| Identification | More | [Name]
PHENYLMERCURIC CHLORIDE | [CAS]
100-56-1 | [Synonyms]
(CHLOROMERCURI)BENZENE
CHLOROPHENYL MERCURY
MERCURI PHENYL CHLORIDE
PHENYLMERCURIC CHLORIDE
PHENYLMERCURY CHLORIDE
PHENYLMERCURY(II) CHLORIDE
PMC
STOPSPOT
(chloromercuri)-benzen
(chloromercurio)-benzen
Agrenal
Agronal
Benzene, (chloromercuri)-
Benzene, (chloromercurio)-
Chlorid fenylrtutnaty
chloridfenylrtutnaty
chloridfenylrtutnaty(czech)
chlorophenyl-mercur
Fenylmercurichlorid
fenylmercurichlorid(czech) | [EINECS(EC#)]
202-865-1 | [Molecular Formula]
C6H5ClHg | [MDL Number]
MFCD00000463 | [Molecular Weight]
313.15 | [MOL File]
100-56-1.mol |
| Chemical Properties | Back Directory | [Appearance]
white fine crystalline powder | [Melting point ]
248-250 °C (dec.)(lit.) | [storage temp. ]
Poison room | [solubility ]
soluble in DMSO | [form ]
solid | [Water Solubility ]
Soluble in benzene, ether, pyridine. Very slightly soluble in water | [Merck ]
14,7301 | [BRN ]
3536717 | [Henry's Law Constant]
3.8×102 mol/(m3Pa) at 25℃, Abraham et al. (2008) | [Exposure limits]
ACGIH: TWA 0.1 mg/m3 (Skin)
NIOSH: IDLH 10 mg/m3; TWA 0.05 mg/m3; Ceiling 0.1 mg/m3 | [Cosmetics Ingredients Functions]
PRESERVATIVE | [CAS DataBase Reference]
100-56-1(CAS DataBase Reference) | [EPA Substance Registry System]
Mercury, chlorophenyl- (100-56-1) |
| Safety Data | Back Directory | [Hazard Codes ]
T+,N | [Risk Statements ]
R26/27/28:Very Toxic by inhalation, in contact with skin and if swallowed .
R33:Danger of cumulative effects.
R50/53:Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment . | [Safety Statements ]
S13:Keep away from food, drink and animal feeding stuffs .
S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) .
S36:Wear suitable protective clothing .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S60:This material and/or its container must be disposed of as hazardous waste .
S61:Avoid release to the environment. Refer to special instructions safety data sheet . | [RIDADR ]
UN 2026 6.1/PG 3
| [WGK Germany ]
3
| [RTECS ]
OW1400000
| [HazardClass ]
6.1 | [PackingGroup ]
II | [HS Code ]
28439090 | [Safety Profile]
Poison by ingestion, intraperitoneal, and subcutaneous routes. Human mutation data reported. When heated to decomposition ir emits very toxic fumes of Cland Hg. See also MERCURY COMPOUNDS and CHLORIDES. | [Hazardous Substances Data]
100-56-1(Hazardous Substances Data) | [Toxicity]
LD50 s.c. in rats: 30 mg/kg (Umeda) |
| Hazard Information | Back Directory | [Chemical Properties]
white fine crystalline powder | [Uses]
Phenylmercuric chloride has been used as an agricultural fungicide.
| [Uses]
The reaction of phenylmercury (II) chloride with acetophenonethiosemicarbazone (Hatsc) in ethanol in 1: 1 mole ratio undergoes symmetrisation forming the products, HgCl2 (Hatse) 2 and Ph2Hg instead of the anticipated compound PhHgCl (Hatse). A new method for the determination of chloride ion is based on the formation of phenylmercury(II) chloride, its extraction into chloroform and reaction with sodium diethyldithiocarbamate to form phenylmercury(II) diethyldithiocarbamate. | [Production Methods]
Phenylmercury chloride was historically produced through a straightforward electrophilic substitution process in which metallic mercury or mercuric salts were reacted with chlorobenzene under conditions that promote formation of an organomercury bond. Industrial routes typically used mercuric acetate or mercuric oxide as the mercury source; these were first converted into a reactive phenylmercury intermediate, often via treatment with phenyl generating reagents such as diazonium salts, and then chlorinated to yield the final chloride. The crude product was purified by recrystallisation to obtain a stable, white crystalline solid suitable for formulation. | [Mechanism of action]
Curative. Mercury-based fungicides work by disrupting enzyme activity in fungal cells, leading to cellular dysfunction and death. | [Pesticide Type]
Fungicide |
|
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Alfa Aesar
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400-6106006 |
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http://chemicals.thermofisher.cn |
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Spectrum Chemical Manufacturing Corp.
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021-021-021-67601398-809-809-809 15221380277 |
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www.spectrumchemical.com/oa_html/index.jsp?minisite=10020&respid=22372&language=us |
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