mg/l - 72 h

(OECD Test Guideline 201)

Remarks: The value is given in analogy to the following substances:

Sodium perchlorate


static test EC50 - Pseudokirchneriella subcapitata (green algae) - > 435,7 mg/l - 72 h

(OECD Test Guideline 201)

Remarks: The value is given in analogy to the following substances: Sodium perchlorate


Toxicity to bacteria
static test EC50 - activated sludge - > 700 mg/l - 3 h (ISO 8192)

Remarks: The value is given in analogy to the following substances: Sodium perchlorate

Persistence and degradability

Not applicable for inorganic substances

Bioaccumulative potential

Mobility in soil

Results of PBT and vPvB assessment

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

Other adverse effects

SECTION 13: Disposal considerations

Waste treatment methods

Product

Offer surplus and non-recyclable solutions to a licensed disposal company. Waste material must be disposed of in accordance with the Directive on waste 2008/98/EC as well as other national and local regulations. Leave chemicals in original containers. No mixing with other waste. Handle uncleaned containers like the product itself.

Contaminated packaging

Dispose of as unused product.

SECTION 14: Transport information

UN number

ADR/RID: 1502 IMDG: 1502 IATA: 1502

UN proper shipping name


ADR/RID: SODIUM PERCHLORATE IMDG: SODIUM PERCHLORATE


IATA: Sodium perchlorate

14.3

Transport hazard class(es)

ADR/RID: 5.1 IMDG: 5.1


IATA: 5.1

14.4

Packaging group

ADR/RID: II IMDG: II


IATA: II

14.5

Environmental hazards

ADR/RID: no IMDG Marine pollutant: no


IATA: no

14.6

Special precautions for user

No data available


SECTION 15: Regulatory information

Safety, health and environmental regulations/legislation specific for the substance or mixture

Regulations on the Safety Management of Hazardous Chemicals
China Catalog of Hazardous chemicals 2015:Not Listed. website: https://www.mem.gov.cn/
Measures for Environmental Management of New Chemical Substances
Korea Existing Chemicals List (KECL):Not Listed. website: http://ncis.nier.go.kr
Philippines Inventory of Chemicals and Chemical Substances (PICCS):Not Listed. website: https://emb.gov.ph/
United States Toxic Substances Control Act (TSCA) Inventory:Not Listed. website: https://www.epa.gov/
European Inventory of Existing Commercial Chemical Substances (EINECS):Not Listed. website: https://echa.europa.eu/
EC Inventory:Not Listed.
Vietnam National Chemical Inventory:Listed. website: https://chemicaldata.gov.vn/
New Zealand Inventory of Chemicals (NZIoC):Listed. website: https://www.epa.govt.nz/
Chinese Chemical Inventory of Existing Chemical Substances (China IECSC):Listed. website: https://www.mee.gov.cn/

SECTION 16: Other information

Abbreviations and acronyms

  • ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
  • CAS: Chemical Abstracts Service
  • EC50: Effective Concentration 50%
  • IATA: International Air Transportation Association
  • IMDG: International Maritime Dangerous Goods
  • LC50: Lethal Concentration 50%
  • LD50: Lethal Dose 50%
  • RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
  • STEL: Short term exposure limit
  • TWA: Time Weighted Average

References

【1】CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple

【2】ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp

【3】ECHA - European Chemicals Agency, website: https://echa.europa.eu/

【4】eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en

【5】ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg

【6】Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp

【7】HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm

【8】IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/

【9】IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home

【10】Sigma-Aldrich, website: https://www.sigmaaldrich.com/

Disclaimer:

The information in this MSDS is only applicable to the specified product, unless otherwise specified, it is not applicable to the mixture of this product and other substances. This MSDS only provides information on the safety of the product for those who have received the appropriate professional training for the user of the product. Users of this MSDS must make independent judgments on the applicability of this SDS. The authors of this MSDS will not be held responsible for any harm caused by the use of this MSDS.

Recommended Products
Sodium hypochlorite SDS Sodium iodate SDS PERCHLORIC ACID SDS SODIUM PERBORATE TRIHYDRATE SDS SODIUM PERCHLORATE MONOHYDRATE SDS